Question

Calculate the lattice energy of lithium iodide, using both the Born–Landé and the Kapustinskii equations. Compare...

TABLE 8.3 Thermochemical Data and Lattice Energies for Alkali-Metal Halides AH, 298 AHSub IE AH EA UB-H UB-L diff. Ulan LIF

Calculate the lattice energy of lithium iodide, using both the Born–Landé and the Kapustinskii equations. Compare these values with those found in Table 8.3.

TABLE 8.3 Thermochemical Data and Lattice Energies for Alkali-Metal Halides AH, 298 AHSub" IE AH EA UB-H UB-L diff." Ulan LIF - 968 -886 - 784 7.5 4.5 5.1 5.1 - 960 - 873 - 774 NaF KF REF CsF - 752 -- 741 -709 4.3 LiCI 1 59.4 107.3 89.2 80.9 76.1 159.4 107.3 89.2 80.9 76.1 159.4 107.3 5.9 4.6 NaCl KCI RbCI CsCI 5.7 5.8 -616. 0 -573.6 - 567.3 -557.7 --553.5 - 408.6 - 411.1 - 436.8 - 435.3 - 443.0 - 351.2 - 361.1 - 393.8 - 394.6 - 395.0 - 270.4 - 287.6 -- 327.9 - 333.8 - 346.6 4.6 520.3 495.9 418. 9 403.1 375.8 520.3 495.9 418.9 403.1 375.8 520.3 495.9 418. 9 403.1 375.8 520.3 495.9 418.9 403.1 375.8 79.0 79.0 7 9.0 79.0 79.0 121.7 121.7 121.7 121.7 121.7 111.9 111.9 111.9 111.9 111.9 106.8 106.8 106.8 106.8 106.8 - 328.0 -328.0 - 328.0 - 328.0 - 328.0 - 349.0 - 349.0 - 349.0 - 349.0 - 349.0 - 324.7 - 324.7 - 324.7 - 324.7 - 324.7 - 295.2 - 295.2 - 295.2 - 295.2 - 295.2 -1046.7 -927.8 -826.4 - 792.7 - 756.4 - 861.0 - 787.0 -- 717.6 -692.0 - 667.6 -818.1 - 751.5 -689.1 - 665.8 - 634.1 - 761.7 - 702.6 .647.6 - 629.4 .610.1 - 724 -810 - 751 -677 -652 -637 - 774 - 719 - 650 -628 -613 - 724 - 675 -614 - 593 - 580 -810 - 746 - 672 - 647 -622 - 772 - 713 - 645 -622 4.3 89.2 LiBr NaBr KBr RbBr CsBr Lil Nal KI RbI Csi 5.7 80.9 76.1 159.4 107.3 89.2 80.9 76.1 -718 -667 5.0 3.9 5.2 5.8 4.9 - 607 -586 - 566
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Here you go !a for Boon - hande equation, Voz - 1.39X10SXA X]z +117=1861-17 ___Mo . As Madeleeng Constant. A- Born exponent ro inter ednicKupustensa ko Equestion, 84.5 sho No - 120 200 w Z+Z-/- - Mo. where vt no. of conser for Li I v = 2 as Vo = -120200 x 2x1 /

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