


3. (4 points) Assign absolute configuration to each stereogenic center(s) in each molecule, draw an enantiomer...
1. (2 points) Draw the enantiomer of the molecule shown below, and indicate absolute configuration for each stereogenic center. 3 c4 ОН Enantiomer
4. (4 points) Assign absolute configuration (R or S) to each stereogenic center of the molecules shown below CH ОН ny NH2 OH
7.(a) Draw and label (a) the enantiomer and 6) compound. (4 points) me enantiomer and (b) a s of diaststomers of the following (b) Will a 50:50 mix of the enantiomers be optically active (rotate plane polarized light). Explain the reason for your answer (3 points) b) Will a 50:50 mix of the two structures you drew in (b) be optically active (rotate plane polarized light). Explain the reason for your answer (3 points) 8. Assign the chiral center as...
please help me. Draw a Fisher projection for X and
assign the absolute configuration for the stereogenic center.then
draw a skeletal structure of the enantiomer of X
Br transpose manipulate Br СІ Configuration (circle one): R S Enantiomer:
4. Assign R or S configuration to each chiral center in each of the following molecules (A-D). Which are enantiomers and which are diastereoisomer? Hint: redraw the molecules if it makes it easier to visualize or use a modeling kit. H H A В CH Br Hас, Br 'CHs Нo Hас H он Br Br D CHз Hас Н. "CHз но Он CH3
4. Consider the molecules shown below. Assign the R/S configuration to each chiral center below. If you have difficulty, try building a molecule. (4 points) он Br н NH2 Br
15 uestion 25 Assign the Ror S configuration to each stereogenic center in the Fischer projection below. CHO HTH a+H H- OH CH3 O R, S, R R, R, R OOOOO S, S, S SRS S, S, R
This molecule has several chiral centers labeled. Indicate the R/S configuration for the center labeled B. HN NH OR os This molecule has several chiral centers labeled. Indicate the R/S configuration for the center labeled B. H3 CH3 НО СН3 НЕ ОН IIIty .(с NH2 ОН. ОН о ОН о
18. Assign the absolute configuration of the two stereocenters in stereoisomer of 2-bromo-3-pentanol shown below. Br ОН a) 2R, 3R b) 2R, 3S c) 2S, 3R d) 2S, 3S 19. The following are 5 stereorepresentations of 1,5-dimercaptopentane-1,5-diol. Taking (1) as a reference structure. Determine if each of the other stereorepresentations are conformers to (1), enantiomers to (1) and diastereomers of (1). OH OH Enantiomer Diastereomer Conformer HS SH (2) он SH Enantiomer Diastereomer Conformer OH OH HS "ОН (3) ON...
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9. Assign the absolute (Ror S) configuration to the chirality centers in each of the following molecules (10 points). CHO HO- но -н CH.CH