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Suppose that you have two different solutions made using the same solvent. When you cool the...

Suppose that you have two different solutions made using the same solvent. When you cool the first one, the entire solution freezes at a single temperature. When you cool the second one, however, the solution startsfreezing at one temperature, but the temperature is different when it finishes freezing. Which of the two solutions has the lower freezing point, and why?

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Answer #1

First solvent has a sharp freezing point. This implies that the first solvent is pure.

The second solvent does not have a sharp freezing point. This implies that the second solvent is not pure. It has some solute dissolved in it. Hence, the chemical potential of the second solvent is lower than the first solvent.

According to colligative properties, the solvent with solute dissolved in it will experience freezing point depression.

Hence, the second solvent has the lower freezing point.

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