Give the correct formula for each complex ion shown below. Then draw the structure of the...
Give the correct formula for each complex ion shown below. Then draw the structure of the ion, along with one example of a diastereomer and one example of an enantiomer. If the ion has no diastereomers or enantiomers, write ‘NA’. (15 pts)
a. cis–dibromodichloroplatinate(II)
|
Formula_______________________________________ Ion |
Diastereomer |
Enantiomer |
b. trans–diamminebis(ethylenediamine)cobalt(III)
|
Formula_______________________________________ Ion |
Diastereomer |
Enantiomer |
trioxalatochromate(III)
|
Formula_______________________________________ Ion |
Diastereomer |
Enantiomer |
d. amminebromocyanohydroxozincate(II)
(tetrahedral)
|
Formula:_______________________________________ Ion |
Diastereomer |
Enantiomer |
Homework Answers
Cis-dichlorodibromo platinate(II) ------------------------------ [Pt Br2 Cl2 ]2-
Br Cl 2- Br Cl 2-
Pt Pt
Br Cl Cl Br
trans-diamine bis-( ethylenediamine) cobalt(III) ------------[ Co (en)2 ( NH3 )2 ] 3+
trioxalato chromate (III) --------------------------------------- [ Cr ( C2 O4 )3 ]3-
aminebromocynohydraxo zincate(II) -------------------- [Zn ( NH3 ) Br2 (CN) (OH) ]2-
N / A
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Give the correct formula for each complex ion shown below. Then
draw the structure of the...
Complex # of Coordination number Oxidation number Complex Structure ligands geometry NH4Co(NCS)(py): [RhBr(CO)s(NO...
Complex # of Coordination number Oxidation number Complex Structure ligands geometry NH4Co(NCS)(py): [RhBr(CO)s(NO) K[Fe(CN) [Hgl.] Cu(NH)Cl 3. What are the bond angles for the following geometries: Tetrahedral Linear Square planar_ Octahedral 4. A complex ion contains tungsten(II) bound to 4 water molecules and 2 fluoride ions. Using appropriate conventions write out its formula. 5. A complex ion contains copper(II) bonded to ethylenediamine and two water molecules. Using appropriate conventions write out its formula.
Complex # of Coordination number Oxidation number...
3. For each of these following complexes: Hexaaquacobalt(III), Trioxalatocobaltate(III), Triglycinatocobaltate(III),...
3. For each of these following complexes: Hexaaquacobalt(III), Trioxalatocobaltate(III), Triglycinatocobaltate(III), Tricarbonatocobaltate(III), and Tris(1,10-phenanthroline)cobalt(III).... Write out the chemical formula Identify the coordination number of the metal ion Identify whether the ligand is monodentate or polydentate Does the complex form cis-trans isomers? Does the complex form enantiomers? 4. In each of the complexes mentioned, cobalt has an oxidation state of +3. How many d electrons does Co(III) have? 5. Draw the Crystal Field splitting diagram for the Co(III) complex assuming it is...
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CORRECT ANSWER ONLY NO EXPLANATION
04-09-2019 Each of the next questions will be graded over 10 points. Answer 80 points. 1. Which of the following reaction will proceed to the formation of products Ayco" + 2 H2O → CoOz +4H' +e. D) Fe-Fe +e 2. Which of the following is mostly ionic? A) Col 3. Which of the following complexes is tetrahedral? 4. Which of the following complexes is chiral? (py- pyridine, en ethylenediamine 5. How many isomer have the...
Write the molecular formula and draw the molecular structure of each of the following coordination compounds....
Write the molecular formula and draw the molecular structure of each of the following coordination compounds. Indicate the d-electron count of each metal center. (e) cis-dichlorobis(ethylenediamine palladium(IV) bromide (f) diamminesilver(I) dicyanoargenate(I) (g) pentacarbonyliron(0) (h) tris(2,2-bipyridine)osmium(II) sulfate
Give the correct names for the structures drawn (i.e. A-E) or draw the structure for each...
Give the correct names for the structures drawn (i.e. A-E) or draw the structure for each of the names given (i.e., F-G) for the compounds below, and use the cis/trans, R/S labeling when appropriate.1a-Chloro-6-(trans) cyclobuty1 - 3- (cis) cyclohexyl-2-(cis) hydroxy-5-(rans) flouro-4-(cis) - (3 - Hydroxypropyl) cyclohexane
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1)- Give the correct name (A-B) or draw the structure (C) for each of the following compounds, and use cis/trans, labeling when appropriate (Choose 2 Problems) CH[CH(CH:)),CF.CH[C(CH), JCH,C(CH),CHCI(CH(CH;)2] Name of A: Name of B: Trans- 1 cyclobutyl 3 isobutylyyclohexane Structure of C: Note: You must provide all answers on the original question sheet for and your answer should be written where specified. 1)- Give the correct name (A-B) or draw the structure (C) for each of the following compounds, a...
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Complex # of Coordination number Oxidation number Complex Structure ligands geometry NH4Co(NCS)(py): [RhBr(CO)s(NO) K[Fe(CN) [Hgl.] Cu(NH)Cl 3. What are the bond angles for the following geometries: Tetrahedral Linear Square planar_ Octahedral 4. A complex ion contains tungsten(II) bound to 4 water molecules and 2 fluoride ions. Using appropriate conventions write out its formula. 5. A complex ion contains copper(II) bonded to ethylenediamine and two water molecules. Using appropriate conventions write out its formula.
Complex # of Coordination number Oxidation number...
CORRECT ANSWER ONLY NO EXPLANATION
04-09-2019 Each of the next questions will be graded over 10 points. Answer 80 points. 1. Which of the following reaction will proceed to the formation of products Ayco" + 2 H2O → CoOz +4H' +e. D) Fe-Fe +e 2. Which of the following is mostly ionic? A) Col 3. Which of the following complexes is tetrahedral? 4. Which of the following complexes is chiral? (py- pyridine, en ethylenediamine 5. How many isomer have the...
Give the correct names for the structures drawn (i.e. A-E) or draw the structure for each of the names given (i.e., F-G) for the compounds below, and use the cis/trans, R/S labeling when appropriate.1a-Chloro-6-(trans) cyclobuty1 - 3- (cis) cyclohexyl-2-(cis) hydroxy-5-(rans) flouro-4-(cis) - (3 - Hydroxypropyl) cyclohexane
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