
For bromination Br/FeBr3 is
used. selective alkylation of benzene can be carried out using
Sc(CF3SO3)3 With allylic or vinylic alcohol. Electron deficient
fused ring gives Birch reduction.
5. Each transformation shown below requires at least two steps. Provide the reagents/conditions for each transform...
5.
Each transformation shown below requires at least two steps.
provide the reagent/conditions for each transformation. 6. Predict
the products from the birch reduction shown below. Bonus: Prodvide
a synthesis for the target molecule using benzene
5. Each transformation shown below requires at least two steps. Provide the reagents/conditions for each transformation. (20 pts) Reagents ? Reagents A-2 COM Reagents D-? Reagents B-? Reagents C-2 6. Predict the products from the Birch reductions shown below. (3 pts) ON N NH,...
each transformation shown below requires at least two steps.
provide the reagents/conditions for each transformation.
5. Each transformation shown below requires at least two steps. Provide the reagents/conditions for each transformation. (20 pt A:Br2, Febra Bich - CH Reagents ? Reagents A-? CHNO₂, H₂SO4 2.) Fe, HCl 3.) NaOH Reagents D- Reagents ? Reagents ? 6. Predict the product from the Birch reduction shown below: (3 pts) Na, NH3 CHLOH
mation shown below requires at least two steps. Provide the reagents/conditions for each & Each transformatie transformation. (20 pts) Reagents A-? Reagents ? Reagents D? Reagents .....: Reagents ? 6. Predict the product from the Birch reduction shown below: (3 pts) N2, NH3 CH, OH Bonus: (6 pts) Provide a synthesis for the target molecule using benzene.
4. Provide a plausible mechanism for the reaction shown. (6 pts) Naal 5. Each transformation shown below requires at least two steps. Provide the reagents/conditions for each transformation. (20 pts) Reng Remsc 6. Predict the products from the Birch reductions shown below. (3 pts) Mì, NHÀ са он Bonus: (6 pts) Provide a synthesis for the target molecule using benzene. CO2H oto сон TM
5. Each transformation shown below requires at least two steps. Provide the reagents/conditions for each 10. O transformation. (20 pts) Reagents ? Reagents A-2 Reagents D-7 Reagents B-? Reagents ?
Each transformation shown below requires at least two steps. Provide the reagents/conditions for each transformation. CHS Reagents F-? Reagents A=? CH Reagents D=? Reagents B=? CH Recents C-
4. Provide a plausible mechanism for the reaction shown. (6 pts) 7 NaNH. Hycor ND 5. Each transformation shown below requires at least two steps. Provide the reagents/conditions for each transformation. (20 pts) Reagents Reagents A! Reagents D-7 Reagents Reagents 6. Predict the products from the Birch reductions shown below. (3 pts) Nz, NHU CH OH Bonus: (6 pts) Provide a synthesis for the target molecule using benzene. CO2H CO2H TM 1. Draw Frost circle diagrams for each compound shown....
Can you please answer all of them?
Section B: Free Response (you must show your work for full credit) 1. Draw Frost circle diagrams for each compound shown. Assume that all atoms in the ring are sp2 hybridized. Populate the pi electrons in the corresponding MO's. Identify the compound as aromatic or antiaromatic. (5 pts) 2. What is the Hückel number of pi electrons for the molecule shown below? How many pi electron pairs does it have? Would you expect...
4. Provide a plausible mechanism for the reaction shown. (6 pts) NaNH . NHA 5. Each transformation shown below re transformation. (20 pts) two steps. Provide the reagents/conditions for each
18. Write a curved arrow mechanism for the reaction shown below. You must show the electrophile and sigma complex. (6 pts) осн, AICI 19. Each transformation shown below requires at least two steps. Provide the reagents/conditions for each transformation. (20 pts) Reagents A- Reagents P COM Reagemts D- Regents D- Resgents C сон