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You wish to make a buffer solution using an acid (HA) with a Ka of 8.90 x 10-6 and a salt of its conjugate base (NaA). If you
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Answer #1

Sol.

As Conc. of HA = [HA] = 1.50 M

Conc. of NaA = [NaA] = 2.25 M

Ka = 8.90 × 10-6

pKa = - log(Ka) = - log( 8.90 × 10-6 ) = 5.05  

So , Using Henderson - Hasselbalch equation ,

pH = pKa + log ( [NaA] / [HA] )

= 5.05 + log ( 2.25 / 1.50 )

=   5.23

Also , Hydronium Concentration at equilibrium

= [H3O+] = 10-pH

= 10-5.23  

=  5.89 × 10-6 M

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