splitting of orbitals is directly related with the hybridisation posses by the complex
and as we know the splitting patterns
for S orbital the symmetry set is A1g
for P orbital splitting set is T 1u
and d orbital splitting into t 2g and e g sets
t2g denotes group of three orbitals dxy ,dyz,dzx
and e_{eg} set denotes group of 2 orbitals d z2 , d( x2 -y2)
(a) linear complex ML2 has SP hybridisation
symmetrys setsare A 1g , T 1u
(b) pyramydal M L3 has SP3 hybridisation A 1g + T 1u
(c) for ML7 hybridisation pattern is S P3d3
here in octahedral environment = A 1g + T 1g + T 2g
these are the splitting symmytry of d orbital.
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