Pb(ClO3)2(aq)+2NaI(aq)⟶PbI2(s)+2NaClO3(aq)
What mass of precipitate will form if 1.50 L of highly concentrated Pb(ClO3)2 is mixed with 0.900 L 0.100 M NaI? Assume the reaction goes to completion.
mass of precipitate in grams:
moles of NaI reacting = M(NaI)*V(NaI)
= 0.100 M * 0.900 L
= 0.090 mol
From reaction,
mol of PbI2 formed = (1/2)*number of moles of NaI reacted
= (1/2)*0.090 mol
= 0.045 mol
Molar mass of PbI2,
MM = 1*MM(Pb) + 2*MM(I)
= 1*207.2 + 2*126.9
= 461 g/mol
use:
mass of PbI2,
m = number of mol * molar mass
= 4.5*10^-2 mol * 4.61*10^2 g/mol
= 20.75 g
Answer: 20.8 g
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