The standard enthalpy of formation (ΔH∘f) is the enthalpy change that occurs when exactly 1 mol of a compound is formed from its constituent elements under standard conditions. The standard conditions are 1 atm pressure, a temperature of 25 ∘C , and all the species present at a concentration of 1 M . A "standard enthalpies of formation table" containing ΔH∘f values might look something like this: Substance ΔH∘f H(g) 218 kJ/mol H2(g) 0 kJ/mol Ba(s) 0 kJ/mol Ba2+(aq) −538.4 kJ/mol C(g) 71 kJ/mol C(s) 0 kJ/mol N(g) 473 kJ/mol O2(g) 0 kJ/mol O(g) 249 kJ/mol S2(g) 129 kJ/mol
What is the balanced chemical equation for the reaction used to calculate ΔH∘f of BaCO3(s)?
If fractional coefficients are required, enter them as a fraction (i.e. 1/3). Indicate the physical states using the abbreviation (s), (l), or (g) for solid, liquid, or gas, respectively without indicating allotropes. Use (aq) for aqueous solution.
BaCO3 (s) ;
balanced chemical equation :
Ba (s) + C (s) + 3/2 O2 (g) ------------> BaCO3 (s)
Explanation :
the standard states of reactants :
Ba (s) , C (s) , O2 (g)
The standard enthalpy of formation (ΔH∘f) is the enthalpy change that occurs when exactly 1 mol of a compound is formed...
The standard heat of formation, ΔH∘f, is defined as the enthalpy change for the formation of one mole of substance from its constituent elements in their standard states. Thus, elements in their standard states have ΔH∘f=0. Heat of formation values can be used to calculate the enthalpy change of any reaction. Consider, for example, the reaction 2NO(g)+O2(g)⇌2NO2(g) with heat of formation values given by the following table: Substance ΔH∘f (kJ/mol) NO(g) 90.2 O2(g) 0 NO2(g) 33.2 Then the standard heat...
Calculate ΔH∘rxn for this reaction using standard enthalpies of formation. (The standard enthalpy of formation of gaseous propane is -103.9 kJ/mol
Enthalpy of Formation
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A scientist measures the standard enthalpy change for the following reaction to be 591.0 kJ : 2H2O(1)—>2H2(g) + O2(g) Based on this value and the standard enthalpies of formation for the other substances, the standard enthalpy of formation of H2O(l) is kJ/mol. A scientist measures the standard enthalpy change for the following reaction to be -2903.4 kJ: 2C2H6(g) + 7 O2(g)—>4CO2(g) + 6 H2O(g) Based on this value and the standard...
Part A - Calculating an Enthalpy of Reaction from Enthalpies of Formation Calculate the enthalpy change for the reaction: 2 H2O2(l) → 2 H2O(l) + O2(g) using enthalpies of formation: ΔH∘f[H2O2]ΔH∘f[H2O]==−187.8 kJ/mol−285.8 kJ/mol Calculate the enthalpy change for the reaction: using enthalpies of formation: Multiple choice answers below: -98.0 kJ -196.0 kJ +98.0 kJ +196.0 kJ
Part A) What is ΔH∘rxn for the following chemical reaction? CO2(g)+2KOH(s)→H2O(g)+K2CO3(s) You can use the following table of standard heats of formation (ΔH∘f) to calculate the enthalpy of the given reaction. Element/ Compound Standard Heat of Formation (kJ/mol) Element/ Compound Standard Heat of Formation (kJ/mol) H(g) 218 N(g) 473 H2(g) 0 O2(g) 0 KOH(s) −424.7 O(g) 249 CO2(g) −393.5 K2CO3(s) −1150kJ C(g) 71 H2O(g) −241.8kJ C(s) 0 HNO3(aq) −206.6 Express the standard enthalpy of reaction to three significant figures and...
1. A scientist measures the standard enthalpy change for the following reaction to be -2913.0 kJ: 2C2H6(g) + 7 O2(g)->4CO2(g) + 6 H2O(g) Based on this value and the standard enthalpies of formation for the other substances, the standard enthalpy of formation of H2O(g) is kJ/mol. 2. A scientist measures the standard enthalpy change for the following reaction to be -138.6 kJ : H2(g) + C2H4(g)->C2H6(g) Based on this value and the standard enthalpies of formation for the other substances, the...
A scientist measures the standard enthalpy change for the following reaction to be -2847.0 kJ: 2C2H6(g) + 7 02(g) —4CO2(g) + 6H2O(g) Based on this value and the standard enthalpies of formation for the other substances, the standard enthalpy of formation of CzH6(g) is kJ/mol. A scientist measures the standard enthalpy change for the following reaction to be -15.0 kJ : Ca(OH)2(aq) + 2 HCl(aq) +CaCl(s) + 2 H20(1) Based on this value and the standard enthalpies of formation for...
What is the standard enthalpy of formation of What is the standard enthalpy of formation of CH 3 CH 2 CH 2 CHO(l)? CH3CH2CH2CHO(l)? 2CH 3 CH 2 CH 2 CHO(l)+5O 2 (g)→8H 2 O(l)+8CO 2 (g); 2CH3CH2CH2CHO(l)+5O2(g)→8H2O(l)+8CO2(g); ΔH°=–4943.6 kJ ΔH°=–4943.6 kJ Substance ΔH° f (kJ/mol) CO 2 (g) -393.5 H 2 O(l) –285.8 a. –245.4 kJ/mol b. +245.4 kJ/mol c. –1792.5 kJ/mol d. –3151.1 kJ/mol e. +3151.1 kJ/mol
A.Using standard heats of formation, calculate the standard enthalpy change for the following reaction. N2(g) + 3H2(g) = 2NH3(g) B.Using standard heats of formation, calculate the standard enthalpy change for the following reaction. CaCO3(s) = CaO(s) + CO2(g) C. A scientist measures the standard enthalpy change for the following reaction to be -2910.6 kJ: 2C2H6(g) + 7 O2(g) = 4CO2(g) + 6 H2O(g) Based on this value and the standard enthalpies of formation for the other substances, the standard enthalpy...
Calculate the standard enthalpy change, ΔH, for the formation of 1 mol of strontium carbonate (the material that gives the red color in fireworks) from its elements. Sr(s) + C(graphite) + 32 O2(g) -----> SrCO3(s) The information available is: (1) Sr(s)+ 12O2(g) ---->SrO(s) DeltaH= -592kj (2) SrO(s) + CO2(g) -----> SrCO3(s) DeltaH= -234kj (3) C(graphite) + O2 (g) ----->CO2 (g) DeltaH= -394kl