balanced reaction is
P4(s) + 6Cl2(g) ---> 4PCl3(l)
given
mass of P4 = 23.3g
molar mass of P4 = 124.895 g/mol
moles of P4 = given mass/molar mass = 23.3g/124.895 g/mol = 0.186 mol
mass of Cl2 =84.8 g
molar mass of Cl2 = 70.9 g/mol
moles of Cl2 = 84.8g/70.9 g/mole = 1.194 mole
According to balanced reaction 1 mole P4 needs 6 moles of Cl2
here 0.186 mols P4 require 6*0.186mol Cl2 = 1.116
but we have 1.194 mol of Cl2 hence Cl2 will be excess
reagent and P4 is the limiting reagent
since limiting reactant is P4,we need to calculate mols of P4 to clculate mol of product
From balanced equation 1mols P4 produce 4 mols PCl3
So 0.186 mols P4 yields 4 * 0.186 = 0.751 mols PCl3
now convert mols to mass
mass of PCl3 = mols of PCl3*molar mass =0.751*137.33 g/mol
= 103.13 g
moles of Cl2 left =
0.187 moles of P4 react with 1.116 moles of Cl2
moles of Cl2 left = 1.194 -1.116 = 0.078 moles
mass of Cl2 unreacted= 0.078 mols*71g/mol = 5.538g
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