
1) H2SO4, HNO, 2) H2SO4 (fuming) 3) Br2, FcBry, 3. Starting with benzene, how would you...
Starting with benzene, how would you synthesize the following
products? You can use any chemical you can find from chapter 7- 13,
or 16-18 to help you in your synthesis. (15 pts, 5 points
each)
3. Starting with benzene, how would you synthesize the following products? You can use any chemical you can find from chapter 7-13, or 16-18 to help you in your synthesis. (15 pts, 5 points each) OH o-bo
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3. Synthesize 1,1-diphenylethylene, starting from benzene. You may use any reagents to complete the synthesis. (10pts.) Retrosynthesis may be helpful.
4. Propose an efficient synthesis of the molecule below starting with benzene. You can use any other reagents you want. NOTE: Some reactions produce ortho- and para-products. It is allowable to just take ONE of the products and use it in the next synthesis or claim it as the final product (we assume that ortho- and para-products can be separated). (3 points) CH2CH2CH Br
Problem #3 Show how you would synthesize ethyl benzoate in good yield starting from benzene. You may use any other reagent necessary
just need wuestion 20 completed all work
20 Starting from benzene or anisole and any other reagent of your choice, design a synthesis for cach of the following compounds. (18 pts) осн. OCH Q --C 21. Predict the products from the Birch reductions shown below. (3 pts) Na, NH C,OH Bonus: (6 pts) Provide a synths for the target molecule using benzene. сон 1 1
Design a synthesis for 1-bromo-4-methyl-2-nitrobenzene using benzene as the starting material. You can handwrite everything. Please show the structures of the intermediates after each step as well as the reagents used. (NOTE: you can NOT use Friedel-Craft alkylation after Nitration.) ALSO, Professor said: ch3Br/FeBr3 --> Br/FeBr2 --> HNO3/H2SO4 OR Br2/FeBr2 -> CheCL/ALCL3 -> HNO3/H2SO4 would NOT work. Hint: need protecting group
7. Synthesis Problem (15 points) Show how you would synthesize 3 of the 4 following compounds in one chemical reaction. You may use any starting material you wish and any organic and inorganic reagents. Clearly indicate which ones you want graded by circling the molecules н, осн, Br ОН
1. Propose a synthesis of the molecule below starting with benzene. You can use any other reagents you want. (2 points) сн.CH, но-с-сн, сH;
Problem #3 Show how you would synthesize the compound represented in the Fischer projection below starting from acetylene. You may use any other reagent necessary. HC-OH HC-OH Extra Credit When treated with hydrogen and a platinum catalyst, an unknown compound X absorbs 5 equivalents of hydrogen to give 7-butylcyclohexane. Treatment of X with an excess of ozone, followed by dimethyl sulfide and water, gives the products shown below. Propose a structure for X.
starting from Benzene, how would you synthesize 2-chloro 4-nitroanaline 4-chloro 2 nitropropylbenzene 1-bromo 2-phenylethane