6) as reaction is spontaneous so delG is - ve#
As liquid is converted to solid so entropy decreases hence delS is also - ve#
As we know delG=delH-TdelS
delG to be - ve delH has to be - ve so del H is - ve#
6. Sodium acetate crystallizes spontaneously at 25°C from a saturated aqueous solution. What are the signs...
Question 16 of 45 Submit FeCl3 has a van't Hoff factor of 3.4. What is the freezing point of an aqueous solution made with 1.71 m FeCl3? (Kf for water is 1.86 °C/m) °C 4 7 5 8 6 9 Question 20 of 45 Submit Determine AGº for the phase change CO2(g) → CO2(aq) at 25°C. AH° = -19.4 kJ/mol AS° = +92.3 J/mol-K kJ/mol (1 4 7 +/- 2 5 8 3 6 9 0 x 100 May 7...
5. Which of the following species is amphiprotic in aqueous solution? (a) CH3NH2 c) NH4 (e) HSO (d) F (b) Н:0" 6, Use Table 15.2 (page 529) to decide whether the species on the left or those on the right are favored by the reaction. a. NH4 (aq) + H2PO4" (aq) # NH3(aq) + HsPO b. HCN (aq) + HS(aq) CN" (aq) +H2S c. HCO +OH CO2 H2S d. Al(H20)6 3+ +OH = Al(H20) s2+ OH 7. The equilibrium constant...
Using enthalpies of formation
(Appendix C), calculate ΔH ° for the following reaction at 25°C.
Also calculate ΔS ° for this reaction from standard entropies at
25°C. Use these values to calculate ΔG ° for the reaction at this
temperature. COCl2(g) + H2O(l ) h CO2(g) + 2HCl(g).
Appendix C Thermodynamic Quantities for Substances and Ions at 25°C Substance or lon AH; (kW/mol) 0 AG: (kJ/mol) 0 S° (J/mol-K) 20.87 ΔΗ, (kJ/mol) -946.3 - 33422 AG; {kj/mol) --859,3 -2793 (J/mol-K)...
53) A buffer solution contains carbonic acid (H CO) and sodium bi carbonate (NaHCO), each at a concentration of 0.100 M. The relevant equilibrium is shown below. What is H:COs(ag)+ HOo (a)+HCOs (ag) K.-4.5x 10 54) At 40 C, the pH of water is 6.77, what is lon-Prodact Constant for Water, Kw.at 40°C 55) If a solution of acetic acid has a pH-2.74 and a pK474, wh in the solution? Show your calculations is the ratio of (CH Co/ICOH) 56)...
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QUESTION 2 Calculate the pOH of a solution at 25.0°C that contains 2.95 x 10-12 M hydronium ions. 2.95 O 11.53 12.00 O 7.00 2.47 QUESTION 1 An aqueous solution at 25.0°C contains [H') -0,085 M. What is the pH of the solution? O 13.0 O 0.9850 O 1.07 O 1.20 10-13 O -1.07 QUESTION 2 10-12 M hydronium ions. Calculate the pOH of a solution at 25.0°C that...
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A4 The molecular dipole vector is the sum of bond polarities and indicates the direction and extent of polarity on a molecule, the vector arrow points from the net negative domain towards the net positive domain. Identify which ONE of the following molecules has the molecule polarity correctly indicated by the dipole vector H H H H H H H H H H H (A) (B) (C) H H H H H (D) (E) A8 When a...
Food and beverage containers are commonly made of tin, steel, aluminum, or a combination of metals. Suppose that a laboratory procedure requires a can be made of aluminum. Which property can be used to determine if a can is likely to be made of aluminum? O color Odensity volume mass What is the density of a pear that occupies 32 cm and has a mass of 42 g O 0.7619 g-cm 0 2.0 g.cm O 1.3125 g-cm O 0.76 g.cm...
What results when a secondary alcohol is oxidized? a. a ketone d. an acid b. an amine e. no reaction c. an aldehyde Which of the following combinations will react spontaneously? A. 12 + Cu2+ B. Pb2+ + Ag C. Zn2+ + Mg D. Sn2+ + Ni2+ The general formula for a cycloalkane can be represented by which of the following? a. C,H, C. CH b. C.H2n+2 d. C.H21-2 In a certain reaction AH =-136 kJ and E, = 96...