6. Intramolecular dehydration to form a cyclic monoester is most likely to occur when which of...
11. Identify the product(s) of the following reaction. A. I B. II C. III D. IV E. V Gom Do is a From co be on) porno porno olyan 12. What is the final product obtained when toluene is subjected to the following reaction sequence? i) Clz (large excess), heat, hv; ii) OH-/H20, heat; iii) H30+ A. I OH B. II OH COH C. III U OH D. IV E. V I II Hol YCC, III HOCCI3 C/ стон с...
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6. (1 pts) Which of the following charged compounds is most stable AB.C.D or E? А В C Е 7. (1 pts) Which resonance structures contributes most to the resonance hybrid AB.D or D? A В C D (2 pts) Circle the conjugate base and underline the acid 8. н н 9. (2 pts) Circle the base and underline the conjugate acid он но
4. Circle out of the following which is not a reducing sugar? А. НОНС с. НОНС ОН. OCH3 H3CO НО ОН ОН ОН ОН D. В. НОН,С НОНС ОН ОН HO HO OCH ОН ОН OCH3 5. Provide the product of the following reaction Н. А. Н. -он Br2 , НО но -H pH = 6 НО -Н Но -H CH2OH
Which is the major product of this reaction? CN 1. Et MgBr 2. acid workup our order on one A B C D A B С D Which compound is a D-isomer? Н. Н. T НО- -Н НО——н НО -Н Н——он Но——Н НО- H -Н он І Н. -он H- -он НО -Н НО -Н CH2OH НО- Н -ОН НО -Н СН2ОН Н. -он НОН Сньон CH OH А B с D OA B Ос D
For each pair of species, predict which is the stronger base? 5. Он or 1. 2. or В в NH NH (a) (b) 6. Rank the following from most stable to least stable. 2. 3. 4. Нас Н-с O H -н CH H CH,сH, сн,сн CH,CH 7. Which cation would be the most stable? А. В. C. D. What is the order of increasing contribution to the resonance hybrid? 8. CF3 ÇF3 CF3 I II III
Q:
which structure beat represents the following disubstituted
cuclohexane?
Q: which fisher projection corresponds with the following
molecule?
8. Whien structure best represents the foliowing disubstituted cyclohexane? Cн CHs H. нс нс CH CHs II d. I V a. b. III е. IV с. 9. Which of the following molecules has the highest melting point? но IV Ш I п d. II III a. e. b. IV I с. 10. Which Fischer projection corresponds with the following molecule? Br HO...
Provide the product for the following reaction І. Br HOCH,CH,OH Mg/ether H2SO, Н,0° 2. H,0 но он ОН он IV он у Predict the product of the following synthesis. 1. Br2, H20 2. NaOH, HO 3. CH2OH, H+ OCH, н,со OCH, A B с OCH OCH OCH, D E Predict the product for the following reaction. OH Acid Catalyst + 25 °C O А D с B
For each pair of species, predict which is the stronger base? 5. Он or 2. or HH 1. NH NH (b) 6. Rank the following from most stable to least stable. 4. 1. 2. 3. Н-с H H Н.с H -H H CH3 CH,сн, CH,сH CH,CH H 7. Which cation would be the most stable? А. В. C. D. What is the order of increasing contribution to the resonance hybrid? 8. CF3 Lnkentn CF3 CF3 Ш II I
Oxidation and Red uction Identification (basic) For each of the reactions depicted below -indicate which form is the oxidize mo lecule and which is the reduced. (6 points) 7-DEHYDROCHOLESTEROL НО H NADPH H NADP pyruvate COO lactate ҫоо но-с н + NAD* CHз C-0NADH+H CHз lactate dehydrogenase CHOLESTEROL но сОо- COO- Succinate Delydrogenase С—н Н—с—н E-FAD E-FADH2 + Н—С Н—с—н СОО- COO- Fumarate Succinate (trans- isomer)
2. Which of the following is most likely a polar covalent bond? Na-C b. Н—Н d. KF а. Са—О е. С—N с.