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5 a) identify the anomeric carbon in the below molecule b) identify the thpe of ring...
is the following sugar an aldose or ketose? why? what carbon
is its anomeric carbon? is this sugar d or l? which structure (a-d)
describes its beta- anomer?
Н CH OH CH2OH CH OH -оон CH2OH ОН о ОН ₂ ООН ОН ОН ОН HO-31 ОН ОН ОН ОН ОН Нота-Н -Н НА-ОН Н -ОН 6CHOH ОН ОН ОН ОН A в D
Consider the following molecule: Circle the anomeric carbon in the following structure and indicate whether it represents the beta or the alpha anomer. Is this sugar a pyranose or a furanose?
5. Glucose can form two different ring structures as shown. Draw a mechanism to show how each is formed (don't worry about the stereochemistry around the anomeric carbon) он CHO HO HO он OH но OH он pyranose form of D-glucose OH CH2OH HO D-glucose HO но он он furanose form of D-glucose
Select all of the descriptions that are accurate for this molecule of glucose CH2OH н с— о, н VH С он н C OH но с H Он it is a hexose it is in the alpha form it is in the beta form it is a furanse it is a pyranose it is a Haworth projection It is a Fischer projection Select all of the descriptions that are accurate for this molecule. CH-он Он Он ОН It is a...
30. Which of the choices below is the enantiomer of D-glucose? сно сно нон HO-EH сно на-он D-glucose Іно-Ен н -он но-Ен EH,OH сно но н-он но -н нон Сн,он но-Ен на-он но -н но-Ен н -он нон CHO но -н н-он но-Ен нон снен CHOH Сн,он 3. Which of the following structures is an a-anomer? Сн,он —о, он o ноноон нонс осн он — о оно сн, он он онон он он он он тон КСн,он y CH, OH...
Carbohydrates 1. Label each of the monosaccharides shown below as a triose, tetrose, pentoso, or hexose. но CH OH HT -он - он Н - ОН но -н но -Н но -н нон сньон он но -н НОН CH OH нон нон нон снон CH OH сон сон H- OH H- -он OH cң, он н-с-он Сн,он снон 2. Label each of the monosaccharides shown above as a ketose or aldose. 3. Identify all of the chiral carbons in the...
12. Circle each anomeric carbon in the sugars below. (2 points) Which of the sugars below is a reducing sugar? (1 point) Which sugar contains a glycosidic linkage? (1 point) CH-OH носно он н и носн,он они нон glucose fructose он Ин Н CH,он нон носно А он нон но/н,он и онон н sucrose 13. Extra credit: What type of enzyme catalyzes phosphate transfer? What type of enzyme usually catalyzes the rearrangement of a molecule? (2 points each)
1. Draw glucose B-D-glucose in a chair form, and circle the anomeric carbon. Why is the anomeric carbon significant? 2. Why is cyclization of sugars important? What does the concept of mutarotation indicate to us about dual roles of monosaccharides? Two part question: 3. Why are monosaccharides most commonly found in pyran and furan ring forms, rather than: A) other ring motifs -(think along the lines of: why NOT 3,4, or 7 membered rings)? B) in their linear form? 4....
Answer for 1a and 1b
1. Below are the cyclic and open-chain structures for glucose and fructose. (6 points total) а) Label each structure as glucose or fructose. (1 pt each, 4 pts) b) Glucose is a(n) and fructose is a(n). (ketose, aldose) (1 pt each, 2 pts) CH,OH -он HOCH ОН HOH н но/сн,он он OH H o=4 нон Но+н н+он н+он CH2OH CH2OH с=0 но-н нон н+он Сн,он
Question 10 0.5 pts Below is the structure of fructose, which numbered carbon is the anomeric carbon? CH2OH HO HO ОН. 2 Н. 31 CH2OH OH H 5 1 o O 6 O 3 O o