Calculate the mass of H2C2O4•2H2O will be required to react with about 16 ml of your potassium permangate solution".
KMnO4 solution = 0.02 Mole / L
As per Reaction shown by you :
2 KMnO4 + 4 H2C2O4
Mn2O3 +8 CO2 + 4 H2O +
K2O
2 moles of KMnO4 reacts with 4 moles of oxalic acid.
(you check reaction provided by you, as per redox reaction between these two : 2 moles of KMnO4 reacts with 5 moles of oxalic acid. )
Calculations :
Moles of KMnO4 involved = (16 ml * 0.02 mol /L ) / (1000 ml /L ) = 3.2*10-4 moles
Since, as Reaction shown by you 2 moles of KMnO4 reacts with 4 moles of oxalic acid,
we will need = 2*3.2*10-4 moles = 6.4*10-4 moles of H2C2O4•2H2O.
Molar mass of H2C2O4•2H2O = 126.08 g / mol
So, mass of H2C2O4•2H2O required = 126 g / mol * 6.4*10-4 mole = 0.08069 g
(You are correct , if you are taking correct reaction into consideration )
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