Given : Ethanol (l) ( 1 g ) + 0.918 kJ
Ethanol ( vapor) ( 1 g)
We have relation, q = n
H vap. -------------------->(1)
Where, q is amount heat transferred to the substance,
n is no. of moles of substance ,
H
vap. is enthalpy of vaporization of substance.
To calculate enthalpy of vaporization we need to calculate no. of moles of ethanol.
We have, No. of moles = Mass / Molar mass
No. of moles of ethanol (n) = 1 g / ( 46.07 g /mol) = 0.021706
mol
Now, put q = 0.918 kJ , n = 0.021706 mol in equation 1, we get
0.918 kJ = 0.021706 mol (
H vap )
(
H vap ) = 0.918 kJ / 0.021706 mol = 42.29 = 42.3 kJ / mol
ANSWER :
H vap of ethanol = 42.3 kJ / mol
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