1:5000 means 1 kg of KMnO4 in 5000 L of the solution.
So in 5000 L of solution, amount of KMnO4= 1 kg
In 1 L of solution, KMnO4= 1/5000= 2 * 10^-4 L = 0.2 gram
5% stock solution means 5 gram of KMnO4 in 100 ml of solution.
0.2 gram = 20 *0.2 = 4 ml of solution .
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