1. (20 pts) Write the structure of the product of each step of these reactions. Be...
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
Predict the products of the following reactions.
I will rate fast. Thank you in advance!
excess NaNH2 THF Br Br H 1. NaNH2 2. CH3CH2Br H2SO4, H20 v MSO. MO H2, Pd/Baso quinoline, CH3OH Na, NH3 Na, NH, 1 equivalent HBr NaNH2 Br (excess) 1. Sia BH, THF 2. H202, NaOH h. HgSO4 H2SO4 H20
In each reaction box, place the best reagent and Conditions from the list below. H C C H Br Br H2, Lindlar catalyst H20, H2SO4, Hgso4 CH3CH2Br HBr 1-equiv BH3/THF HBr 2-equiv CH3CH2CH2Br CH3Br H202/NaOH Br2 1-equiv NaOH NaNH2 Br2 2-equiv
Give the major organic product(s) of the reactions of l-methyl-2-deuteriocyclohexene (D = "H) with the reagents given. Be sure to show all stereoisomers formed, and indicate which isomers are formed in equal and in unequal quantities. CHE 1-methyl-2-deuteriocyclohexene (a) (1) BH, THF: (2) H:03, NaOH, H:0 (b) HBr, AIBN (c) Br, H:0 Give the major organic product(s) of the reactions shown below. Be sure to show all stereoisomers formed, and indicate which isomers are formed in equal and in unequal...
In each reaction box, place the best reagent and conditions from the list below. CH3 HBr CH3Br Br2 H2, Lindlar catalyst bromocyclohexane BH3 THF H202, NaOH, H20 H20, H2SO4 excess NaNH2 CH3CH2Br SOC
write a major product for each of the following reaction,
indicate appropriate stereochemistry
1.(CH3)3COK, (CH3)2COH 2. Brz, cena 2 3. x's NaNH2 ; H20 W 14. HgSO4, H2SO4, H2O ÇI 1. x's NaNH2; H20 * 2. k, NH3, CH3CH2OK 3. KMnO4 , H2SO4, 4 1. B2H, THF; NaOH(aq), H202 2. SOBrą, o 1. H2SO4, A OH 318 , NaNH2 4. H2, Lindlar catalyst 2. HBr, H202 3.(CH3)3COK, (CH3)3COH 4. R-COOH; H30°
First we start with ______________and immediately
add ______________followed by ______________ work up to give the new functional
group ______________. Then treatment
with ______________and ______________will give (syn /
anti) ______________addition to give the
______________(stereochemistry) ______________(functional
group) . The final product can be formed by
adding ______________ .
Br OH P) CH3CH2ONa, CH3CH2OH Q) (CH3)3COK, (CH3)3COH R) NaNH2, NH3 S) Na, NH3 T) H2 A) NBS B) Br2, CCI4 C) Cl2, CCl4 D) HBr E) HBr, ROOR F) H20 G) Hg(OAc)2, NaOH, H20 H) HgSO4, H2O, H2SO4 ) H30workup)...
In each reaction box,
place the best reagent and conditions from the list
below.
In each reaction box, place the best reagent and conditions from the list below. CH3 BH3 THF H20, H2SO4 excess NaNH2 HBr SOCI2 CH3CH2Br H2, Lindlar catalyst H202, NaoH, H20 Br2 bromocyclohexane CH3Br
18. Which sequence of reagents would be expected to accomplish the transformation of 1-butyne shown below? A) 1)H2O/H2SO4, HgSO4 cat.; B) 1)HBr C)1)H2, Lindlar catalyst; D) )HBr, peroxides; E) O 2) H2, Pt 2) H2, Pt; 2) BH3*THF; 2) NaOH; 2) H2O 3) NaOH 3) H202, NaOH 3) H2, Pt
In each reaction box, place the best reagent and conditions from the list below. H CEC-H H2, Lindlar catalyst CH3CH20i H20, H2SO4, HgSO4 CH3C Br2 2-equiv. CH3CH2CH2Cl BH3/THF NaOH HBr 2-equiv. H202/ NaOH HBr 1-equiv. NaNH Br2 1-equiv