Homework Answers
4. Since, the spectroscopic data shows that there are only two
different types of Proton. Both the protons are also singlet. Since
out of four examples only compound B have two
different types of proton and they are singlet as well. Hence, only
B fits to the spectroscopic data. 
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4. Which of the following structures fits the following spectroscopic data. 1H NMR: 1.4 ppm (singlet,...
Which compound corresponds to the following H NMR data? 7.5 ppm, multiplet, 5H 4.8 ppm, singlet,...
Which compound corresponds to the following H NMR data? 7.5 ppm, multiplet, 5H 4.8 ppm, singlet, 2H 3.2 ppm, septet, 1H 1.2 ppm, doublet, 6H Select one: O a. *or
Use the following 1H NMR data to produce structures of these compounds: (a) CH002 PPM (b)...
Use the following 1H NMR data to produce structures
of these compounds:
(a) CH002 PPM (b) C3H CIO - 12 To PPM (c) C,H,Bro PPM (d) C13H1603 1.328, (6H, doublet), 2.138, (3H, singlet), 4.328, (1H, septet), 4-478, (1H, singlet), 7.308, (5H, multiplet),
Propose a structure for C3H5CIO2 that fits the following 1H NMR data: 1H singlet at 11.5...
Propose a structure for C3H5CIO2 that fits the following 1H NMR data: 1H singlet at 11.5 ppm; 1H quartet at 4.4 ppm; 3H doublet at 1.7 ppm
just the circled ones only 8.10 Suggest structures consistent with the following 'H NMR data: a....
just the circled ones only
8.10 Suggest structures consistent with the following 'H NMR data: a. Сно triplet (1.0 ppm, 3H) singlet (2.1 ppm, 3H) quartet (2.4 ppm, 2H) b. С Н.о, triplet (1.2 ppm, 3H) singlet (2.1 ppm, 3H) quartet (4.1 ppm, 2H) усно singlet (2.4 ppm, 3H) multiplet (7.5 ppm, 5H) singlet (1.6 ppm, 6H) singlet (3.1 ppm, 2H) multiplet (7.3 ppm, 5H) 1. Сно, triplet (1.2 ppm, 3H) singlet (2.4 ppm, 3H quartet (4.2 ppm, 2H) ....
7. Which compound below best fits the following spectral data? 8. How many signals would you...
7. Which compound below best fits the following
spectral data?
8. How many signals would you expect to see in the
broadband decoupled C^13 spectra of the following compounds?
9. If a proton gave an NMR signal at 3.2 ppm on a MHz
NMR, what would the chemical shift be of this proton (in ppm) if
the sample was run in 400 MHz NMR?
7. Which compound below best fits the following spectral data? (6 points) H-1 NMR 0.9 ppm...
Which compound matches the following 1H NMR spectrum? singlet 3H singlet 3H PPM A. B. i....
Which compound matches the following 1H NMR spectrum? singlet 3H singlet 3H PPM A. B. i. C D. ОН H Ос B OD ОА
The following spectroscopic data corresponds to an unknown compound with the molecular formula C3H8O. Deduce and...
The following spectroscopic data corresponds to an unknown compound with the molecular formula C3H8O. Deduce and draw the structure of the compound that corresponds to the data. 1H NMR: δ 3.8 (septet, 1H), 3.6 (singlet, 1H), 1.0 (doublet, 6H) ppm. 13C NMR: δ 65, 24 ppm.
7. Which compound below be H-1 NMR 0.9 ppm (quartet fits the following spectral data? (6...
7. Which compound below be H-1 NMR 0.9 ppm (quartet fits the following spectral data? (6 points) 1.2 ppm (sextet 2 hydrogens), 2.1 ppm (triplet, hydrogens), 4.3 ppm (singlet 3 hydrogens) C-13 NMR 5 signals 25 ppr ppm (CH2); 61 ppm: (CH3) 198 Ppm (C). IR strong peak 1735 cm Ignals 25 ppm (CH): 35 ppm (CH2), 46 ppm (CH2); 61 ppm: em Mass Spee parent M+ = 102 Mass Spec paren ou 0 H2 CH3 HjC Holo H3C- CC...
3. Propose structures for compounds that fit the following 1H NMR data: a. C.H.Cl2: 8 1.60...
3. Propose structures for compounds that fit the following 1H NMR data: a. C.H.Cl2: 8 1.60 (doublet, 3H), 2.15 (multiplet, 2H), 3.72 (triplet, 2H), and 4.27 (multiplet, 1H) b. C.H.Br: 8 1.1 (doublet, 6H), 1.9 (multiplet, 1H), and 3.4 (doublet, 2H) c. CH 40:8 0.9 (triplet, 6H), 1.6 (sextet, 4H), and 2.4 (triplet, 4H) d. CsH1002: 8 1.2 (doublet, 6H), 2.0 (singlet, 3H) and 5.0 (septet, 1H)
Propose structures that fit the following formula and NMR data. (a) C3H100 singlet at 2.10 8...
Propose structures that fit the following formula and NMR data. (a) C3H100 singlet at 2.10 8 (3H) doublet at 0.958 (6H) multiplet at 2.43 8 (1H) (b) C10H14 singlet at 1.30 8 (9 H) singlet (broad) at 7.308 (5H) (c) C9H11Br quintet at 2.15 8 (2H) triplet at 2.758 (2H) triplet at 3.38 8 (2H) singlet at 7.22 8 (51) IR spectrum: strong peak near 1720 cm (d) C18H14 O2 Singlet at 2.20 8 (3H) Singlet at 5.08 8 (1H)...
Which compound corresponds to the following H NMR data? 7.5 ppm, multiplet, 5H 4.8 ppm, singlet, 2H 3.2 ppm, septet, 1H 1.2 ppm, doublet, 6H Select one: O a. *or
Use the following 1H NMR data to produce structures
of these compounds:
(a) CH002 PPM (b) C3H CIO - 12 To PPM (c) C,H,Bro PPM (d) C13H1603 1.328, (6H, doublet), 2.138, (3H, singlet), 4.328, (1H, septet), 4-478, (1H, singlet), 7.308, (5H, multiplet),
Propose a structure for C3H5CIO2 that fits the following 1H NMR data: 1H singlet at 11.5 ppm; 1H quartet at 4.4 ppm; 3H doublet at 1.7 ppm
just the circled ones only
8.10 Suggest structures consistent with the following 'H NMR data: a. Сно triplet (1.0 ppm, 3H) singlet (2.1 ppm, 3H) quartet (2.4 ppm, 2H) b. С Н.о, triplet (1.2 ppm, 3H) singlet (2.1 ppm, 3H) quartet (4.1 ppm, 2H) усно singlet (2.4 ppm, 3H) multiplet (7.5 ppm, 5H) singlet (1.6 ppm, 6H) singlet (3.1 ppm, 2H) multiplet (7.3 ppm, 5H) 1. Сно, triplet (1.2 ppm, 3H) singlet (2.4 ppm, 3H quartet (4.2 ppm, 2H) ....
7. Which compound below best fits the following
spectral data?
8. How many signals would you expect to see in the
broadband decoupled C^13 spectra of the following compounds?
9. If a proton gave an NMR signal at 3.2 ppm on a MHz
NMR, what would the chemical shift be of this proton (in ppm) if
the sample was run in 400 MHz NMR?
7. Which compound below best fits the following spectral data? (6 points) H-1 NMR 0.9 ppm...
Which compound matches the following 1H NMR spectrum? singlet 3H singlet 3H PPM A. B. i. C D. ОН H Ос B OD ОА
7. Which compound below be H-1 NMR 0.9 ppm (quartet fits the following spectral data? (6 points) 1.2 ppm (sextet 2 hydrogens), 2.1 ppm (triplet, hydrogens), 4.3 ppm (singlet 3 hydrogens) C-13 NMR 5 signals 25 ppr ppm (CH2); 61 ppm: (CH3) 198 Ppm (C). IR strong peak 1735 cm Ignals 25 ppm (CH): 35 ppm (CH2), 46 ppm (CH2); 61 ppm: em Mass Spee parent M+ = 102 Mass Spec paren ou 0 H2 CH3 HjC Holo H3C- CC...
3. Propose structures for compounds that fit the following 1H NMR data: a. C.H.Cl2: 8 1.60 (doublet, 3H), 2.15 (multiplet, 2H), 3.72 (triplet, 2H), and 4.27 (multiplet, 1H) b. C.H.Br: 8 1.1 (doublet, 6H), 1.9 (multiplet, 1H), and 3.4 (doublet, 2H) c. CH 40:8 0.9 (triplet, 6H), 1.6 (sextet, 4H), and 2.4 (triplet, 4H) d. CsH1002: 8 1.2 (doublet, 6H), 2.0 (singlet, 3H) and 5.0 (septet, 1H)
Propose structures that fit the following formula and NMR data. (a) C3H100 singlet at 2.10 8 (3H) doublet at 0.958 (6H) multiplet at 2.43 8 (1H) (b) C10H14 singlet at 1.30 8 (9 H) singlet (broad) at 7.308 (5H) (c) C9H11Br quintet at 2.15 8 (2H) triplet at 2.758 (2H) triplet at 3.38 8 (2H) singlet at 7.22 8 (51) IR spectrum: strong peak near 1720 cm (d) C18H14 O2 Singlet at 2.20 8 (3H) Singlet at 5.08 8 (1H)...
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