

Explanation: Reaction of alkene with H+, H2O produces more substituted alcohol as product. Reaction of alcohol with HBr gives SN1 substitution reaction and produces tertiary alkyl halide as product. Reaction of alkene with peracid produces epoxide as product. opening of epoxide with acetylide ion produces alcohol as product. Reaction of alkene with Cl2, H2O produces halohydrin as product. Dehydration of alcohol with H2SO4 produces alkene as product. t-BuOK is a strong base which abstracts acidic proton gives epoxide as product.
Fill in the missing pieces of the chemical roadmap below. H/HO HBr PhCOOOH Cl2 in H2O...
fill missing reagents
Roadmap Ch.10 #3 xs NaNH Br Br *S HBT Na MIC) 19-BRN 2. 42, ND UD Br₂ HO 12 OW nd OH للر
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5. Fill in the missing structures (products or reagents, including stereochemistry, if relevant) and specify the most likely mechanism (SN1, S2, E1, E2) for formation of the product you have drawn. If a mixture will occur,show the major products. CH,ONa Сн,он нсулснэ H₃C Br HO H2O/acetone H₃C LIOH CH₂ H₂c a DMF 6. For the series shown below, label the most stable alkene, and the least stable alkene. CHE CH, CHE CH, -CH3
Question 20 15 pts OH A) HBr K) Cl2, hv B) NaOH, H2O L) SOCI2 C) CH3COONa, DMF M) LiAIH4, THE D) CH3CH2CH2CH2MgBr, ether N) NaBH4, CH3CH2OH E) CH3CH2MgBr, ether O) CH3CH2OH, H2SO4 F) CH3CH2Li, ether P) CH3CH2ONa, CH2OH G) CrO2, H2SO4, H2O Q) H30+ H) PCC, CH2Cl2 R) PBr3 1) Bre, hv S) H2, Pd J) heat T) CH2CH2CH2CH2OH, hea U) H20, H2SO4 Look at the given synthesis and the provided reagents. Fill in the blanks with the single...
4. Fill in the missing reactant(s), reagents, or product. a cl AICI: H2NNH2, NaOH, heat 1. V 2. H2O SO3 Cl2, FeCl3 H2SO4 Bry, FeBrz H2CrO4, heat oire . on . moto - good OH HCI heat OH 1) NaOH 2) H .3 obrane + HO OOO Y + NH3 => sem HCI, H2O wom zoud
Fill in the missing products in each synthesis
7 7 H2O H-5O or PCC MgBe 1) Ph OCH, 1) 7 2) HO, NaOH
Question 3 (20 points) – Fill in the missing reagent, reactant, or product V 1) CH,CVAICI, 2) KMnO4/H2SO4 3 SOCI, CI(3 eq) FeCl2 1) (CH2CH2),Culi 2) H,O/H3O+ Michael Acceptor PCC i. 1) KOC(CH):/HOC(CH): 2) mCPBA الد 3) CH,MgBr 4) H2O/HO* NH A 1) NH, TH,SO4 (cat.) 2) NADH 1) 2) 3)
Fill in missing reactants and
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HO OH 1. Os04 2. NaHSO3(aq) 1. Hg(OAc)2, H20 2. NaBH4 Na NH3 (1) Br. Br X.s. Br2 V B CC14 1. NaNH2 2. EtCI correct SCH I, CH,SH RISCH3 analogy to Bra, H₂O dil. H2SO4 HO
fill the blanks for reactants,conditions or products
1. BH3 2. H2O2, HO H3C Br2, H2O =CH₂ 7. H₂C NaNH2 CH3CH2-CEC-H CH3CH2Br
(10 pts) Fill in the missing intermediates (two), final product, and reagents (two) in the llowing multistep synthesis. Br X OH -- NH 에 CH,Br 6) (5 pts) Write out the 3-step arrow pushing mechanism showing how cyclopentanol is dehydrated to make cyclopentene: он conc. H,SO + HO heat
OH Fill in the following reaction scheme based on the Roman numerals provided below: но H OH HO HO-H Step 1 HO-H Step 2 H H-OH H OH HOH HOH Step 3 HOH нон но-н HO-H CH, OH CH, OH CH, OH cal HCI HCN HIO NH, OH NaBH но EROH IV V NaOCH PdBaso H,09 BE HO VII cat HCI CH,OH VIII VI XI X HO, HNO, H.O heat XI Fe (50 XII BnB Nah DMF heat XIII ....