1) When 0.519 mol of HCOOH is dissolved in 0.409 L of water, proton transfer occurs.
HCOOH + H2O ⇄HCOO- + H3O+
The equilibrium concentration of H3O+ ions is 0.0149 M. Evaluate Keq.
Initial concentration of HCOOH = mol of HCOOH / volume in L
= 0.519 mol / 0.409 L
= 1.27 M
HCOOH + H2O <-> HCOO- + H3O+
1.27 0 0 (initial)
1.27-x x x (at equilibrium)
Given at equilibrium,
[H3O+] = 0.0149 M
So,
x = 0.0149 M
Use:
Keq = [HCOO-][H3O+] / [HCOOH]
= x*x / (1.27-x)
= (0.0149* 0.0149) / (1.27-0.0149)
= 1.77*10^-4
Answer: 1.77*10^-4
1) When 0.519 mol of HCOOH is dissolved in 0.409 L of water, proton transfer occurs....
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