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10.44 ( For the alkynes shows below, show the product(s) expected to form when treated under...
Practice Worksheer 8: Alkynes 4. Draw the major product for each transformation. Draw the major regioisomer and ster...
Practice Worksheer 8: Alkynes 4. Draw the major product for each transformation. Draw the major regioisomer and sterosome where appropriate. CI, CHCI HgSO4, H,SO a. B He, diglyme b, HD, NaOH H2 (excess), Pd/C CHE Hz (excess), Pd/CaCO3 quinoline, Pb(OAC) CH₃ Na”, NH3(1), -196 °C Page 3 of 4
9.44 (•) Determine whether the following reactions are redox reactions. If they are, identify whether the...
9.44 (•) Determine whether the following reactions are redox reactions. If they are, identify whether the molecule has been oxidized or reduced. (a) (b) ý modo de volg Br2, heat + HO og sm. .- Br + H-Br (c) H2SO4 t o H2SO4 , .- CH3 NaBHA CH2OH OH OH - OH .PY OH + BH3 o-Na 9.45 (•) Predict the product(s) that would result when the alkenes are allowed to react under the following conditions: i) Bra; ii) Cl2;...
In each reaction box, place the best reagent and Conditions from the list below. H C...
In each reaction box, place the best reagent and Conditions from the list below. H C C H Br Br H2, Lindlar catalyst H20, H2SO4, Hgso4 CH3CH2Br HBr 1-equiv BH3/THF HBr 2-equiv CH3CH2CH2Br CH3Br H202/NaOH Br2 1-equiv NaOH NaNH2 Br2 2-equiv
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary HBr Br2 CH2Cl2 HBr...
Provide the major product(s) for the following reactions: Show
Stereochemistry when necessary
HBr Br2 CH2Cl2 HBr Br2 ROOR H20 H2O СН,ОН H30* 1) BH3, THE 2) H2O2, NaOH, H2O 1) Hg(O2CCF3)2 CH3OH 2) NaBH4, NaOH 1) Hg(OAc)2, H20, THF 2) NaBH4, NaOH H2 Pd/C
Question 9.27, 9.30 Choose one reagent from the Table to carry out the following conversions. Use...
Question 9.27, 9.30 Choose one reagent from the Table to carry out the following conversions. Use letters from the table to specify reagents. Reagents КMnO,/ Н,о* O3 d 1. Br2 g a 2. KOH in ethanol H2/ Lindlar catalyst hr H20/ H2SO4/ HgSO4 е 1. NaNH2 in NH3 2. CH3Br Li in NH3 1 equiv Br2 f 1. BH3 in THF C 2. H202 in NaOH a) CHACH,сH,сH,CECH CHн-CH-CH-CH2CH-CH CHз b) сHa-CHa-CEс-сн, CH3CH2 The following synthesis requires more than one...
Predict the major organic product or products of each of the following reactions: Identify the mechanism...
Predict the major organic product
or products of each of the following reactions:
Identify the mechanism
taking place in each of the reactions and please provide
explanation.
H2SO4 a) (CHỊ) CH CH=CH, HO Hg(OAc)2 NaBH4 b) (CH3)2CH CH=CH2 H2O BH3: THE H2O2, NaOH c) (CH3),CH CH=CH2 H2SO4, H2O d) CHCECH HgSO4 HZ/Ni f) + Cl2 + H2O g) Cold KMnO4 dilute h) 1. CH CO-OH 2. Hz0 Br2 i) CC14
5. Reaction Trees - For each of the branches below, show the possible products and indicate...
5. Reaction Trees - For each of the branches below, show the possible products and indicate the major products (if any) Bonus: earn 1 point for naming any of the correctly predicted products. OH Na, NH3, -78 deg C H2O H2SO4 HgSO4 NaNH2 CEC-H H2 Lindlar's catalyst 1. disiamylborane 2. H2O, HO, H2O2 H2/Pt C HCITED ni more See SOMOS
First we start with ______________and immediately add ______________followed by ______________ work up to give the new functional...
First we start with ______________and immediately
add ______________followed by ______________ work up to give the new functional
group ______________. Then treatment
with ______________and ______________will give (syn /
anti) ______________addition to give the
______________(stereochemistry) ______________(functional
group) . The final product can be formed by
adding ______________ .
Br OH P) CH3CH2ONa, CH3CH2OH Q) (CH3)3COK, (CH3)3COH R) NaNH2, NH3 S) Na, NH3 T) H2 A) NBS B) Br2, CCI4 C) Cl2, CCl4 D) HBr E) HBr, ROOR F) H20 G) Hg(OAc)2, NaOH, H20 H) HgSO4, H2O, H2SO4 ) H30workup)...
not real sure how to do H or K Product(s) Reactants/conditions a. H2,Pt H2/Pd/BaSO4, quinoline Na/NH3...
not real sure how to do H or K
Product(s) Reactants/conditions a. H2,Pt H2/Pd/BaSO4, quinoline Na/NH3 b. 2 eq, HCI H2SO4, HgSO4, H2O 1 eq, Cl2 2 eq. Cl2 1. NANH2 2. CH3CH2Br YR h. 1. Sia2BH/THF i. 2. H2O2/OH j. KMnO4, H2O KMnO4, NAOH NANH2, NH3 H2, Pd H2/Pd/BaSO4, quinoline k. I. m. n. Na/NH3 о. 2 eq, HCI p.
Give the missing reagent(s). Due 11/22/19 Give the missing reagent(s). CH3 Пон CH3 ОН CH3 он...
Give the missing reagent(s).
Due 11/22/19 Give the missing reagent(s). CH3 Пон CH3 ОН CH3 он он CH3 пон lot Matching: ACH, инно он CH3 пон "HOH Matching: H2SO4, H20 1) BH3.THF 2) H2O2, OH-1 C2 1) Br2, H2O 2) NaH KMnO4 Cold, Dilute,Basic HCl 1) Hg(OAc)2, H2O 2) NaBH4, OH! H2O, H2SO4 mCPBA 1) mCPBA 2) H:07 H2 1) OsO4 2) NaHSO3 (1) O₃ 2) (CH3)2S Na, Liquid NH; | 1) mCPBA 2) H2O, OH"! Lindlar's Catalyst
Practice Worksheer 8: Alkynes 4. Draw the major product for each transformation. Draw the major regioisomer and sterosome where appropriate. CI, CHCI HgSO4, H,SO a. B He, diglyme b, HD, NaOH H2 (excess), Pd/C CHE Hz (excess), Pd/CaCO3 quinoline, Pb(OAC) CH₃ Na”, NH3(1), -196 °C Page 3 of 4
9.44 (•) Determine whether the following reactions are redox reactions. If they are, identify whether the molecule has been oxidized or reduced. (a) (b) ý modo de volg Br2, heat + HO og sm. .- Br + H-Br (c) H2SO4 t o H2SO4 , .- CH3 NaBHA CH2OH OH OH - OH .PY OH + BH3 o-Na 9.45 (•) Predict the product(s) that would result when the alkenes are allowed to react under the following conditions: i) Bra; ii) Cl2;...
In each reaction box, place the best reagent and Conditions from the list below. H C C H Br Br H2, Lindlar catalyst H20, H2SO4, Hgso4 CH3CH2Br HBr 1-equiv BH3/THF HBr 2-equiv CH3CH2CH2Br CH3Br H202/NaOH Br2 1-equiv NaOH NaNH2 Br2 2-equiv
Provide the major product(s) for the following reactions: Show
Stereochemistry when necessary
HBr Br2 CH2Cl2 HBr Br2 ROOR H20 H2O СН,ОН H30* 1) BH3, THE 2) H2O2, NaOH, H2O 1) Hg(O2CCF3)2 CH3OH 2) NaBH4, NaOH 1) Hg(OAc)2, H20, THF 2) NaBH4, NaOH H2 Pd/C
Question 9.27, 9.30 Choose one reagent from the Table to carry out the following conversions. Use letters from the table to specify reagents. Reagents КMnO,/ Н,о* O3 d 1. Br2 g a 2. KOH in ethanol H2/ Lindlar catalyst hr H20/ H2SO4/ HgSO4 е 1. NaNH2 in NH3 2. CH3Br Li in NH3 1 equiv Br2 f 1. BH3 in THF C 2. H202 in NaOH a) CHACH,сH,сH,CECH CHн-CH-CH-CH2CH-CH CHз b) сHa-CHa-CEс-сн, CH3CH2 The following synthesis requires more than one...
Predict the major organic product
or products of each of the following reactions:
Identify the mechanism
taking place in each of the reactions and please provide
explanation.
H2SO4 a) (CHỊ) CH CH=CH, HO Hg(OAc)2 NaBH4 b) (CH3)2CH CH=CH2 H2O BH3: THE H2O2, NaOH c) (CH3),CH CH=CH2 H2SO4, H2O d) CHCECH HgSO4 HZ/Ni f) + Cl2 + H2O g) Cold KMnO4 dilute h) 1. CH CO-OH 2. Hz0 Br2 i) CC14
5. Reaction Trees - For each of the branches below, show the possible products and indicate the major products (if any) Bonus: earn 1 point for naming any of the correctly predicted products. OH Na, NH3, -78 deg C H2O H2SO4 HgSO4 NaNH2 CEC-H H2 Lindlar's catalyst 1. disiamylborane 2. H2O, HO, H2O2 H2/Pt C HCITED ni more See SOMOS
First we start with ______________and immediately
add ______________followed by ______________ work up to give the new functional
group ______________. Then treatment
with ______________and ______________will give (syn /
anti) ______________addition to give the
______________(stereochemistry) ______________(functional
group) . The final product can be formed by
adding ______________ .
Br OH P) CH3CH2ONa, CH3CH2OH Q) (CH3)3COK, (CH3)3COH R) NaNH2, NH3 S) Na, NH3 T) H2 A) NBS B) Br2, CCI4 C) Cl2, CCl4 D) HBr E) HBr, ROOR F) H20 G) Hg(OAc)2, NaOH, H20 H) HgSO4, H2O, H2SO4 ) H30workup)...
not real sure how to do H or K
Product(s) Reactants/conditions a. H2,Pt H2/Pd/BaSO4, quinoline Na/NH3 b. 2 eq, HCI H2SO4, HgSO4, H2O 1 eq, Cl2 2 eq. Cl2 1. NANH2 2. CH3CH2Br YR h. 1. Sia2BH/THF i. 2. H2O2/OH j. KMnO4, H2O KMnO4, NAOH NANH2, NH3 H2, Pd H2/Pd/BaSO4, quinoline k. I. m. n. Na/NH3 о. 2 eq, HCI p.
Give the missing reagent(s).
Due 11/22/19 Give the missing reagent(s). CH3 Пон CH3 ОН CH3 он он CH3 пон lot Matching: ACH, инно он CH3 пон "HOH Matching: H2SO4, H20 1) BH3.THF 2) H2O2, OH-1 C2 1) Br2, H2O 2) NaH KMnO4 Cold, Dilute,Basic HCl 1) Hg(OAc)2, H2O 2) NaBH4, OH! H2O, H2SO4 mCPBA 1) mCPBA 2) H:07 H2 1) OsO4 2) NaHSO3 (1) O₃ 2) (CH3)2S Na, Liquid NH; | 1) mCPBA 2) H2O, OH"! Lindlar's Catalyst
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