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Please show the mechanism and final produxts flr rhe folllwing
reactions:
1. LDA, THE Br, CH;CO2H...
B2 CH3COOH 1.NaOEt, EtOH, 25c add base to ketone 2. CHA CHA M ELAT.782 1. LDA,...
B2 CH3COOH 1.NaOEt, EtOH, 25c add base to ketone 2. CHA CHA M ELAT.782 1. LDA, THE, -78C LDA, THE B ~ 3. LDA, THE Br CI2, KOH
2) CHs LDA 1) LDA 3 2) Ci OH, H20 -OH, H2O CHO 1 LDA 2)...
2) CHs LDA 1) LDA 3 2) Ci OH, H20 -OH, H2O CHO 1 LDA 2) CH3CH2Br Он, H2O 1) NaOEt 8 2) NaOEt OEt 10 Cl NaH 2 (excess) 12 HO Bra(excess) 13 HO LDA 14L THF, -78 C NaOEt, EtOH NaOEt, EtOH 16 NaOEt, EtOH 17 Br но 18 OOEt 1)NaOEt, EtOH 2) H3O 19 OEt 20 l HO o CHO + H20
Bra CH,COOH CIL, KOH 1. NaOEt, EtOH 2. (CH3)2CHCHI మండము 1. LDA, THF,-780 Br i NADE, EIGH NaOEt, EtOH
Bra CH,COOH CIL, KOH 1. NaOEt, EtOH 2. (CH3)2CHCHI మండము 1. LDA, THF,-780 Br i NADE, EIGH NaOEt, EtOH
Please show a clear mechanism. 7.) What is the mechanism and main product for the following series of reactions? (4...
Please show a clear mechanism.
7.) What is the mechanism and main product for the following series of reactions? (4 points) (Spring '18) 0 0 0 1.) CH-CH20 Na* 2.) HCI 3.) 5 x LDA 4.) 4x Br 5.) excess H,0', A
3. Give the major organic product(s) of each of the following reactions or sequences of reactions....
3. Give the major organic product(s) of each of the following reactions or sequences of reactions. Br2 CH3COOH OH 1. Bry, PB 2. H2O CH, III 13, NaOH (excess) HC-C-C- CH H20 CH; 1.2 equiv. NaOet, EtOH VOE2.AAB O= OE: + (CH),CHCHCH,Br 1. NOE! EtOH 2.H20, heat
Fill in the missing information. OEI NOE EIO H,0 ELOH Heat 1. LDA, THE 2.CH,! NH(CH),...
Fill in the missing information. OEI NOE EIO H,0 ELOH Heat 1. LDA, THE 2.CH,! NH(CH), H 1. 2. H,07 NaOEt, EtOH ** Know how to do all Review of Reaction reactions. (Reagents, reactant categories, product categories). **
pls do B to P thanks HCFO AIC Br CH O A (Substitution) NO 1) LDA...
pls do B to P thanks
HCFO AIC Br CH O A (Substitution) NO 1) LDA 2) H,о* 1) NaOh 2) 3) H5o', A 2) нCL H,о H then H.O EIMgBr H 1) Eto 2) но", А EtO OEt CN NaH J Br LDA/THF K -78 °C Br LDATHF L 0°C Br S H2 Raney Ni M 1) CF COOOH 2) LIAIH N Ph.PECHCH ETOH P HCI
HCFO AIC Br CH O A (Substitution) NO 1) LDA 2) H,о* 1)...
1. NaOEt CO2Et 2. H30+ 3. heat Br. Br CORET + H3C V CO2H H₂C +...
1. NaOEt CO2Et 2. H30+ 3. heat Br. Br CORET + H3C V CO2H H₂C + CO2 + E H3C CO2Et The malonic ester synthesis is a carbonyl alkylation reaction. It is used to prepare carboxylic acids from primary alkyl halides, lengthening the carbon In progress by two atoms. Thus, the product can be visualized as being a "substituted acetic acid." The reaction consists of three steps: generation of the enolate anion followed by SN 2 reaction with a primary...
Provide the major product for the following reactions: b. NaH, THF CH Br 1.1 eq LDA,...
Provide the major product for the following reactions:
b. NaH, THF CH Br 1.1 eq LDA, THF D O NaOD 1. LDA (1.1 eq) 2. CH2CH 3. LDA (1.1 eq, -78 °C) 4. CH 1 equiv. Br2 NaOH, H2O
1) LDA 2) CH,Br c)
1) LDA 2) CH,Br c)
B2 CH3COOH 1.NaOEt, EtOH, 25c add base to ketone 2. CHA CHA M ELAT.782 1. LDA, THE, -78C LDA, THE B ~ 3. LDA, THE Br CI2, KOH
2) CHs LDA 1) LDA 3 2) Ci OH, H20 -OH, H2O CHO 1 LDA 2) CH3CH2Br Он, H2O 1) NaOEt 8 2) NaOEt OEt 10 Cl NaH 2 (excess) 12 HO Bra(excess) 13 HO LDA 14L THF, -78 C NaOEt, EtOH NaOEt, EtOH 16 NaOEt, EtOH 17 Br но 18 OOEt 1)NaOEt, EtOH 2) H3O 19 OEt 20 l HO o CHO + H20
Bra CH,COOH CIL, KOH 1. NaOEt, EtOH 2. (CH3)2CHCHI మండము 1. LDA, THF,-780 Br i NADE, EIGH NaOEt, EtOH
Please show a clear mechanism.
7.) What is the mechanism and main product for the following series of reactions? (4 points) (Spring '18) 0 0 0 1.) CH-CH20 Na* 2.) HCI 3.) 5 x LDA 4.) 4x Br 5.) excess H,0', A
3. Give the major organic product(s) of each of the following reactions or sequences of reactions. Br2 CH3COOH OH 1. Bry, PB 2. H2O CH, III 13, NaOH (excess) HC-C-C- CH H20 CH; 1.2 equiv. NaOet, EtOH VOE2.AAB O= OE: + (CH),CHCHCH,Br 1. NOE! EtOH 2.H20, heat
Fill in the missing information. OEI NOE EIO H,0 ELOH Heat 1. LDA, THE 2.CH,! NH(CH), H 1. 2. H,07 NaOEt, EtOH ** Know how to do all Review of Reaction reactions. (Reagents, reactant categories, product categories). **
pls do B to P thanks
HCFO AIC Br CH O A (Substitution) NO 1) LDA 2) H,о* 1) NaOh 2) 3) H5o', A 2) нCL H,о H then H.O EIMgBr H 1) Eto 2) но", А EtO OEt CN NaH J Br LDA/THF K -78 °C Br LDATHF L 0°C Br S H2 Raney Ni M 1) CF COOOH 2) LIAIH N Ph.PECHCH ETOH P HCI
HCFO AIC Br CH O A (Substitution) NO 1) LDA 2) H,о* 1)...
1. NaOEt CO2Et 2. H30+ 3. heat Br. Br CORET + H3C V CO2H H₂C + CO2 + E H3C CO2Et The malonic ester synthesis is a carbonyl alkylation reaction. It is used to prepare carboxylic acids from primary alkyl halides, lengthening the carbon In progress by two atoms. Thus, the product can be visualized as being a "substituted acetic acid." The reaction consists of three steps: generation of the enolate anion followed by SN 2 reaction with a primary...
Provide the major product for the following reactions:
b. NaH, THF CH Br 1.1 eq LDA, THF D O NaOD 1. LDA (1.1 eq) 2. CH2CH 3. LDA (1.1 eq, -78 °C) 4. CH 1 equiv. Br2 NaOH, H2O
1) LDA 2) CH,Br c)
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