
2) Fill in each of the following boxes with the structure of the major reaction product...
2) Fill in each of the following boxes with the structure of the major reaction product(s) from each of the following reactions. (28 points total). a) Pd(PPhale NaOH b) + Pd(OA) (CH CHN CN 1. NaBH 2. H2O HH OH но -н H- OH HH OH CH,OH HNO, но NH,OH trace of acid 1. CHI (excess 2. Ag,0 H2O, heat CI 1 CRUS POY Grubbs catalyst) Page 2 of 5
i need help with b,e, and f please!
2) Fill in each of the following boxes with the structure of the major reaction product(s) from each of the following reactions. If you believe that no reaction will take place, write NR in the box (28 points total) BO PSPP) NaOH Pd OA) (CH.CH N.R. bi OCH Brin Ho CO2H H OH HFoH MOCOH нон CH OH CH₂OH H OH CO2H НО 애 Coat сно на H OH HO+H H- OH...
Draw the structure of the one major product expected for each
of the following reactions. Indicate stereochemistry where
applicable
Chemistry 2310 Ch 8 and 10 Test-Addition Reactions of Alkenes and Intro to Radicals 1.) BH3 Br. k) PhCO3H 1.) O 2.) DMS Ni H3C n) HO 1.) H2SO4 heat 2.) Br2 1.) Br2, light 2.) NaOEt 3.) Ch. H2O o) 1.) Cl2, light 2.) NaOEt 3.) Os followed by DMS p) 1.) BH3 THF followed by H202/HO 2.) TsCl, pyridine...
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) Ç(CH3) 30 1) PhČCI, AICI: 11. 2) Et2NH, H2, Raney-Ni, heat 12. ÇO,Me 1) EtMgBr (2 equiv.) 2) H20, H30* O 13. CNH2 1) Bry, NaOH, H,0 O 2) (CH3)2CHCCI, pyridine 14. Brą, H20 CHO HOEH H HOH НЕОН HO+H CH OH 15. H2N. ***** оо CO2 1) (CH3),COCOCOC(CH3)3 2) -N: C: NH- 16. CHO нон PhNHNH2 H+OH (3 equiv.)...
Give the structure of the major organic product(s) for each if
the following reactions (or reaction sequences). Show all hydrogens
when they are critical, e.g. for aldehydes
3. Give the structure of the major organic product(s) for each of the following reactions (or reaction sequences). Show all hydrogens when they are critical, e.g. for aldehydes. Hot 3 O + Brz Born b. 2 8Hz WH2 + CH₃ CH-C-0H - So A 70 DE CH2 Br 0 Hz cat per B...
2. Give the structure of the major organic product for each step in the following reaction sequences. 1. LAH POC 2 HO CH.CH Zn(Hig) FeBr. HOI heat KOH, heat H,SO 1. BH-THE 1. CH,Mgi 2. H,0* heat 2.H.O., NaOH TSCI pyridine Nal NaCN EROH-H,0 aantone CH,ON Nacro, H,SO, H,0 CH, OH
2) What is the product of the following reactions [8 Points) HO 1) NaOH 2)CH2Li 3)H+, H20 OH 1) CH3I (Excess) 2) Ag20 3) Heat 1) LDA 2) CH2Br
Draw the major product of the following reaction that begins with a retro-aldol, followed by an intramolecular aldol condensation. (5 points) OH OH C7H100 H20 heat Create OscerSketch Answer 6 Determine and draw the structures of compounds A and B only. Do not draw the structure of compound X. Place each structure above its letter. HINT: Both A and B are esters. (10 points) LDA 1. compound B 1. NaOEt O= O= A Х -78 °C 2. H30* OEt 2....
organic
III. Predict the major product(s) or fill in the reagent(s) for the following reactions. If there is no reaction write NR. (6 points each, 36 points total) Show the correct stereochemistry when needed!! 16 HO H,Cro (excess) -CHO 17 1)0, (2 equiv.) 2) Mezs (2 equiv.) 18 Ph Ph он om Ph Ph 19 1) mCPBA 2) EtONa, EtOH 20 1) LIAIH (excess) 2) H20*, ,0+ 21 1) NaNH, 2) CH,Br 3) HBr (2 equiv.)
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) Ç(CH3)3 o 11. 1) PhČCI, AICI 2) EtANH, H2, Raney-Ni, heat 12. ÇO Me 1) EtMgBr (2 equiv.) 2) H20, H30* 13. o CNH2 1) Brą, NaOH, H20 o 2) (CH3)2CHCCI, pyridine 14. CHO HO+H H-OH Br2, H20 H-HOH HO+H CH2OH