Solution:
The option will be K2SO4.
Because K2SO4 reacts with Ca(NO3)2 to form a sparingly soluble salt CaSO4.
Ca(NO3)2 + K2SO4 = CaSO4 + 2KNO3
Ca(NO3)2 is dissociated as,
Ca(NO3)2. = Ca2+ + 2NO3-
4 x 10^-5 M = 4 x 10^-5 M -- 2 x 4 x 10^-5 M
Thus
[Ca2+] = 4 x 10^-5 M
Ksp for CaSO4 = 7.1 x 10^-5 M
Ksp = [Ca2+] [SO4--]
[SO4--] = Ksp / [Ca2+] = 7.1 x 10^-5/4 x10^-5
= 1.775
Thus, [SO4--] = 1.8 M
Therefore,
Solution of K2SO4 must posses concentration of 1.8 M.
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