Question

Identify and mark up the NMR for this ketone. Refractive Index is 14.39 at 22.3 degrees Celsius.

Aldehyde and Ketones 2.70 ppm 2.15 ppm 12 11 10 9 8 7 6 5 4 ppm 3.96 6.00

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Answer #1

The molecule along with the NMR is below .

O PPM

The two peaks indicate the 2.15 ppm peak corresponding to 6 protons and the 2.70 peak corresponds to 4 protons , And , both peaks are singlets . So , no chance of coupling between two dissimilar protons . This is possible with the above mentioned structure . Instead of Sulfur(S) , we could have thought of Oxygen(O) , but due to higher electronegativity , the peaks should have appeared at greater than 3 . Thus , Sulfur is there .

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