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8. For the reaction below dentify the nucleophile and the electro 9. The following reaction can...
which had the weakest bond between its atoms Br2 Cl2 HBr
HCl?
11. A) Calculate the heat of the reaction given the bond dissociation energies. (5 pts) (CHs) C-CI + HCI Cl-CI (CHs) C-H + Give the structure of 3-Methylpentane (3 pts) 12. For the reaction below identify the nucleophile and the electrophile: 8. 9. The following reaction can be classified as a (3 pts) ecid eatalyst d) oxidation a) Addition c) substitution 6) rearrangement atoms?
Classify each of the following organic reactions. Substitution Addition Elimination Type of Reaction Reaction CH3 CH3 CH3-CH=C-CH3 + H20 – CH3-CH2-C-CH3 OH CH3-CH2-CH=CH2 + HCI → CH3-CH2-CH-CH3 CI CH3-CH-CH2-CH3 + CH3-CH=CH-CH3 + HBr Br
1. For the following substitution reaction, please (a) calculate the AHran. (b) is this reaction an exothermic or endothermic process? (5 pts) CHE CH3 H-C-Br + H-O-H + H-Br CHE н-с-он сн. Bond dissociation energies (CH3)2CH-Br 285 kJ/mol (CH),CH-OH 401 kJ/mol H-OH 498 kJ/mol H-Br 368 kJ/mol
2). Consider the following intramolecular S2 reaction. no ♡ + HI A) (5 pts) Use the table of Bond Dissociation Enthalpies (at the back of the exam) to calculate the approximate ΔΗπη. B) (3 pts) Is the reaction endothermic or exothermic? Why? C) (6 pts) Draw the Reaction Energy Coordinate Diagram. Label the axes, reactant(s), product(s), transition state(s), intermediate(s), activation energy, and reaction enthalpy. D) (3 pts) In regards to entropy, would you expect the reaction to be favorable, or...
5.59. The following equations represent (a) an addition reaction, (b) a substitution reaction, (c) an elimination reaction, and (d) a rearrangement. Calculate for each, and compare amongst the various reactions (i) the atom efficiencies for atoms of each element, (ii) the overall atom efficiency, and (iii) the E-factor. In calculating the E-factor, state your assumption about which is the desired product. Br а. Br2 Br Н С. b. Н.С ОН Br H20 HBr Br с. ""CHз CH,CH2O-Na Н.С CH3 CH3...
Which of the following is true for reactions A, B, and C? 8. CH3CH2CH,+ Br CH,CH2CH2 + HBr CH CH2CH, + Br CH CH CH3 + HBr CH CH:CH; + Cl CH,CH-СH, + HCI A C a. Reaction A has the lowest activation energy b. Reaction B is the fastest reaction c. Reaction C has the lowest activation energy d. Reaction C is the slowest reaction 9. Which of the following statements is false? a. The rates of Sy1 reactions...
Problem of the Day 18 1. (10 pts) Consider the following reaction: TO + HBr a. Estimate AH for this reaction (use table 6.1 in your textbook) b. Is AS for this reaction positive or negative? Explain. C. Determine if AG is positive or negative. d. Is the sign of AG (positive or negative) dependent on temperature? Why? TABLE 6.1 BOND DISSOCIATION ENERGIES (AH) OF COMMON BONDS KJ/MOL KCAL/MOL KI/MOL KCAUMO Bonds to H H2C=CH-CH3 HCC-CH3 KJ/MOL KCAL/MOL 385 92...
2. Estimate AH for the reaction below using bond enthalpies: (10 pts) CH2=CH-CH=CH2 + HCI → CH3-CHCI-CHCI-CH, Average Bond Enthalpies in kJ/mol. C=C +839 C-H +413 C-CI +328 H-CI +432
what is the best name for the following compound
6-For the reaction the alcohol product is classified as a CH --Primary Alcohol b-Secondary Alcohol e-Tertiary Alcohol d-Quaternary Alcohol 7-Zaitsev's Rule: When an alkene is produced in an elimination reaction, - The major product is the one with highly substituted double bond. - The major product is the one with less substituted double bond. - The minor product is the one with highly substituted double bond. d-Addition of hydrogen the richest...
the following compound is
9 Which is the major product of the follow CHOCH, OH NaBr ? of the following substitution reaction? D) All of the Above E) None of the Above A) CH₃ CH₂ Br B) CH3CH(Na, c) CH₂-E-H 20 Which is the major product of 5 CHA CH=CH-CH2 HBr ? the following substitution reaction? major product of CHE OH SHA A) CH₂ CH-CH=CH3 CH2 () CH3 C=CH-CH2 B) CH3 C- CH₂ - CH3 D) None of the Above...