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Can you explain with all necessary steps and equations? thank you 6. The reaction 2 H2...
6. The reaction 2 H + 2 NO N ; + 2 H20 may proceed by the following mechanism: 2 NO - N20 (kand k) H + N202 + NO + H2O (kz) H + NO + N2 + H2O (ku). Use the steady-state approximation to predict the rate law for the formation of the product N2.
Please answer each part with work shown. Thank you.
6. The following three mechanisms have been proposed for a particular reaction. Mechanism II Mechanism III Mechanisml H2 +NO-H2O+N (slow) N +NON2+0 (fast) O+H2-> H2O (fast) 2 NO-N202 (fast equilibrium) H2-N202-H20+ N3O (slow) H2+N20-H2O+N2 (fast) H2 + 2 NO- H2O+N2O (slow) N20+ H2N2+ H2O (fast) a) What is the overall reaction that each proposed mechanism supports? b) Calculate the ΔΗ'm for the overall reaction. c) For each mechanism, draw an energy...
2. Consider the reaction below between nitric oxide and hydrogen gas: 2 NO(g) + 2 H2(g) - N2 + 2 H2009) Upon being studied experimentally, it has been determined that the rate law expression for this reaction is first order in Hz and second order in NO(g). With this information in mind, answer the following: [Tip: You can assume that the steady-state approximation is valid for any intermediate here.) a. As written, is the reaction above a valid mechanism? In...
2) A proposed reaction mechanism for nitric oxide, NO, produced in hydrogen fueled jet engines 1s 2 NO(g) N202(g) N202(g) + H2(g) H20(g) +N20(g) N20(g) +H2(g) N2(g) + H20(g) fast slow fast a) Write a balanced equation for the overall chemical reaction (1/2 mark) b) Determine the theoretical rate law. (1 mark) c) Using the blank reaction progress diagram below sketch the energy profile of this exothermic reaction mechanism, labeling the positions of NO. H2,N 02, N2O, H2O, N2. (3...
Can you explain with all necessary steps and equations? thank
you
4. Use the method of initial rates (the simple method, not the more robust approach) to determine the rate law and rate constant for the reaction NH + NO3 - N2 + 2 H2O (acid solution) Given the following data: [HNO2]/M [NH *] / M. Rate x 108/mol Li's! 0.0092 0.098 34.9 0.0092 0.049 16.6 0.0488 0.196 335 0.0249 0.196 156
14. The reaction 2 H2(g) + 2 NO(g) ® N2(g) + 2 H2O(g) is proposed to have the alternate mechanism: 2 NO(g) ® N2O2(g) FAST N2O2(g) + H2(g) ® N2O(g) + H2O(g) SLOW N2O(g) + H2(g) ® N2(g) + H2O(g) FAST If the rate law is found to be Rate = k[H2][NO]2, could this support the proposed mechanism? Does the rate law indicate that the reaction is termolecular?
The experimental rate law for the reaction 2H2(g) + 2 NO(g) → N2(g) +2 H2O(g) is d[N2) = kods[Hz][NO] Below is a proposed mechanism: H2(g) + NO(g) + NO(g) = N2O(g) + H2O(g) H2(g) + N2O(g) = N2(g) + H2O(g) ki k2 (a) Under what conditions does this mechanism give the observed rate law? Express kobs in terms of the rate constants for the individual steps of the mechanism. A second proposed mechanism is: NO(g) + NO(g) = N2O2(g) N2O2(g)...
The reaction of NO gas with H2 gas has the following rate law: Rate = k[H2][NO]2 A proposed mechanism is: Step 1: H2 (g) + 2 NO (g) → N2O (g) + H2O (g) Step 2: N2O (g) + H2 (g) → N2 (g) + H2O (g) What is the molecularity is step 1? What is the molecularity in step 2? Which step is the rate-determining step?
The reaction 2 NO(g) + H2(g) --> N2O(g) + H2O(g) proceeds through the following mechanism: 2 NO(g) --> N2O2(g) N2O2(g) + H2(g) --> H2O(g) + N2(g) (b) What would the rate law be if the first step of this mechanism were rate-determining? Rate = k [NO] [H2]Rate = k [NO]2 [H2] Rate = k [NO] [H2]2Rate = k [NO]1/2 [H2] Rate = k [NO] [H2]1/2 Rate = k [NO]2 Rate = k [NO]2 [H2]1/2 Rate = k [NO]
J.D. Chapple-Sokol, C.J. Giunta, and R.G. Gordon (J. Electrochem. Soc. 136, 2993 (1989)) proposed the following radical chain mechanism for the initial stage of the gas-phase oxidation of silane by nitrous oxide: (1) (2) (3) (4) (5) (6) N2O N2 +O O SiH4 SiH3+ OH SiH3+H20 SiH30+ N2 SIH3OH+ SiH3 (H3Si)20 OH SIH4 SIH3+N20 SIH3O+ SiH4 SIH3+ SiH30 Label each step with its role in the chain. Use the steady-state approximation to show that this mechanism predicts the following rate...