
Draw all stereoisomers formed in each reaction. o . outro od NBS DMSO, H20 H2O H2SO4
Draw all stereoisomers formed in the reaction below.
1. Predict the major organic products of the following reactions. Draw all stereoisomers that are formed. НО, OH 1 eq ,H2SO4 (assume H2O workup of reaction to neutralize product) 1. LDA 2. (assume H,O workup of reaction to neutralize product) 3. Hg(OAC)2 4. NaBH, EtOH 1eq HBr EtOH ambiente 1. Brz. CCL 2. NaOET, ETOH OH
Draw the major product for each reaction. он. CH3 heat N(CH3)3 a. LiAIH4, Et20 b. H30*/H20 1. NaCN, DMSO Br 2. a. LiAIH4. THF b. H3O+/H2O 1. NaN3, DMSO Br 2. a. LiAIH4, THF b. H3O /H20 1. HNO3, H2SO4 2. SnCl2 3. Br2 4. a. HNO2, H2SO4 H3C b. H2PO2 NH2 1. NaNO2, HCI, H20 но 2. HBF4
1. Determine if E1 or E2 and the product formed. H₂O H2O t-butoxide DMSO OCH 3 CHONa. DMSO -ochz Br CHOU CHOH OH acetic acid ОН 2. Draw all the possible products. OH
9. Give the curved arrow mechanism for each reaction. H2SO4 b. H,o OH c. H20 H2SO d. OH H2o 10. For the following reaction, H,so, H,O он a. Give the curved arrow mechanism for the reaction, showing formation of both products b. Identify the major product and explain why it is favored. c. Draw the energy diagram for the formation of the major product. 11. Give the major organic product for the following reactions. If a racemic mixture is expected,...
Draw the products of each reaction. Include all stereoisomers formed. NaBH CH,OH You are not [1] MgBr [2] H 0 Problem 21.15 Draw the products of each reaction. CHO NaCN HCI be a one 1903,4 Problem 21.17 Draw the products of the following Wittig reactions. FO + Ph P=CH,
CH3 CH3 4. Draw the products formed in each reaction Pd CH3 Pd H2SO4 H,O
Draw all stereoisomers formed when the following alkene is treated with mCPBA. How many stereoisomers of the product are possible? Draw the product of the reaction, including stereochemistry.
46) What is the major product formed in the 4-step reaction sequence? Io non o od NH C AICI NO2 2) H0 3) HNO3, H2SO4 4) H2NNH, KOH 47) What is the final product formed in the following sequence of reactions? NHCOCH3OH 1) H,SO./H201) NaNO,, HCI ? heat Conc. H,SO 2 ) H3PO, SOGH 2) dilute NaOH NH21 oor hoe oud SO,H 48) Which of the following reactions would occur as written? Select all that apply. O CHOCI Snc 1)...
29. Give the curved arrow mechanism for each reaction. DOH H2SO4, H,O heat F H2SO4, H2O . х арин OH H SOHO heal 30. For the following reaction, OH H,SO,H,O heat a. Draw the curved arrow mechanism. b. Use the mechanism to explain why acid is a catalyst in the dehydration reaction. C. Draw the energy diagram.