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34. Which pair of compounds can be distinguished by reacting them with dilute bromine water in the dark? A CH,CH2COOH and CH,
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Answer #1

Bromine water dissipates its brown color with alkenes, alkynes, phenols and enols.

Among the given pairs of compounds, the compounds in option B can be distinguished by using bromine water.

CH3CH2CHCHCH3 and CH3CH2CH2CH2CH3

CH3CH2CHCHCH3 is an alkene and will decolorize bromine water whereas CH3CH2CH2CH2CH3 will not decolorize bromine water.

The decolorization happens due to following addition reaction

CH3CH2CH=CHCH3 + Br2(aq) \rightarrow CH3CH2CH(Br)CH(Br)CH3

CH3CH2CH2CH2CH3 + Br2(aq) \rightarrow No decolorization of brown color of bromine water

Among the other pairs given, none of the compounds can dissipate brown color of bromine water in dark, hence they cannot be distinguished by reacting with bromine water.

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