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. The order of reaction of ag Electron transfer reaction is a) 0 c) 1.5 4...
EXERCISE Writing Reaction Mechanisms: Acyl Transfer Electron pairs :0: H-o-H CH3 C Erase + Na :0– CH3 :0 - H Write the first step of the reaction mechanism using curved arrows to show electron reorganization. 0 O H3C- + Na OH HO + H-ô-CH 0 - Nat OCH < Recheck Next (1 of 5)
(9) A spontaneous process has the change of free energy (a) AG > 0 (b) AG <0 (c) AG = 0 (d) AH >0 and AS <0 (10) A chemical reaction has AH = 10 kJ, AS = 50 J/K at temperature T = 300 K, the reaction AG = (a) 5000 (b)-5000 (c) 10000 (d) 50 (11) For reaction : Ag (s) + 1/2 Cl2 (g) = Agt (aq) + CI+ (aq), the standard free energy of formation: AGE"...
(9) A spontaneous process has the change of free energy (a) AG>0 (c) AG = 0 (b) AG <O (d) AH>0 and AS <O (10) A chemical reaction has AH = 10 kJ. AS = 50 J/K at temperature T = 300 K. the reaction AG = J. (a) 5000 (b) -5000 (c) 10000 (d) 50 (11) For reaction: Ag (s) + 2 Cl2 (g) Ag° (aq) +CI (aq), the standard free energy of formation: AGf° (Ag*) = 77.1 kJ/mol,...
C) Explain the meaning of the following: 1- AG° is zero: 2- An ( number of moles) is zero: 3- AS° is zero. 4- n (reaction order ) = 0 5- AG=0
Part D Ag has an anomalous electron configuration. Write the observed electron configuration of Ag. Express your answer in complete form in order of orbital filling. For example, 18° 28' should be entered as 1s 22s 2. ► View Available Hint(s) Submit
4. What is the shift (in volts) of an electrochemical 1 electron transfer reaction away from the formal potential when the concentration of the oxidized species is 10x the concentration of reduced species? (T=300K). (8 points)
2. (20%) The standard potential of the AgCl/Ag, Cr couple fits the expression FO 0.23659-4.8564x10 0-3.4205x106 +5.869x10 8 Unit: E (V; 0 °c) Where: [4G"(H) = 0]; [4,Ge(Ag) = 0]; [4H.(H): 0]; [4m(Ag) = 0] (a) Evaluate the standard reaction Gibbs energy (G enthalpy (4,He) and entropy (4,Se ) at 298K (b) Calculate the standard Gibbs energy (ApG"(cr)and enthalpy(A4"(cr)of formation of Cl (aq)
2. (20%) The standard potential of the AgCl/Ag, Cr couple fits the expression FO 0.23659-4.8564x10 0-3.4205x106 +5.869x10...
9. The K, expression for Ag,CO, is A) (Ag ][CO; 4) B) (Ag"T[CO, C) (Ag 'Picco D) (Ag '1'[CO;-1/[Ag2CO3] 10. For the reaction H2(g) + 12 (6) + 2 HI At a temperature of 298 K, the equilibrium concentrations are [H.] =0.45 M; [12] = 0.050 M; and [HI] = 0.13 M, respectively. What is K ? A) 23 B) 111 C) 9.0 x 10 D) 0.75 11. A system is at equilibrium when A) Kg B) 4Gº=0 C) E°>...
AH= +62.10 k (5 points total) Consider this reaction: 2 Ag,0(s) - 4 Ag(s) + O2(g) 2. How many joules of heat are absorbed when 12.50 milligrams of silver а. oxide is consumed? b. What volume of silver would be produced if 31 megacalories were absorbed in this reaction? The density of silver is 10.5 g/cm
c) What is the order in the reaction; zero order, 1st order, or
2nd order.
Please show all work, please don't just say that
Step1 From 2nd and 3rd observations [A] has doubled; [B] has
remained the same and rate hs also remained the same. Thus order
with respect to A is 0.
Step2 From 3rd and 4th observations [A] has remained same ;[B] has
become 1.5 times;
the rate has become 2.25 times. Thus order with respect to B...