why H2, HCl, CH2Cl2 has pure rotational spectrum. ?

Explain per each of the following molecules why it should or should not show a pure rotational microwave absorption spectrum: (a) H2, (b) HCl, (c) CH4, (d) CH3Cl, (e) CH2Cl2, (f) H2O, (g) H2O2, (h) NH3
Relative to other lines in a rotational absorption spectrum, the intensity of any given line depends primarily rotational level from which the transition originates. on the size of the population in the In a rotational spectrum of gaseous HCl the most intense absorption line originates in the level for which rotational quantum number J = 3. At what temperature was the spectrum measured ? [Given: Ztran V(2xmKT)3/2/h3; Zrot = 8n2IKT/h2; Zvib-exp(-hv/2KT)/[ 1 -exp(-hv/KT)] ; Erot=j (j + 1 ) h2/8721;...
The vibrational-rotational spectrum of HCl consists of two branches of lines, the R-branch and the P-branch, where the R-branch lines are higher in wavenumber than the P-branch lines. The lines arise from transitions between rotational levels of the v” = 0 vibrational state and rotational levels of the v’ = 1 vibrational state of HCl. What are the quantum numbers of the upper and lower level rotational levels (i.e., J’ and J”) that correspond to the transitions that give rise...
Calculate the frequency of the J = 10 ← 9 transition in the pure rotational spectrum of 12C16O. Assume the equilibrium bond length is 109.99pm. What is the Frequency in Hz? What is the corresponding wavenumber in cm-1?
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Good luck! 1 " The pure rotational spectrum of NO is a series of lines separated by 102.3 GHz (GHz= gigahertz = 109s-1). If the reduced mass of NO is 1.24 × 10-26 kg, determine the N-O bond distance in NO
Which of the molecules HBr, CHCl3, O2, HCN, BF3, (CH3)2O can have a pure rotational spectrum?
(b) The rotational Raman spectrum of 1 N2 (m(N) - 14.0031u) shows a series of Stokes lines separated by 1.4567 cm, when it is exposed to monochromatic laser radiation with wavelength of 156 nm. (i) Derive the energy separation expression of the J 3 the pure rotational Raman spectrum of 1N2 1 transition in (i) Calculate the frequency of the above transition in the pure rotational Raman spectrum of 1"N2. 4
(b) The rotational Raman spectrum of 1 N2 (m(N)...
can we get a rotational micrware, millimeter worl, or far IR spectrum for O2? Why or why not?
a. Sketch the expected shape of the pure vibrational absorption spectrum of a diatomic molecule that is well described by the harmonic oscillator model (absorbance as a function of frequency). (We are pretending that there are no rotations occurring for this question. For real diatomic molecules, if they are IR active, there will also be rotational excitations and therefore a rovibrational spectrum.) In what portion of the electromagnetic radiation spectrum would you expect this absorption to occur? b. Sketch the...
The moments of inertia of HCl and KCl molecules are 1.5913 uÅ2 and 131.0596 uÅ2, respectively. (i) Do these molecules have a pure rotational spectrum? (ii) Using the rigid rotor model draw a sketch of the rotational spectrum for each molecule indicating the selection rules. Explain if there are any differences between the spectra.