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7a) Show the products for each of the following reactions. (6 pts) H2SO4 HNO3, A CH3COCI...
Help sos 1. Show the expected product(s) of the following reactions. For products containin or cis/trar...
Help sos
1. Show the expected product(s) of the following reactions. For products containin or cis/trar asymmetric carbon atoms, indicate relative stereochemistry (syn/anti relationships) and/or whether a racemic mixture is produced. (8 pts each) 1. HNO3, H2so4 NO 2. Fe, HCI OCH3 3. NaNO2 aq. HCI 4, CuCN, Δ сно но 1. Br2 H20 2. Fe SO)S b. HO- -H OH s CH2OH 1. SOCI2 2. NH3 H3C 3. Br2 NaOH, H2O 1. KOH 2. PhCH2CH Br 3. NH2NH2 d....
Predict the product(s) or reagents for the following reactions: (0.75 pts each) que HNO3, H2SO4 -Br...
Predict the product(s) or reagents for the following reactions: (0.75 pts each) que HNO3, H2SO4 -Br
Question 18 18 pts A) H2SO4 H20, heat R) NaBH2CN, CH2CH2OH B) NaOH, H2O, heat S)...
Question 18 18 pts A) H2SO4 H20, heat R) NaBH2CN, CH2CH2OH B) NaOH, H2O, heat S) NaOH, Br2, H20, heat C) H3O+ (workup) T) NaNO2, HCI, H2O,0°C D) H20 U) CH3CH2CHO E) NaHCO3 (workup) V) CH2CH2CH2CHO F) NaOH, H2O, heat, pressure W) CH2CH Br G) NH3, heat X) CH2CH2CH2Br H) KNH2, NH3 Y) CH2CH2CH2CH2Br 1) TEA Z) (CH3)3CCOCI J) LiAIH4 AA) (CH3)3CCH COCI K) K2CO3 AB) (CH3)2CHCOCI L) CH2N2 AC) (CH3)2CHCH2COCI M) NaN3, DMF AD) CH2CHBO N) KCN, DME AE)...
Please show all of your steps. Thank you! 5 (20 pts). (a) Propose a reasonable synthesis,...
Please show all of your steps.
Thank you!
5 (20 pts). (a) Propose a reasonable synthesis, using indicated diketone as starting material. ini ² and any C4 or less starting materials (SMS) (any reagents are allowed) Hint: as a C3 SM use Br (b) Propose two syntheses, which will use two distinct methods for construction of the 6-membered ring: (1) Crossed-Claisen condensation and (2) Claisen condensation(s). must use this reagent plus any acyclic Cg or less BONUS (5 pts). In...
12) Write the mechanism for the following nitration and predict the product. (10 pts) OH HNO3...
12) Write the mechanism for the following nitration and predict the product. (10 pts) OH HNO3 H2SO4 13) In the Diels Alder Reaction, 14.7g cyclopenta-1,3-diene (MW=66.1 g/mol) and 15.2g methyl arexate (MW= 86.09 g/mol) in 30 mL of diethyl ether (Density=0.713 g/cm^3;MW= 74.12 g/mol) was used for synthesis of 22.22g of Bicyclo[2.2.1]hept- 5-ene-2-carboxylic acid methyl ester (MW=152.19 g/mol). Please show your work. (10 pts) a. What is the limiting reagent during the reaction? b. What is the % yield of...
show all work please thanks!!! 2. (6 pts total: 2 pts each) Complete the following transformations by indicating the...
show all work please thanks!!!
2. (6 pts total: 2 pts each) Complete the following transformations by indicating the reactant structure or the major organic product(s) Place your answer(s) in the space provided. Be certain to indicate stereochemistry where applicable. Cl2 cat. H2SO4 H2O conc. HBraq) CH3 CHE
5. Show the expected products for the following reactions: (2 pts each, 16 pts total) 0...
5. Show the expected products for the following reactions: (2 pts each, 16 pts total) 0 O NH 1) Conc, KMnO4, NaOH 2) H20+ 3) xs PhMgCI 4) H20" 1) KCN, HCl 2) PCC, CHCI 3) PhyP 1) dilute H2SO4 2) PCC, CH.CL 3) NH w 1) SOCI 2) EtMgBr 3) H.O ОН 1) KCN, HCl 2) H0 3) SOCI, 4) i 1) HCI | 2) HENNH. [H] 3) KOH,H,O, heat 1) RCO,H 2) LAIH 3) H.O 4) H NET,...
5,6,7,8th please 5. Show the expected products for the following reactions: (2 pts each, 16 pts...
5,6,7,8th please
5. Show the expected products for the following reactions: (2 pts each, 16 pts total) 0 O NH 1) Conc, KMnO4, NaOH 2) H20+ 3) xs PhMgCI 4) H20" 1) KCN, HCl 2) PCC, CHCI 3) PhyP 1) dilute H2SO4 2) PCC, CH.CL 3) NH w 1) SOCI 2) EtMgBr 3) H.O ОН 1) KCN, HCl 2) H0 3) SOCI, 4) i 1) HCI | 2) HENNH. [H] 3) KOH,H,O, heat 1) RCO,H 2) LAIH 3) H.O 4)...
Calculate the theoretical yield and percent yield for experiments 7, 8, and 9. For experiment 9,...
Calculate the theoretical yield and percent yield for
experiments 7, 8, and 9. For experiment 9, determine the
theoretical yield based on starting with 0.50g of 3-nitrobenzoic
acid. Show work
Acid I (experiment 7): Weight of methyl 3-nitrobenzoate = 1.9
g
Acid II (experiment 8): Weight of 3-nitrobenzoic acid = 1.75
g
Acid III (experiment 9): Weight of 3-nitrobenzamide = 0.30 g
Experiment 7:
-2.5 mL concentrated H2SO4
-1.75 mL concentrated HNO3 (16M)
-2.1 mL concentrated Methyl Benzoate
Experiment 8:...
Help sos
1. Show the expected product(s) of the following reactions. For products containin or cis/trar asymmetric carbon atoms, indicate relative stereochemistry (syn/anti relationships) and/or whether a racemic mixture is produced. (8 pts each) 1. HNO3, H2so4 NO 2. Fe, HCI OCH3 3. NaNO2 aq. HCI 4, CuCN, Δ сно но 1. Br2 H20 2. Fe SO)S b. HO- -H OH s CH2OH 1. SOCI2 2. NH3 H3C 3. Br2 NaOH, H2O 1. KOH 2. PhCH2CH Br 3. NH2NH2 d....
Predict the product(s) or reagents for the following reactions: (0.75 pts each) que HNO3, H2SO4 -Br
Question 18 18 pts A) H2SO4 H20, heat R) NaBH2CN, CH2CH2OH B) NaOH, H2O, heat S) NaOH, Br2, H20, heat C) H3O+ (workup) T) NaNO2, HCI, H2O,0°C D) H20 U) CH3CH2CHO E) NaHCO3 (workup) V) CH2CH2CH2CHO F) NaOH, H2O, heat, pressure W) CH2CH Br G) NH3, heat X) CH2CH2CH2Br H) KNH2, NH3 Y) CH2CH2CH2CH2Br 1) TEA Z) (CH3)3CCOCI J) LiAIH4 AA) (CH3)3CCH COCI K) K2CO3 AB) (CH3)2CHCOCI L) CH2N2 AC) (CH3)2CHCH2COCI M) NaN3, DMF AD) CH2CHBO N) KCN, DME AE)...
Please show all of your steps.
Thank you!
5 (20 pts). (a) Propose a reasonable synthesis, using indicated diketone as starting material. ini ² and any C4 or less starting materials (SMS) (any reagents are allowed) Hint: as a C3 SM use Br (b) Propose two syntheses, which will use two distinct methods for construction of the 6-membered ring: (1) Crossed-Claisen condensation and (2) Claisen condensation(s). must use this reagent plus any acyclic Cg or less BONUS (5 pts). In...
12) Write the mechanism for the following nitration and predict the product. (10 pts) OH HNO3 H2SO4 13) In the Diels Alder Reaction, 14.7g cyclopenta-1,3-diene (MW=66.1 g/mol) and 15.2g methyl arexate (MW= 86.09 g/mol) in 30 mL of diethyl ether (Density=0.713 g/cm^3;MW= 74.12 g/mol) was used for synthesis of 22.22g of Bicyclo[2.2.1]hept- 5-ene-2-carboxylic acid methyl ester (MW=152.19 g/mol). Please show your work. (10 pts) a. What is the limiting reagent during the reaction? b. What is the % yield of...
show all work please thanks!!!
2. (6 pts total: 2 pts each) Complete the following transformations by indicating the reactant structure or the major organic product(s) Place your answer(s) in the space provided. Be certain to indicate stereochemistry where applicable. Cl2 cat. H2SO4 H2O conc. HBraq) CH3 CHE
5. Show the expected products for the following reactions: (2 pts each, 16 pts total) 0 O NH 1) Conc, KMnO4, NaOH 2) H20+ 3) xs PhMgCI 4) H20" 1) KCN, HCl 2) PCC, CHCI 3) PhyP 1) dilute H2SO4 2) PCC, CH.CL 3) NH w 1) SOCI 2) EtMgBr 3) H.O ОН 1) KCN, HCl 2) H0 3) SOCI, 4) i 1) HCI | 2) HENNH. [H] 3) KOH,H,O, heat 1) RCO,H 2) LAIH 3) H.O 4) H NET,...
5,6,7,8th please
5. Show the expected products for the following reactions: (2 pts each, 16 pts total) 0 O NH 1) Conc, KMnO4, NaOH 2) H20+ 3) xs PhMgCI 4) H20" 1) KCN, HCl 2) PCC, CHCI 3) PhyP 1) dilute H2SO4 2) PCC, CH.CL 3) NH w 1) SOCI 2) EtMgBr 3) H.O ОН 1) KCN, HCl 2) H0 3) SOCI, 4) i 1) HCI | 2) HENNH. [H] 3) KOH,H,O, heat 1) RCO,H 2) LAIH 3) H.O 4)...
Calculate the theoretical yield and percent yield for
experiments 7, 8, and 9. For experiment 9, determine the
theoretical yield based on starting with 0.50g of 3-nitrobenzoic
acid. Show work
Acid I (experiment 7): Weight of methyl 3-nitrobenzoate = 1.9
g
Acid II (experiment 8): Weight of 3-nitrobenzoic acid = 1.75
g
Acid III (experiment 9): Weight of 3-nitrobenzamide = 0.30 g
Experiment 7:
-2.5 mL concentrated H2SO4
-1.75 mL concentrated HNO3 (16M)
-2.1 mL concentrated Methyl Benzoate
Experiment 8:...
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