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Part B: Cell Potential and Temperature (Pb/Cu cell) 1. Fill in the table. Use cell one...
Effect of Temperature on Cell Potential Cell designation: E (measured) Temperature (°C) PbPb2+ || Cu2+ Cu; 0.455 Temperature (K) AG (calculated) 0.497 295 0.512 Sn Sn2+ || Cult | Cu; 0.548 0.554 279 295 0.566 343 Y AS determined from the slope of a plot of AG versus T AS Pb Cur AS Sn|Cu = AH° Pb | Cu=- AHSn Cu=- AHº calculated at 298 K (show calculations) from AG = AH-TAS AH = AG+TAS
Electrochemical Cells and Thermodynamics Key (calculated) Shorthand cell designation ΔΟ (calculated) E cell (measured) Temperature ( ) and Keq for an exemplary pair. For Pb | Pb2+ Isn2+ Sn: Show calculations for E half-cell (calculated) Half-cell equation Effect of Temperature on Cell Potential Cell designation: E (measured Tempegature fc) Temperature (kK) AG (calculated) 5 c 1134 228 K 2315 AS determined from the slope of a plot of AG versus T (show calculations) AfP calculated at 298 K 233
Electrochemical...
Ive
attacthed all my results. I just need help calculating question 4
and 5
(5 pts) Part II. Your experimental data: how many sig figs should your temperature data have? Show work for one calculation of temp in Kelvin. Show work for one AG calculation: Approximate Measured Cell Calculated Temp (°C) Calculated Temp (°C) potential Temp (K) AG Ecell (V)* (kJ/mol)* * measured value 70.21 0.581 343 1-112.1 65.12 0.680338 - 111.9 Show work: 60.02 0.5715333 -1110 °C -> 5.05+278.15...
equation in graph: E=1.13E+00-1.08E-04T
8. (10 pts) A cell is constructed Cu2+ to Cu, while the zinc is oxidized from Zn to Zn+. The cell potential is measured as temperature, yielding the graph below. with a copper anode and a zinc cathode. The copper is reduced from 1 3E-00-1.08E-04 T e» 1 8 280 290 300 310 320 330 340 350 Determine Δrrn // and ΔrrnS for this reaction from the data given.
8. (10 pts) A cell is constructed...
Can someone please help me finish the tables and
calculations.
Thanks in advance
Data Sheet Part A: Dependence of Reaction Rate on Concentration Table 1 H Temperature Time Relative mixture ! (seconds) | rate 1000 Reaction BrOsl (eC) . 1235.6 Avg. time 2. 67.S 3. 08,24 Avg. time 2. 74.2 3. 70.74.O Avg. time 24.o' 4 弘·11 0.2 OD3 0.00 8 100 o.oy | 23.5 3. 29. Avg. time 교 Table 2: Calculations for the [I']. [Bro, & [H'] BrOs...
use tabulated standard electrode potential to calculate the
standard cell potential for the reaction occurring in an
electrochemical cell at 25 C. (The equation is balanced.)
3Ni^2+(aq)+2Cr(s)--->3Ni(s)2Cr^3+(aq)
Express your answer to two significant figures and include the
appropriate units.
em 26 E (V) -0.45 -0.50 -0.73 -0.76 -1.18 Standard reduction half-cell potentials at 25°C Half-reaction E° (V) Half-reaction Aul+ (aq) + 3e +Au(s) 1.50 Fe2+ (aq) + 2eFe(s) Ag+ (aq) +e-Ag(s) 0.80 Cr3+ (aq) + Cr²+ (aq) Fe+(aq) + 3e...
Partner's Name Instructor Procedure I, Voltaic Cell Zn/Zn2+ 1.0 M || Cu2+ 1.0 M/Cu In the space below write the equations for the two half reactions and sum them appropriately to calculate the standard reaction potential for a 1.0 M voltaic cell. Show the overall net ionic equation for this reaction. 9pts.) Standard reaction potential Write the expression for Q for this redox reaction. (4 pes) In the space below show a calculation using the Nemst equation to determine the...
how
do I solve this?
1. Use the Nernst equation to calculate the standard cell potential for a voltaic cell of a Sn electrode in 0.10M Sn2(a) in one half-cell and Al in 0.10M AP) in the other. (EPe Eaode- Emode 1.52 V, Show your work. Hint: Check E values of the reduction haif reactions. Write the one with more negative E as oxidation half reaction (change the sign); ensure that equal number of electrons are exchanged ie. electrons cancel,...
Cell Potential and Equilibrium Standard reduction potentials The equilibrium constant, K, for a redox reaction is related to the standard cell potential, Ecel, by the equation Reduction half-reaction (V) Ag+ (aq) + e-→Ag(s) Cu2+ (aq) + 2e-→Cu(s) 0.34 Sn (a) 4e-Sn(s 0.15 2H' (aq) + 2e-→H2 (g) Ni2+ (aq) + 2e-→Ni(s)-0.26 Fe2+ (aq) + 2e-→Fe(s)-0.45 Zn2+ (aq) + 2e-→Zn(s)-0.76 Al3+ (aq) +3e-→Al(s) -1.66 Mg2+ (aq) + 2e-→Mg(s) -2.37 0.80 n FEcell where n is the number of moles of electrons...
Table 3: Experimental Data for Part 2: Determination of Activation Energy k Time* T* [1] [S,0,?] Rate (M/s) (s) (C) (M) (M) Run 3 153 20.5 .0208 .0416 4.03*10^-6 4.65*10^-3 (Room T) Run 6 198 9 .0208 .0416 3.15*10^-6 3.64*10^-3 (Cool) Run 7 112 31 .0208 .0416 5.58*10^-6 6.45*10^-3 (Warm) Run 8 40 51 .0208 .0416 1.56*10^-5 1.80*10^-2 (Warmer) 1/T (1/K) In k Run 3 1/293.5 -5.37 Run 6 1/282 -5.62 Run 7 1/304 -5.044 Run 8 1/324 -4.02 20....