13. Electrochemical cell
a) balanced overall reaction for a sucessful cell made from these two couples
2Ag+ + H2SO3 + H2O ---> SO4^2- + 4H+ + 2Ag
b) line notation for the cell
Ag+(aq) | Ag(s) || H2SO3(aq) | SO4^2-(aq),H+(aq)
c) Eo = Ecathode - Eanode
= 0.80 - 0.172
= 0.628 V
d) equilibrium constant Kc at 25 oC
T = 25 oC + 273 = 298 K
R = gas constant
n = 2
F = Faraday constant
Using,
dGo = -nFEo = -RTlnKc
Kc = nFEo/RT
= inv.ln(2 x 96500 x 0.628/8.314 x 298)
= 1.76 x 10^21
e) when cell voltage E = 0.51 V
Using Nernst equation,
E = Eo - 0.0592/n log[activity of products/activity of reactants]
n = 2
feeding values,
[activity of products/activity of reactants] = inv.log[(0.628 - 0.51) x 2/0.0592]
= 9694
13. Find the standard reduction potentials for the following half-reactions: So+4H" + 2e-> HSO H2O and...
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