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Can someone show the major product as well as an explanation
with it?
H30 j. Ph-CH3...
Which of the reactions will yield the indicated compound as the major product? Check all that...
Which of the reactions will yield the indicated compound as the
major product? Check all that apply.
CI (i) CI ♡ CI 1. HNO3, H2SO4 2. HN(CH3)2 NO2 CI (ii) 1. HNO3, H2SO4 2. HN(CH3)2 NO2 CI CI (iii) OCH3 OCH3 1. HNO3, H2SO4 2. HN(CH3)2 O2N CI (iv) OCH3 1. NaN(CH3)2, HN(CH3)2 OCHZ 2. Br2 Br H2C H2C CI (v) H3C AICI: H3C CH3 CH3 (vi) H2N 1) HNO3, H2SO4 HN 2) NaOH, H2O NO2
e. 4-HC-C6H4-NH-C(O)-CH3 + Cl2/H4C-COH ------> H30* f. 4-nitro-1-chlorobenzene + NaOH H2O g. Ph-CH2-CH2-CH2-CO2H + AICI: ------->...
e. 4-HC-C6H4-NH-C(O)-CH3 + Cl2/H4C-COH ------> H30* f. 4-nitro-1-chlorobenzene + NaOH H2O g. Ph-CH2-CH2-CH2-CO2H + AICI: -------> h. All trans-H2C=CH-CH=CH-OCH3 + H2C=CH-C(O)-H i. 1-bromo-3-chlorobenzene + HNO3/H2SO4 j. CsH5-CH=CH-CH3 + HBr/peroxides --------> H30* k. Ph-CH2-CH3 + KMnO./NaOH/A ----------> L. CoHs-CCl3 + Bry/FeBr ---------- H30* m. Ph-Br + KNH/-33 °C --------
g. Ph-C(O)-NH2 4 NaOH Br2 h. (HC)2CH-C(CHa)2 -> HO N(CH3)3 i. Ph-N2, CI- + CuCN -->...
g. Ph-C(O)-NH2 4 NaOH Br2 h. (HC)2CH-C(CHa)2 -> HO N(CH3)3 i. Ph-N2, CI- + CuCN --> H30* (cat) Na/ETOH j. cyclohexanone+ H2NOH Pd(OAc)2 (1 mole%) k. Ph-I + 4-O2N-C&H4-HC=CH2 Cul/Pd(PPH3)4) L. HO-CH2-CH2-CC-H +1-CH=CH-(CH2)4-CH3
17. Use ANY needed reagents to effect the following transformation. (30 points) starting material product List...
17. Use ANY needed reagents to effect the following transformation. (30 points) starting material product List of Reagents -N:C:N- KMnO4, H2SO4 8 00 (CH3),COCOCOC(CH3)3 Ag(NH3)2+, 120 Fe, HCI KMnO4, NaOH, H2O, cold AlCl3 Bra (excess), NaOH (excess), H20 Brz, Fe Br2, H20 Br2, H2O, H3O+ Br2, hy Br2, NaOH (excess), H2O Br2, P Buli CF3CO,H CH;=0 Formaldehyde оо CH3COCCH o CH_CC1, pyridine H2, Lindlar's catalyst H2.Pd/C H2, Pa/C, high pressure H, Raney-Ni HANNH HENNH, KOH, (HOCH2CH2)20, heat H2O H20, H2SO4,...
Draw the major product for each reaction. он. CH3 heat N(CH3)3 a. LiAIH4, Et20 b. H30*/H20...
Draw the major product for each reaction. он. CH3 heat N(CH3)3 a. LiAIH4, Et20 b. H30*/H20 1. NaCN, DMSO Br 2. a. LiAIH4. THF b. H3O+/H2O 1. NaN3, DMSO Br 2. a. LiAIH4, THF b. H3O /H20 1. HNO3, H2SO4 2. SnCl2 3. Br2 4. a. HNO2, H2SO4 H3C b. H2PO2 NH2 1. NaNO2, HCI, H20 но 2. HBF4
5. Identify the major product expected to form at the completion of the following synthetic sequence....
5. Identify the major product expected to form at the completion of the following synthetic sequence. O OH SO3, H2SO4 Br2 H2O H3O*-H2O но ОН Br ОН Он Он Br о Он Br но но Но НО но Br SO3H Br Br (A) (B) (C) (D) (E) 6.Which of the following synthetic sequences is expected to yield 2-chloro-4-nitrobenzoic acid in highest yleld? 1. KMnO OH Cla- FeCl HNO3- H2SO heat (A) 2. H30 1. KMnO4 , OH HNO- H2SO Clo-...
4. Predict the major product in the following reactions. relationship between: Lindlar cat. A and C i. m-CPBA H2 CH3 ii...
4. Predict the major product in the following reactions. relationship between: Lindlar cat. A and C i. m-CPBA H2 CH3 ii. H30* H2O Ph A B and D H2SO4 i. m-CPBA Ph CH3 heat ii. H30* H2O OH
4. Predict the major product in the following reactions. relationship between: Lindlar cat. A and C i. m-CPBA H2 CH3 ii. H30* H2O Ph A B and D H2SO4 i. m-CPBA Ph CH3 heat ii. H30* H2O OH
Predict the major organic product or products of each of the following reactions: Identify the mechanism...
Predict the major organic product
or products of each of the following reactions:
Identify the mechanism
taking place in each of the reactions and please provide
explanation.
H2SO4 a) (CHỊ) CH CH=CH, HO Hg(OAc)2 NaBH4 b) (CH3)2CH CH=CH2 H2O BH3: THE H2O2, NaOH c) (CH3),CH CH=CH2 H2SO4, H2O d) CHCECH HgSO4 HZ/Ni f) + Cl2 + H2O g) Cold KMnO4 dilute h) 1. CH CO-OH 2. Hz0 Br2 i) CC14
Fill in the reagent/product/reactant: OCH3 1) K* -OCH3, HOCH3 2) H30*, A 1) NH,OH, H+ (cat.)...
Fill in the reagent/product/reactant:
OCH3 1) K* -OCH3, HOCH3 2) H30*, A 1) NH,OH, H+ (cat.) 2) H2SO4 O NX OH SOCI 1) LiAlH4 2) H2O NaN3, A NaOH, Bra HO, A
write a major product for each of the following reaction, indicate appropriate stereochemistry 1.(CH3)3COK, (CH3)2COH 2....
write a major product for each of the following reaction,
indicate appropriate stereochemistry
1.(CH3)3COK, (CH3)2COH 2. Brz, cena 2 3. x's NaNH2 ; H20 W 14. HgSO4, H2SO4, H2O ÇI 1. x's NaNH2; H20 * 2. k, NH3, CH3CH2OK 3. KMnO4 , H2SO4, 4 1. B2H, THF; NaOH(aq), H202 2. SOBrą, o 1. H2SO4, A OH 318 , NaNH2 4. H2, Lindlar catalyst 2. HBr, H202 3.(CH3)3COK, (CH3)3COH 4. R-COOH; H30°
Which of the reactions will yield the indicated compound as the
major product? Check all that apply.
CI (i) CI ♡ CI 1. HNO3, H2SO4 2. HN(CH3)2 NO2 CI (ii) 1. HNO3, H2SO4 2. HN(CH3)2 NO2 CI CI (iii) OCH3 OCH3 1. HNO3, H2SO4 2. HN(CH3)2 O2N CI (iv) OCH3 1. NaN(CH3)2, HN(CH3)2 OCHZ 2. Br2 Br H2C H2C CI (v) H3C AICI: H3C CH3 CH3 (vi) H2N 1) HNO3, H2SO4 HN 2) NaOH, H2O NO2
e. 4-HC-C6H4-NH-C(O)-CH3 + Cl2/H4C-COH ------> H30* f. 4-nitro-1-chlorobenzene + NaOH H2O g. Ph-CH2-CH2-CH2-CO2H + AICI: -------> h. All trans-H2C=CH-CH=CH-OCH3 + H2C=CH-C(O)-H i. 1-bromo-3-chlorobenzene + HNO3/H2SO4 j. CsH5-CH=CH-CH3 + HBr/peroxides --------> H30* k. Ph-CH2-CH3 + KMnO./NaOH/A ----------> L. CoHs-CCl3 + Bry/FeBr ---------- H30* m. Ph-Br + KNH/-33 °C --------
g. Ph-C(O)-NH2 4 NaOH Br2 h. (HC)2CH-C(CHa)2 -> HO N(CH3)3 i. Ph-N2, CI- + CuCN --> H30* (cat) Na/ETOH j. cyclohexanone+ H2NOH Pd(OAc)2 (1 mole%) k. Ph-I + 4-O2N-C&H4-HC=CH2 Cul/Pd(PPH3)4) L. HO-CH2-CH2-CC-H +1-CH=CH-(CH2)4-CH3
17. Use ANY needed reagents to effect the following transformation. (30 points) starting material product List of Reagents -N:C:N- KMnO4, H2SO4 8 00 (CH3),COCOCOC(CH3)3 Ag(NH3)2+, 120 Fe, HCI KMnO4, NaOH, H2O, cold AlCl3 Bra (excess), NaOH (excess), H20 Brz, Fe Br2, H20 Br2, H2O, H3O+ Br2, hy Br2, NaOH (excess), H2O Br2, P Buli CF3CO,H CH;=0 Formaldehyde оо CH3COCCH o CH_CC1, pyridine H2, Lindlar's catalyst H2.Pd/C H2, Pa/C, high pressure H, Raney-Ni HANNH HENNH, KOH, (HOCH2CH2)20, heat H2O H20, H2SO4,...
Draw the major product for each reaction. он. CH3 heat N(CH3)3 a. LiAIH4, Et20 b. H30*/H20 1. NaCN, DMSO Br 2. a. LiAIH4. THF b. H3O+/H2O 1. NaN3, DMSO Br 2. a. LiAIH4, THF b. H3O /H20 1. HNO3, H2SO4 2. SnCl2 3. Br2 4. a. HNO2, H2SO4 H3C b. H2PO2 NH2 1. NaNO2, HCI, H20 но 2. HBF4
5. Identify the major product expected to form at the completion of the following synthetic sequence. O OH SO3, H2SO4 Br2 H2O H3O*-H2O но ОН Br ОН Он Он Br о Он Br но но Но НО но Br SO3H Br Br (A) (B) (C) (D) (E) 6.Which of the following synthetic sequences is expected to yield 2-chloro-4-nitrobenzoic acid in highest yleld? 1. KMnO OH Cla- FeCl HNO3- H2SO heat (A) 2. H30 1. KMnO4 , OH HNO- H2SO Clo-...
4. Predict the major product in the following reactions. relationship between: Lindlar cat. A and C i. m-CPBA H2 CH3 ii. H30* H2O Ph A B and D H2SO4 i. m-CPBA Ph CH3 heat ii. H30* H2O OH
4. Predict the major product in the following reactions. relationship between: Lindlar cat. A and C i. m-CPBA H2 CH3 ii. H30* H2O Ph A B and D H2SO4 i. m-CPBA Ph CH3 heat ii. H30* H2O OH
Predict the major organic product
or products of each of the following reactions:
Identify the mechanism
taking place in each of the reactions and please provide
explanation.
H2SO4 a) (CHỊ) CH CH=CH, HO Hg(OAc)2 NaBH4 b) (CH3)2CH CH=CH2 H2O BH3: THE H2O2, NaOH c) (CH3),CH CH=CH2 H2SO4, H2O d) CHCECH HgSO4 HZ/Ni f) + Cl2 + H2O g) Cold KMnO4 dilute h) 1. CH CO-OH 2. Hz0 Br2 i) CC14
Fill in the reagent/product/reactant:
OCH3 1) K* -OCH3, HOCH3 2) H30*, A 1) NH,OH, H+ (cat.) 2) H2SO4 O NX OH SOCI 1) LiAlH4 2) H2O NaN3, A NaOH, Bra HO, A
write a major product for each of the following reaction,
indicate appropriate stereochemistry
1.(CH3)3COK, (CH3)2COH 2. Brz, cena 2 3. x's NaNH2 ; H20 W 14. HgSO4, H2SO4, H2O ÇI 1. x's NaNH2; H20 * 2. k, NH3, CH3CH2OK 3. KMnO4 , H2SO4, 4 1. B2H, THF; NaOH(aq), H202 2. SOBrą, o 1. H2SO4, A OH 318 , NaNH2 4. H2, Lindlar catalyst 2. HBr, H202 3.(CH3)3COK, (CH3)3COH 4. R-COOH; H30°
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