Entropy of naphthalene:
Consider naphthalene C10H8 at atmospheric pressure.
It is a solid with a melting point at 80.1 degrees Celsius and a boiling point at 218 degrees Celsius. The latent heat of fusion is 19,123 kJ / mol. The molar heat at constant pressure of solid naphthalene has a functional temperature dependence (in K) which is linear. Its value is 0 at T = 0 K and 188.41 J / mol-K at T = 317.15 K. The molar heat at constant pressure of liquid naphthalene has a functional temperature dependence (in K) which is also linear. At T = 357.91 K, it is 219.34 J / mol-K and at T = 460.25 K, it increases to 317.47 J / mol-K.
Find the entropy change that 1 kg of naphthalene undergoes when heated from 0 to 100 degrees Celsius at atmospheric pressure.
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Entropy of naphthalene: Consider naphthalene C10H8 at atmospheric pressure. It is a solid with a melting...
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One mole of liquid naphthalene at its freezing point of 80 ˚C is brought into contact with a very large ice-water bath, which remains at 0 ˚C as the naphthalene freezes and cools to 0˚C. The enthalpy of fusion of naphthalene is 19.2 kJ mol-1 and ~ C p for solid naphthalene is 180 J K-1 mol-1. Calculate the decrease in entropy for the naphthalene and the increase in entropy for the overall system (naphthalene + ice-water bath).
Physical Chemistry
Calculate the change in entropy when one mole of metallic aluminum is heated at one bar pressure from an initial temperature of 25 °C to a final temperature of 750 °C. The molar heat capacities of solid and liquid aluminum at one bar pressure are 29.2 J mol K1 and 31.75 J mol K, respectively. The specific enthalpy of fusion of aluminum at its melting point (660.46 °C) is 396.57 J g1. The molar mass of aluminum is...