What is the maximum number of phases that can be in equilibrium in a ternary system? Explain.
The answer is 4.
Explanation:
From Gibbs' phase rule we know that F = C – P + N,
where F is the number of degrees of freedom, C is the number of components and P is the number of phases in thermodynamic equilibrium
Now, for a ternary system (C = 3) at constant pressure (N = 1), Gibbs phase rule, becomes
P + F = C + N = 3 + 1 = 4
Or,
P = 4 – F
Thus, when F = 0, P will have its maximum value of 4, which means that the maximum number of phases present for this situation is 4.
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