Reactions in solutions:
The viscosity of water at 20 ℃ is 1.0019 ?? ∗ ? ∗ ?^-2 and at 30 ℃ it is 0.7982 ?? ∗ ? ∗ ?^-2 . What is the activation energy of diffusion? Assuming the water molecule’s radius to be 0.5 nm, what is the diffusion coefficient of water that 20 ℃? How far on average would a single water molecule travel in solution, every second?
Reactions in solutions: The viscosity of water at 20 ℃ is 1.0019 ?? ∗ ? ∗...
The diffusion coefficient for horse hemoglobin in water is 1.26 × 10–10 m2 s–1 at 40 °C. The viscosity of water at 40 °C is 0.653 × 10–3 kg m–1 s–1. Estimate the radius of hemoglobin assuming the molecule to be spherical and obey Stokes’s law. Comment on the size of Hemoglobin to a corona virus unit which has a diameter of 120 nm.
Calculate the diffusion coefficient for the protein cytochrome c in aqueous solution assuming sphericity and using the Stokes-Einstein equation at 25degree C. The hydrodynamic radius is R =19.0 Angstroms. The viscosity of water is 1.00 cP = 0.00100 kg/m-s. D_cytc =__m^2/s. If the critical reaction distance is the sum of their radii, what value is expected for the Smoluchowski theory second order rate constant for a diffusion controlled reaction between two cytochrome c's? k_d = Lmol^-1s^-1 What would be the...
Contrast elementary and overall reactions with some examples. What is meant by the term 'rate-limiting step? Define a zero-, first- and second-order reaction and find an example of each for from the aqueous geochemistry world (text, web, etc). Using Excel, develop graphical representations of zero-, first (reactant)- and second-order (reactant^2) rate expressions showing: rate (y) vs. time (x) reactant cone. (y) vs. time (x) Discuss how these idealized plots might be used to interpret observed experimental rate data. Compare and...
Suppose that a force of 1 pN is applied to a globular
100 kDa protein. In the absence of damping, how fast will the
protein be moving after 1 ns? During this time, how far will the
protein have moved? GIven the damping coefficient quoted in Table
2.2, what is the actual terminal velocity of the protein?
Table 2.2 Physical properties of a globular protein of molecular mass To0 Property Mass Density Volume Radius Drag coefficient 60 pN-s/m Diffusion coefficient...
Water (density 998 kg/mº, dynamic viscosity 0.001 Pa s) is pumped between two reservoirs at a volumetric flow rate of 0.006 m/s through a 120-m long pipe of 5 cm diameter. The roughness ratio of the pipe is a/d = 0.001. There are some fittings and valves in the pipe system, as shown in Figure Q1. The loss coefficients of the valves and fittings can be found in Table Q1. The Darcy friction factor can be found in the Moody...
Paragraph k acids and bases. We need to we will be working with solutions of both strong acids and bases, and wea good idea of what compounds are actually present in these solutions before we begin. Write an equation for the solution that results when each compound is placed in water. For the ionic compounds, there will be a second hydrolysis equation that takes place. Make sure that you use single arrows to represent full extent reactions, and double arrows...
Hi I need help with finding the triiodide in diluted
soultion ( i think you use M1V1=M2V2) but I'm not sure with what
values. I also need it for the excinction coefficient value. b for
the equation is 1.3, please help!
Procedure termination of the absorption spectrum oftrilodide. Please review the discussion n spectroscopy in Experiment 15. Iodine and triodide solutions are both colored and of absorption absorb light in the visible region of the spectrum. Iodine has nm in...
Question 1 (20 marks) (a) (10 marks) This is a section of a dam that holds up water up to a height of 25 m in the spring. When summer arrives, due to evaporation, this height drops by 10 m. As a design engineer on this project, you are to design a gate for releasing water. This gate opens about a single pivot point (dark circle) by angle e (30 about the vertical axis. The customer requires some questions to...
i
dont know what im doing. help.
4.3-Precipitation Reactions 3. The following molecular views show reactant solutions for a precipitation reaction (with H,O molecules omitted for clarity). a) Which compound is dissolved in beaker A: KCI, Na2SO4, MgBrz, or Ag2SO.? b) Which compound is dissolved in beaker B: NH,NO3, MgSO Ba(NO3), or CaFZ? c) Write a balanced molecular, total ionic, and net ionic equations for the reaction that occurs when solutions A and B are mixed. d) If 1 L...
some of the reagents used in this lab are easily confused: such as
persulfate and thiosulfate. A student inadvertently switched these
reagents, adding the persulfate to beaker A and thiosulfate to
beaker b. How would this affect the results? What would the student
observe with respect to the mixture in beaker A?
3. Some of the reagents used in this lab are easily confused: such as persulfate (S.O,2-) and thiosulfate (S,0,2-). A student inadvertently switched these reagents, adding the persulfate...