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Question 4: Complete each of the following reactions by giving the principal organic 20 pts product(s)...
4. Synthesis Reactions. Draw the feature product of the following reactions. (8 x 3 pts) 1....
4. Synthesis Reactions. Draw the feature product of the following reactions. (8 x 3 pts) 1. Mg Ph Br 2. CO2 3. H a "NH2 Ph 1. NaOH, CI 2. LAIH b. CHỊCH NHA NaBHgCN, H+ Ph C. Br (excess) NH d NaOH H HO OH H CH e. 1. NaOH H2O NH 2. H+ o= 1. NaOH H2O 2. SOCI N(CH3)2 3 HO
5. Show the expected products for the following reactions: (2 pts each, 16 pts total) 0...
5. Show the expected products for the following reactions: (2 pts each, 16 pts total) 0 O NH 1) Conc, KMnO4, NaOH 2) H20+ 3) xs PhMgCI 4) H20" 1) KCN, HCl 2) PCC, CHCI 3) PhyP 1) dilute H2SO4 2) PCC, CH.CL 3) NH w 1) SOCI 2) EtMgBr 3) H.O ОН 1) KCN, HCl 2) H0 3) SOCI, 4) i 1) HCI | 2) HENNH. [H] 3) KOH,H,O, heat 1) RCO,H 2) LAIH 3) H.O 4) H NET,...
5,6,7,8th please 5. Show the expected products for the following reactions: (2 pts each, 16 pts...
5,6,7,8th please
5. Show the expected products for the following reactions: (2 pts each, 16 pts total) 0 O NH 1) Conc, KMnO4, NaOH 2) H20+ 3) xs PhMgCI 4) H20" 1) KCN, HCl 2) PCC, CHCI 3) PhyP 1) dilute H2SO4 2) PCC, CH.CL 3) NH w 1) SOCI 2) EtMgBr 3) H.O ОН 1) KCN, HCl 2) H0 3) SOCI, 4) i 1) HCI | 2) HENNH. [H] 3) KOH,H,O, heat 1) RCO,H 2) LAIH 3) H.O 4)...
10. Write the structural formula for the principal organic product of each of the following reactions....
10. Write the structural formula for the principal organic product of each of the following reactions. (8 marks) 0 CH.CH,CH,COOH + CH- chchi- CH,CH-C-Cl CH.CH,OH b. ce CH-C-Cl + CHỊCH,CH,OH C HCOOH + CHỌCH,OH d. BONUS: Write out full reaction schemes for (a) the alka hydrolysis of methyl propanoate and sodium hydroxide, and (b) the acid hydrolysis of ethyl acetate and water. (2 bonus marks total)
4. Give the major organic product(s) for each of the following reactions or sequences of reactions....
4. Give the major organic product(s) for each of the following reactions or sequences of reactions. H Br 1. N.CN 2. NaOH,H,O, heat 3.H30 Ind o do CH,COOH 1. LiAlH, THF, heat 2.H,0 HO CH Br 1. NaCN, acetone 2.H30, heat h ome couco C:03, H30* он
2. Write the structure of the principal organic product(s) of the following reactions: (112 pts) (a)...
2. Write the structure of the principal organic product(s) of the following reactions: (112 pts) (a) 2-chloropropane + lithium in diethyl ether (b) product of (a) with cyclohexanone, followed by dilute acid (c) benzoic acid + NaOH+H2O (d) hexanoic acid + Brą + PBrz (e) ethyl acetate + CH3CH2O- Nat in ethanol (f) ethyl acetoacetate + sodium ethoxide + 1-bromobutane (g) propanal + ethanol + dissolved HCl gas (h) (CH),CO K + CH I in (CH),COH solvent (i) 2,4-pentanedione +...
4. Complete the reactions below by supplying the reactant, reagent or product. (*pts each OH b...
4. Complete the reactions below by supplying the reactant, reagent or product. (*pts each OH b H,0,HCI Heat O it CI d. (excess) 1. LAIH 2. H2O -CHCH PPh; 3 Name: f. 1. CHACHIMBI 2. H,0 1. LAIH 2. HO h. CuLi(CH 3)2 i. 1. LDA (1 equiv) 2. CHỊCH,C 5
2. Identify the principal organic product of each of the following reactions: (30 pts) (a) acetic...
2. Identify the principal organic product of each of the following reactions: (30 pts) (a) acetic anhydride and 2-pentanol (b) 4-methyl-3-penten-2-one and ammonia in water solution (c) acetophenone (methyl phenylketone) and benzaldehyde+KOH in ethanol solvent (d) methyl butanoate and LDA (lithium diisopropylamide) in THF solution, then ethyl iodide (e) butylamine and excess 1-iodobutane (1) acetanilide and LiAlH, in diethyl ether, followed by addition of water.
Homework Problems Give the name for each of the following: 9.1 COOH a. ОН CHy с....
Homework Problems Give the name for each of the following: 9.1 COOH a. ОН CHy с. CH,-сн-сн,-соон d. (CH,CH2),CCOOH Draw the structural formula for each of the following compounds: 9.2 a. sodium hexanoate b. potassium acetate c. zinc benzoate d. calcium propanoate 9.3 Complete the following reactions: HP CH3 -C-OH CH CH,CH,OH а. + b. (CH),CCH,CH,соон + (СH),СНОН [H COOH с. + CH,CH2OH d. CH,(CH),COOH HP Но- Draw a structural formula for each of the following esters: a. cyclohexyl propanoate...
Give the product(s) of reaction of hexanal with each of the following reagents. 2. (0) носн,сн,он,...
Give the product(s) of reaction of hexanal with each of the following reagents. 2. (0) носн,сн,он, н (b) 1. LIAIH, 2. H,0* (e) NH,он, н" (d) NH,NH2, KOH, heat (e) (CH),СHCH,CH— P(C, Нә» , н" (g) Ag, NH, H,O (h) CrOs, H,SO H,0 () 1. KCN, 2. H,SO MCPBA
Give the product(s) of reaction of hexanal with each of the following reagents. 2. (0) носн,сн,он, н (b) 1. LIAIH, 2. H,0* (e) NH,он, н" (d) NH,NH2, KOH, heat (e) (CH),СHCH,CH—...
4. Synthesis Reactions. Draw the feature product of the following reactions. (8 x 3 pts) 1. Mg Ph Br 2. CO2 3. H a "NH2 Ph 1. NaOH, CI 2. LAIH b. CHỊCH NHA NaBHgCN, H+ Ph C. Br (excess) NH d NaOH H HO OH H CH e. 1. NaOH H2O NH 2. H+ o= 1. NaOH H2O 2. SOCI N(CH3)2 3 HO
5. Show the expected products for the following reactions: (2 pts each, 16 pts total) 0 O NH 1) Conc, KMnO4, NaOH 2) H20+ 3) xs PhMgCI 4) H20" 1) KCN, HCl 2) PCC, CHCI 3) PhyP 1) dilute H2SO4 2) PCC, CH.CL 3) NH w 1) SOCI 2) EtMgBr 3) H.O ОН 1) KCN, HCl 2) H0 3) SOCI, 4) i 1) HCI | 2) HENNH. [H] 3) KOH,H,O, heat 1) RCO,H 2) LAIH 3) H.O 4) H NET,...
5,6,7,8th please
5. Show the expected products for the following reactions: (2 pts each, 16 pts total) 0 O NH 1) Conc, KMnO4, NaOH 2) H20+ 3) xs PhMgCI 4) H20" 1) KCN, HCl 2) PCC, CHCI 3) PhyP 1) dilute H2SO4 2) PCC, CH.CL 3) NH w 1) SOCI 2) EtMgBr 3) H.O ОН 1) KCN, HCl 2) H0 3) SOCI, 4) i 1) HCI | 2) HENNH. [H] 3) KOH,H,O, heat 1) RCO,H 2) LAIH 3) H.O 4)...
10. Write the structural formula for the principal organic product of each of the following reactions. (8 marks) 0 CH.CH,CH,COOH + CH- chchi- CH,CH-C-Cl CH.CH,OH b. ce CH-C-Cl + CHỊCH,CH,OH C HCOOH + CHỌCH,OH d. BONUS: Write out full reaction schemes for (a) the alka hydrolysis of methyl propanoate and sodium hydroxide, and (b) the acid hydrolysis of ethyl acetate and water. (2 bonus marks total)
4. Give the major organic product(s) for each of the following reactions or sequences of reactions. H Br 1. N.CN 2. NaOH,H,O, heat 3.H30 Ind o do CH,COOH 1. LiAlH, THF, heat 2.H,0 HO CH Br 1. NaCN, acetone 2.H30, heat h ome couco C:03, H30* он
2. Write the structure of the principal organic product(s) of the following reactions: (112 pts) (a) 2-chloropropane + lithium in diethyl ether (b) product of (a) with cyclohexanone, followed by dilute acid (c) benzoic acid + NaOH+H2O (d) hexanoic acid + Brą + PBrz (e) ethyl acetate + CH3CH2O- Nat in ethanol (f) ethyl acetoacetate + sodium ethoxide + 1-bromobutane (g) propanal + ethanol + dissolved HCl gas (h) (CH),CO K + CH I in (CH),COH solvent (i) 2,4-pentanedione +...
4. Complete the reactions below by supplying the reactant, reagent or product. (*pts each OH b H,0,HCI Heat O it CI d. (excess) 1. LAIH 2. H2O -CHCH PPh; 3 Name: f. 1. CHACHIMBI 2. H,0 1. LAIH 2. HO h. CuLi(CH 3)2 i. 1. LDA (1 equiv) 2. CHỊCH,C 5
2. Identify the principal organic product of each of the following reactions: (30 pts) (a) acetic anhydride and 2-pentanol (b) 4-methyl-3-penten-2-one and ammonia in water solution (c) acetophenone (methyl phenylketone) and benzaldehyde+KOH in ethanol solvent (d) methyl butanoate and LDA (lithium diisopropylamide) in THF solution, then ethyl iodide (e) butylamine and excess 1-iodobutane (1) acetanilide and LiAlH, in diethyl ether, followed by addition of water.
Homework Problems Give the name for each of the following: 9.1 COOH a. ОН CHy с. CH,-сн-сн,-соон d. (CH,CH2),CCOOH Draw the structural formula for each of the following compounds: 9.2 a. sodium hexanoate b. potassium acetate c. zinc benzoate d. calcium propanoate 9.3 Complete the following reactions: HP CH3 -C-OH CH CH,CH,OH а. + b. (CH),CCH,CH,соон + (СH),СНОН [H COOH с. + CH,CH2OH d. CH,(CH),COOH HP Но- Draw a structural formula for each of the following esters: a. cyclohexyl propanoate...
Give the product(s) of reaction of hexanal with each of the following reagents. 2. (0) носн,сн,он, н (b) 1. LIAIH, 2. H,0* (e) NH,он, н" (d) NH,NH2, KOH, heat (e) (CH),СHCH,CH— P(C, Нә» , н" (g) Ag, NH, H,O (h) CrOs, H,SO H,0 () 1. KCN, 2. H,SO MCPBA
Give the product(s) of reaction of hexanal with each of the following reagents. 2. (0) носн,сн,он, н (b) 1. LIAIH, 2. H,0* (e) NH,он, н" (d) NH,NH2, KOH, heat (e) (CH),СHCH,CH—...
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