Question

The best way to synthesize the following amine is: HN 1. NBS, hy 2. NaNH, NHÀ 1. HNO3 H2SO4 2. Fe, HCI 3. NaOH 1. Biz, FeBrz
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Answer #1

The best way to synthesize the product is option C.

The raction of methyl benzene with Br2, FeBr3 is a Selective reaction and gives higher percentage of para bromo methyl benzene product which further reacts with NaN3 to form azide and reduces to NH2 by H2, Ni to form the desired product.

Option B also forms the desired product but selectivity of Nitration reaction is less so ortho and para product both are formed which decreases the yield for desired product.

Option A and D do not form the desired product.

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