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9. Match each reaction to its single most likely major product or outcome in the box....
Match each reaction to its single most likely major product or outcome in the box. Place the Roman numeral of your choice on the line by the reaction. No answer may be used more than oncents) ОН CH3OH H2SO4 cat. OH a.) Lan i. -NH2 но ни b.) iii. HO^ iv. H NaOCHE CH3OH Lo c.) V. OH vi. 1. LIAIH4, ether 2. H300 d.) toi toi vii. HO NH2 -NH2 viii. e.)
Using the major product bank, match each reaction to its most
likely major product. Only include the MOST likely option.
---Major Product Bank---
---Reactions---
OH i to Lan ii. HON iii. HO iv. ما V. ОН vi. vii. HO NH2 ZI viii. ОН CH3OH H2SO4 cat. H -NH2 H NaOCH3 CH3OH 1. LIAIH4, ether 2. H30 ti bi -NH2
1. Match each reaction to its single most likely major product or outcome in the box. Place the Roman numeral of your choice on the line by the reaction. No answer may be used more than once. ОН HBr OH a.) i. ii. Br OH H2SO4 heat b.) iii. iv. No reaction OH Croz Br o H30 V. vi.
10. A synthetic scheme is shown, with reaction conditions in the box. Each arrow in the scheme has a Roman numeral. Match the correct conditions to each reaction by placing the appropriate letter after each Roman numeral on the answer page. Use each set of conditions no more than once. ii. ОН ili. HO ОН iv. HO Br Br2 H2SO4 heat a.) CHCI b.) NaBH4 c.) ethanol H20 1. LIAIH4, ether 2. H30 HBr d.) NaOCH3 e.) H2O f.) 8.)...
"ОН Step 1 Fill in the following reaction scheme based on the Roman numerals provided below: но Η Ν. HO HOH НО-Н Step 2 H-OH H-OH H ОН HO -Η HO -H НО. H HOH HO -H HO+H CH, OH CH OH CH OH Step 3 HCN cat. HCI H,0 HIO NH,OH NaBHA EROH - 11 III IV V NaOCH, Bra H.0 VII cat HCI CH,OH но" Pa/Baso Hy XI VI VIII х HNO H.O heat XI H,02 Fox(50) XII...
Match each reaction to the most likely major product.
Possible Major Products Below...
-ОН HBr Ста ОН H2SO4 heat ОН Croz H30 -он і. ii. Br iv. No reaction Br V. vi.
Which of the following reaction conditions would specifically target the anomeric carbon of the pyranose below: OH CH OH 20 НО. он HO cal. HCI H20 PaC, H2 II BnBr, NaH DMF, heat III TBDPSCI AgNO, IV HIO CH,COCH, cat. H,SO V cat. HCI CH,OH VII Pd/Baso H VIII VI O VI O O O VII O IV OV VII
OH Fill in the following reaction scheme based on the Roman numerals provided below: но H OH HO HO-H Step 1 HO-H Step 2 H H-OH H OH HOH HOH Step 3 HOH нон но-н HO-H CH, OH CH, OH CH, OH cal HCI HCN HIO NH, OH NaBH но EROH IV V NaOCH PdBaso H,09 BE HO VII cat HCI CH,OH VIII VI XI X HO, HNO, H.O heat XI Fe (50 XII BnB Nah DMF heat XIII ....
Using the bank of reaction conditions, complete the synthetic
scheme. Each condition should only be used one time.
BANK
iii. iv. ОН ОН ш. , м. , HO НО Br H2SO4 heat a.) b.) Br2 CHCI 1. LIAIH 4, ether 2. H30 NaBH4 ethanol H20 HBr d.) NaOCH3 h.) CH3OH H2O e.) f.) 9.) H30
Match each reaction with its reagents. HO 2 + enantiomer 3 ОН 4 + enantiomer + enantiomer 5 لح 6 OH 7 8 OH 9 to C НО. 10 Br + enantiomer Br 11 Br 12 red lockdown Reagents: A.) PB B.) NBS, hv D) NaOH E.) NaNH2 F.) Bra G.) HCI H.) Cl2, H2O 1.) HBO J.) H2 (1 eq), Pt K) Na, NH3 L.) H2SO4, H2O 0.) M.)1. Hg(OAc)2 2. NaBH4 N.) 1. mCPBA 2. H+, H2O P.)...