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draw the structure for the major organic product of each of the following reactions. HOTH PHNHNH,...
draw the structure for the major organic product of each of
the following reactions.
PhNHNH | 16. CHO Нон н+он (3 equiv.) нон но-н CH2OH
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) Ç(CH3) 30 1) PhČCI, AICI: 11. 2) Et2NH, H2, Raney-Ni, heat 12. ÇO,Me 1) EtMgBr (2 equiv.) 2) H20, H30* O 13. CNH2 1) Bry, NaOH, H,0 O 2) (CH3)2CHCCI, pyridine 14. Brą, H20 CHO HOEH H HOH НЕОН HO+H CH OH 15. H2N. ***** оо CO2 1) (CH3),COCOCOC(CH3)3 2) -N: C: NH- 16. CHO нон PhNHNH2 H+OH (3 equiv.)...
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) Ç(CH3)3 o 11. 1) PhČCI, AICI 2) EtANH, H2, Raney-Ni, heat 12. ÇO Me 1) EtMgBr (2 equiv.) 2) H20, H30* 13. o CNH2 1) Brą, NaOH, H20 o 2) (CH3)2CHCCI, pyridine 14. CHO HO+H H-OH Br2, H20 H-HOH HO+H CH2OH
15. HN оо CO; 1) (CH3)3COCOCOC(CH3)3 2) -N:CENH CHO HOTH PhNHNH | 16. HOH (3 equiv.) HO+H н+он CH OH 17. Use ANY needed reagents to effect the following transformation. (30 points) starting material product
15. HN оо CO; 1) (CH3)3COCOCOC(CH3)3 2) -N:CENH CHO HOTH PhNHNH | 16. HOH (3 equiv.) HO+H н+он CH OH 17. Use ANY needed reagents to effect the following transformation. (30 points) starting material product
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) o 11. Ç(CH3)3 1) CH3CCI, AICI: 2) (CH3)2NH H2, Raney-Ni, heat 12. CO2Me 1) PhMgBr (2 equiv.) 2) H20, H30+ O 13. CNH2 1) Brą, NaOH, H20 o 2) CH3CCI, pyridine 14. HNO3 CHO HOEH НЕОН H OH HO+H CH2OH 4
II. Draw the structure for the major organic product of each of the following reactions. 11. Ç(CH3) 30 1) PhČCI, AICI: 2) Et2NH, H2, Raney-Ni, heat 12. ÇO2Me 1) EtMgBr (2 equiv.) 2) H20, H30+ 13. o CNH2 1) Br2, NaOH, H20 O 2) (CH3)2CHČCI, pyridine 14. Br2, H20 CHO HOEH H -OH H-OH HOEH CH2OH
draw the major product
14. HNO, CHO Но+н H-HOH H-HOH HO+H CH2OH 15. oo HNcO; 1) (CH3),COCOCOC(CH3) 3 o N:C:NH/ Ph сно HOTH PHNHNH2 16. HOH (3 equiv.) H +OH HO+H CH2OH
draw the structure for the major organic product of each of the
following reactions.
14. HNO, CHO Но+н -ОН H -ОН НО-н CH OH
11. Predict the major organic product(s) for the following reactions. If there is no reaction write N.R. (6 points each, 72 points total) Show the correct stereochemistry when needed!! -OH HSO heat 1) 0, (2 equiv.) 2) Meys (2 equiv.) HC104 excess CHO NaBH4 (excess) HO CHOH Br ON HỌ, PHÚC