1- Include a concise summary of the remaining starting material % for each substituent
2- Include general rule that correlates EDG/EWG behavior of a substituent and the preferred regiochemistry of the reaction
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1- Include a concise summary of the remaining starting
material % for each substituent
2- Include...
1-Include a concise summary of the remaining starting material % for each substituent 2-Include the general...
1-Include a concise summary of the remaining starting
material % for each substituent
2-Include the general rule that correlates EDG/EWG
behavior of a substituent to its activating/deactivating
effect
3-Include a concise summary of the major product(s) of
each substituent
4- Include general rule that correlates EDG/EWG behavior
of a substituent and the preferred regiochemistry of the
reaction
ОСН, ОСН, ОСН, OCHZ NO2 HNO3 H2SO4 + + NO2 anisole 0-nitroanisole (31%) m-nitroanisole (2%) NO2 p-nitroanisole (67%)
1 - Discuss correctly why each substituent favors the observed major product. (e.g. stability of the...
1 - Discuss correctly why each substituent favors the
observed major product. (e.g. stability of the carbocation
intermediate resonance hybrid, steric hindrance at reaction
location) How does the stability of the intermediates (from the
handout done during the lab) rationalize the observed products
formed? Do more stable intermediate lead to more products or
less
2- Create a general rule that correctly correlates
EDG/EWG behavior of a substituent and the preferred regiochemistry
of the reaction. Where do EDGs tend to substitute?...
Which of following is the best starting material for the reaction below? 1. (CH3)2NH ? 2....
Which of following is the best starting material for the reaction below? 1. (CH3)2NH ? 2. LIAIHA 3. H20 'N NK CN NH2 What is the major product in the following reaction? 1. DIBAL 2. H20 O H O OH OH СІ Which reaction sequence would accomplish this transformation? CN H2SO4/HNO3 Br2 NaNO2/HCI CuCN O Br2/FeBr3 H2SO4/HNO3 KF NaNO2/HCI O H2SO4/HNO3 Zn(Hg)/HCI NaNO2/HCI CuCN o H2SO4/HNO3 Zn(Hg/HCI NaNO2/HCI HBF4
2) Predict the order of reactivity (1=least, 4=most) of primary, secondary, tertiary, and aryl halides toward...
2) Predict the order of reactivity (1=least, 4=most) of
primary, secondary, tertiary, and aryl halides toward nucleophilic
displacement by an SN1 reaction mechanism. Explain
3) Give a detailed summary of the chemistry in both reactions
SN2 and SN1 in details please for both reactions. include any
general statements about the experiments.
LAB)o Organic Chemistry I Lab CHEM 3512 Nueleophilic Substitution Reactions: Sl vs S2 To review Sul, S2, El and E2 reactions and mechanisms and compare and contrast the effect...
1-Include a concise summary of the remaining starting
material % for each substituent
2-Include the general rule that correlates EDG/EWG
behavior of a substituent to its activating/deactivating
effect
3-Include a concise summary of the major product(s) of
each substituent
4- Include general rule that correlates EDG/EWG behavior
of a substituent and the preferred regiochemistry of the
reaction
ОСН, ОСН, ОСН, OCHZ NO2 HNO3 H2SO4 + + NO2 anisole 0-nitroanisole (31%) m-nitroanisole (2%) NO2 p-nitroanisole (67%)
1 - Discuss correctly why each substituent favors the
observed major product. (e.g. stability of the carbocation
intermediate resonance hybrid, steric hindrance at reaction
location) How does the stability of the intermediates (from the
handout done during the lab) rationalize the observed products
formed? Do more stable intermediate lead to more products or
less
2- Create a general rule that correctly correlates
EDG/EWG behavior of a substituent and the preferred regiochemistry
of the reaction. Where do EDGs tend to substitute?...
Which of following is the best starting material for the reaction below? 1. (CH3)2NH ? 2. LIAIHA 3. H20 'N NK CN NH2 What is the major product in the following reaction? 1. DIBAL 2. H20 O H O OH OH СІ Which reaction sequence would accomplish this transformation? CN H2SO4/HNO3 Br2 NaNO2/HCI CuCN O Br2/FeBr3 H2SO4/HNO3 KF NaNO2/HCI O H2SO4/HNO3 Zn(Hg)/HCI NaNO2/HCI CuCN o H2SO4/HNO3 Zn(Hg/HCI NaNO2/HCI HBF4
2) Predict the order of reactivity (1=least, 4=most) of
primary, secondary, tertiary, and aryl halides toward nucleophilic
displacement by an SN1 reaction mechanism. Explain
3) Give a detailed summary of the chemistry in both reactions
SN2 and SN1 in details please for both reactions. include any
general statements about the experiments.
LAB)o Organic Chemistry I Lab CHEM 3512 Nueleophilic Substitution Reactions: Sl vs S2 To review Sul, S2, El and E2 reactions and mechanisms and compare and contrast the effect...
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