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pts) 11. Show all intermediate products. After steps #1 and #2, then, hydrolize the product NH2...
9-17. Syntheses: draw / provide the likely organic product(s) generated in each of the reactions (or reaction sequences) below. As appropriate, pay attention to regiospecificity (new bond formation and location in the product formed) and stereochemistry (direction in space of new bond[s] formed). Indicate ALL likely products; where one product does not predominate, label / indicate the MAJOR product(s). Where a product mix results, indicate the MINOR or TRACE product(s). (12 pts) 9. First, exhaustively alkylate, then add Ag20 and...
Write the products of these reactions
-NH2 1. NaNO2, HCI 2. CuCN 1. N(CH3)3 2. Ag20, H20 3.A 1. LAIHA 2. H20 NaN3 1. LATHA 2. H2O NaCN 1. LIAH 2. H20 Br NaCN H. Ni HNO3 H2SO4 NaOH H20 1. NaNO2 HCI 2. HBF 4 CH3 HNO3 Na Cr207 H2SO4 H2SO4 Sn HCI 1. NaNO2 HCI 2. CuCN
Predict the major product of the following reaction. NH2 1. NaNO2, HCI 2. CuCN NH2 CN NH2 CH_NH2 CN NC IV II -
Please show mechanisms
and steps involved
30. What is the major organic product obtained from the following reaction? Br 1. NaNO2. HCI 2 HBr. CuB NH2 CH3 CH3
(4 pts each, unless otherwise noted, 47 pts total) 9-17. Syntheses: draw / provide the likely organic product(s) generated in each of the reactions (or reaction sequences) below. As appropriate, pay attention to regiospecificity (new bond formation and location in the product formed) and stereochemistry (direction in space of new bond(s) formed). Indicate ALL likely products; where one product does not predominate, label / indicate the MAJOR product(s). Where a product mix results, indicate the MINOR or TRACE product(s). (12...
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1. Show the expected product(s) of the following reactions. For products containin or cis/trar asymmetric carbon atoms, indicate relative stereochemistry (syn/anti relationships) and/or whether a racemic mixture is produced. (8 pts each) 1. HNO3, H2so4 NO 2. Fe, HCI OCH3 3. NaNO2 aq. HCI 4, CuCN, Δ сно но 1. Br2 H20 2. Fe SO)S b. HO- -H OH s CH2OH 1. SOCI2 2. NH3 H3C 3. Br2 NaOH, H2O 1. KOH 2. PhCH2CH Br 3. NH2NH2 d....
provide the structure of the major product in the reaction below 1) CH, (excess) 2) Ag, 3) A CH3 24) Provide the structure of the major organic product in the reaction below. N(CH3)2 -CH 1. MCPBA ZA 25) Provide the structure of the product in the reaction below. What is the name of this type of compound? NH2 NaNO2 HCI CH2CH3 26) Provide the structure of the major organic product in the reaction below. 1. NaNO2, HC 2. CUCN CH3
1. (2 pts) Predict the product for the following transformation. NH2 1. Ac 0 2. t-BUCI, AICI: 3. KOH, H2O 4. NaNO2, HCI 5. Cuci Me
Which of following is the best starting material for the reaction below? 1. (CH3)2NH ? 2. LIAIHA 3. H20 'N NK CN NH2 What is the major product in the following reaction? 1. DIBAL 2. H20 O H O OH OH СІ Which reaction sequence would accomplish this transformation? CN H2SO4/HNO3 Br2 NaNO2/HCI CuCN O Br2/FeBr3 H2SO4/HNO3 KF NaNO2/HCI O H2SO4/HNO3 Zn(Hg)/HCI NaNO2/HCI CuCN o H2SO4/HNO3 Zn(Hg/HCI NaNO2/HCI HBF4
E) V 57. Identify the best product for the reaction. NH2 1. NaNO2, HCI, O C 2. CuCN A) CHANH B) NH₂ CEN D) CH= H