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page 13 8 11. Draw the complete mechanism for the following reaction. Assume that this reaction...
11. Draw the complete mechanism for the following reaction. Assume that this reaction takes place via El mechanism. (Hint: a series of carbocation rearrangements will occur) 1. Weak Base EtOH HO но"
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11. Draw the complete mechanism for the following reaction. Assume that this reaction takes place via E1 mechanism. (Hint: a series of carbocation rearrangements will occur) H H нүн Weak Base EtOH I HO HO
11. Draw the complete mechanism for the following reaction. Assume that this reaction takes place via El mechanism. (Hint: a series of carbocation rearrangements will occur) HH Weak Base EtOH н HO HO 13. Using acetylene as one of the starting materials and any other reagents required, outline a synthetic route (including all reagents, proper order of addition and the product for each step) to obtain the following compound (with the stereochemistry shown):
12. Complete the following reaction. Draw the complete, detailed mechanism for the following reaction. Assume that it takes place via SN mechanism. Will the reaction produce a single stereoisomer, or will it produce a mixture of stereoisomers? If it produces a mixture, then will the isomers be produced in equal amounts? Br HS ?
12. Complete the following reaction. Draw the complete, detailed mechanism for the following reaction. Assume that it takes place via SN mechanism. Will the reaction produce a single stereoisomer, or will it produce a mixture of stereoisomers? If it produces a mixture, then will the isomers be produced in equal amounts? Br HS ?
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12. Complete the following reaction. Draw the complete, detailed mechanism for the following reaction. Assume that it takes place via SN mechanism. Will the reaction produce a single stereoisomer, or will it produce a mixture of stereoisomers? If it produces a mixture, then will the isomers be produced in equal amounts? Br ? + HS
2 # 3 $ 4 % 5 6 tab Q W Y page 14 B 8 12. Complete the following reaction. Draw the complete, detailed mechanism for the following reaction. Assume that it takes place via SN mechanism. Will the reaction produce a single stereoisomer, or will it produce a mixture of stereoisomers? If it produces a mixture, then will the isomers be produced in equal amounts? Br. ? + HS
30. Late papers not accepted. Work Independently. 1. Predict the most likely reaction mechanism (SN1, SN2, E1, E2) and draw all products. CH₂ Na O=CH₂ Hic Br 2 Draw complete mechanism with arrows for the SNI/E1 mechanism. Check for carbocation rearrangements CH3 + H2O 3. Which is the major product for the following reaction? Y CH + NaOH CH HO HO H₃ CH₂ H₃ HOCH CH₂ H₃ CHE CH₂ CH₂ CH3 CH 4. Name the following including the R/S, E/Z...
Predict the most likely reaction mechanism (SN1, SN2, E1, E2) and draw all products. Nato=CH₂ E2 ran Br major 2. Draw complete mechanism with arrows for the SN1/E1 mechanism. Check for carbocation rearrangements. CH3 SMI 애 + H₂O7
3. Additional question. Propose a mechanism for the following reaction. You don't have to draw all resonance forms, but some important resonance forms should be shown. Hints: the mechanism involves two sequential carbocation rearrangements and a spirocyclic carbocation intermediate. H2SO4 heat (rac) OH