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1) Provide structures for A-J in the following roadmap. H NaN LiAIH SOCI, CHINH + B...
Extra Credit II 1) Provide structures for A-J in the following roadmap. H NaN, CHANH, LiAIH...
Extra Credit II 1) Provide structures for A-J in the following roadmap. H NaN, CHANH, LiAIH soa. B D CH,OH (xs) CH, OH E+ А H, A CHO, 1) KOH, H20 2) H30* NH, SOC, 2) Propose a mechanism for the following transformation, including arrows to describe electron flow, and all intermediates. NaOH
1) Provide structures for A-J in the following roadmap. H NaN CH,NH LAIRL CH,OH (XS) CH,OH...
1) Provide structures for A-J in the following roadmap. H NaN CH,NH LAIRL CH,OH (XS) CH,OH SOCI, E A B D Fr, Cafe 1) KOH, HO 2) H0 NH, SOCI: 2) Propose a mechanism for the following transformation, including arrows to describe electron flow, and all intermediates. NaOH HO OH
Two pages 30 1) Provide the structure of the major product for ten of the following...
Two pages
30 1) Provide the structure of the major product for ten of the following fifteen reactions. Assume enough reagent to react with all functional groups capable of reaction. NH NaBH,CN 1) MEB 2)H,0 HO NH NaN, 1) NaNO,, H.SO. NH, 2) HBF. KOH 1) odo H30 opas 1) LiAIH, 2) H.O OH h) NH H,SO H.0, A CN 1 cui Oculi O .-780 Br SOCI, NH 1) CHI (xs) 2) Ag,0,H,O, tion N'HSO, H20 Cu_0 Br corond me...
signment: Amines beint days 2/30 answered H23.8 - Level 3 Homework. Unanswered Which of the following...
signment: Amines beint days 2/30 answered H23.8 - Level 3 Homework. Unanswered Which of the following reaction schemes would not give the product indicated? NaN, H2, Pt A CI N NH 1. H,O, heat 2. NaOH (work-up) 1. KOH B NH 2. ΝΗ, 0 CI С NaCN 1. LIAIH: 2. H2O CI CN NH D NH OH 1. SOCI 2. NHS 1. LIAIHE 2. H. o NH PE DELL
Determine the structures of compounds K-Y in the following reaction sequences. NH MgBr 1. LIAIH, ether...
Determine the structures of compounds K-Y in the following reaction sequences. NH MgBr 1. LIAIH, ether 2. H2O Мt. NaOH 2. CH,OH 2. CHỊCH, B pBig H HR 1. LIAJH, other 2. H2O 1. PICHg) 2. Bu-i OH PBrys NaCN1.CHMgBr, ether 2. CHCH 1. LIAIH, other W 2. H20 CH,(excess) NaOH, A HOOCH HOC CHEV → W NaOCH CH3, y CH,CH,OH 2. NHCI Suggest how you would synthesize each of the following from Acetophenone (acetophenone), using any reagents necessary. (Hint:...
Determine the structures of compounds K-Y in the following reaction sequences. NH MgBr Ho 1. LIAIH4, ether 2. HO 1....
Determine the structures of compounds K-Y in the following reaction sequences. NH MgBr Ho 1. LIAIH4, ether 2. HO 1. NaOH → M- Mchu >N 2. CH CH Br 2. CH,OH ola.ompelen 1. LIAIH., ether PBrs > p 1. PICH) » Q" 2. Bu- H R 2. H2O NaCN OH PBrya 1 V 1. LIAIH, ether 2. 0 .CHMgBrother 2. CH,OH Challe CHET (excess) NaOH, a HGG OCH CHO X- NaOCH,CHY CH.CH OH 2. NHCI
17. Use ANY needed reagents to effect the following transformation. (30 points) starting material product List...
17. Use ANY needed reagents to effect the following transformation. (30 points) starting material product List of Reagents -N:C:N- KMnO4, H2SO4 8 00 (CH3),COCOCOC(CH3)3 Ag(NH3)2+, 120 Fe, HCI KMnO4, NaOH, H2O, cold AlCl3 Bra (excess), NaOH (excess), H20 Brz, Fe Br2, H20 Br2, H2O, H3O+ Br2, hy Br2, NaOH (excess), H2O Br2, P Buli CF3CO,H CH;=0 Formaldehyde оо CH3COCCH o CH_CC1, pyridine H2, Lindlar's catalyst H2.Pd/C H2, Pa/C, high pressure H, Raney-Ni HANNH HENNH, KOH, (HOCH2CH2)20, heat H2O H20, H2SO4,...
a.) H H_Cro acetone b.) 1. XS KMnO,/KOH/HOIA 2.H30* c.) ni XS NaBH,, H,0 H OH...
a.) H H_Cro acetone b.) 1. XS KMnO,/KOH/HOIA 2.H30* c.) ni XS NaBH,, H,0 H OH d.) o 1. XS LAIH/THF/-78 °C 2. H20 H OH e.) NaNH / lig NH3 f.) Br 1. Mg/THE 2. CO2 3. H30 9.) Ph Ph cyclopropene HF CH h.) OH 1. PCCICH.CH 2. Pri 3. N,Cag) 1. LITHF 2.CO 3. NH.Ca) HNO, NH 1. HNO () 2. NaSCH CH.CH AICI, 3-chloro-2-methylpentane m.) 1.Pr.CI. AICI 2. NBS, CCH n.) OH XS H.COM acetone OH...
7. Predict the major organic product or provide reagents needed to complete each reaction. 1. CH3NH2...
7. Predict the major organic product or provide reagents needed to complete each reaction. 1. CH3NH2 (a-b) excess 2. LIAIHA 3. H20 ia -NH ?? excess (c-d) HO NH2 triethylamine ? (e-f) CEN 1. CHẠMgBr 2. H20, H NH2 (g-h) H20, H* H2. Pd (1-1) CH3NH2 4 products (m) 1. LAIH 2. H2O, H & NH (n) 1. LiAIH4 2. H20, H+ 8. Predict the four possible Aldol condensation products and their dehydration products. KOH, H20.A + H 1. Predict...
Extra Credit II 1) Provide structures for A-J in the following roadmap. H NaN, CHANH, LiAIH soa. B D CH,OH (xs) CH, OH E+ А H, A CHO, 1) KOH, H20 2) H30* NH, SOC, 2) Propose a mechanism for the following transformation, including arrows to describe electron flow, and all intermediates. NaOH
1) Provide structures for A-J in the following roadmap. H NaN CH,NH LAIRL CH,OH (XS) CH,OH SOCI, E A B D Fr, Cafe 1) KOH, HO 2) H0 NH, SOCI: 2) Propose a mechanism for the following transformation, including arrows to describe electron flow, and all intermediates. NaOH HO OH
Two pages
30 1) Provide the structure of the major product for ten of the following fifteen reactions. Assume enough reagent to react with all functional groups capable of reaction. NH NaBH,CN 1) MEB 2)H,0 HO NH NaN, 1) NaNO,, H.SO. NH, 2) HBF. KOH 1) odo H30 opas 1) LiAIH, 2) H.O OH h) NH H,SO H.0, A CN 1 cui Oculi O .-780 Br SOCI, NH 1) CHI (xs) 2) Ag,0,H,O, tion N'HSO, H20 Cu_0 Br corond me...
signment: Amines beint days 2/30 answered H23.8 - Level 3 Homework. Unanswered Which of the following reaction schemes would not give the product indicated? NaN, H2, Pt A CI N NH 1. H,O, heat 2. NaOH (work-up) 1. KOH B NH 2. ΝΗ, 0 CI С NaCN 1. LIAIH: 2. H2O CI CN NH D NH OH 1. SOCI 2. NHS 1. LIAIHE 2. H. o NH PE DELL
Determine the structures of compounds K-Y in the following reaction sequences. NH MgBr 1. LIAIH, ether 2. H2O Мt. NaOH 2. CH,OH 2. CHỊCH, B pBig H HR 1. LIAJH, other 2. H2O 1. PICHg) 2. Bu-i OH PBrys NaCN1.CHMgBr, ether 2. CHCH 1. LIAIH, other W 2. H20 CH,(excess) NaOH, A HOOCH HOC CHEV → W NaOCH CH3, y CH,CH,OH 2. NHCI Suggest how you would synthesize each of the following from Acetophenone (acetophenone), using any reagents necessary. (Hint:...
Determine the structures of compounds K-Y in the following reaction sequences. NH MgBr Ho 1. LIAIH4, ether 2. HO 1. NaOH → M- Mchu >N 2. CH CH Br 2. CH,OH ola.ompelen 1. LIAIH., ether PBrs > p 1. PICH) » Q" 2. Bu- H R 2. H2O NaCN OH PBrya 1 V 1. LIAIH, ether 2. 0 .CHMgBrother 2. CH,OH Challe CHET (excess) NaOH, a HGG OCH CHO X- NaOCH,CHY CH.CH OH 2. NHCI
17. Use ANY needed reagents to effect the following transformation. (30 points) starting material product List of Reagents -N:C:N- KMnO4, H2SO4 8 00 (CH3),COCOCOC(CH3)3 Ag(NH3)2+, 120 Fe, HCI KMnO4, NaOH, H2O, cold AlCl3 Bra (excess), NaOH (excess), H20 Brz, Fe Br2, H20 Br2, H2O, H3O+ Br2, hy Br2, NaOH (excess), H2O Br2, P Buli CF3CO,H CH;=0 Formaldehyde оо CH3COCCH o CH_CC1, pyridine H2, Lindlar's catalyst H2.Pd/C H2, Pa/C, high pressure H, Raney-Ni HANNH HENNH, KOH, (HOCH2CH2)20, heat H2O H20, H2SO4,...
a.) H H_Cro acetone b.) 1. XS KMnO,/KOH/HOIA 2.H30* c.) ni XS NaBH,, H,0 H OH d.) o 1. XS LAIH/THF/-78 °C 2. H20 H OH e.) NaNH / lig NH3 f.) Br 1. Mg/THE 2. CO2 3. H30 9.) Ph Ph cyclopropene HF CH h.) OH 1. PCCICH.CH 2. Pri 3. N,Cag) 1. LITHF 2.CO 3. NH.Ca) HNO, NH 1. HNO () 2. NaSCH CH.CH AICI, 3-chloro-2-methylpentane m.) 1.Pr.CI. AICI 2. NBS, CCH n.) OH XS H.COM acetone OH...
7. Predict the major organic product or provide reagents needed to complete each reaction. 1. CH3NH2 (a-b) excess 2. LIAIHA 3. H20 ia -NH ?? excess (c-d) HO NH2 triethylamine ? (e-f) CEN 1. CHẠMgBr 2. H20, H NH2 (g-h) H20, H* H2. Pd (1-1) CH3NH2 4 products (m) 1. LAIH 2. H2O, H & NH (n) 1. LiAIH4 2. H20, H+ 8. Predict the four possible Aldol condensation products and their dehydration products. KOH, H20.A + H 1. Predict...
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