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A. Enantiomers: Certain substances have the unique property of rotating the plane of plane-polarized light. Such...
3. Cyclic compounds The presence of the ring in all but very large ring cyclic molecules prevents full rotation of the ring atoms. For this reason, stereoisomerism may also occur in cyclic molecules. a) Prepare a model of cyclohexane, C6H12. Draw the condensed formula. b) Build a model of methylcyclohexane (C7H14) by replacing one of the hydrogens of cyclohexane with a methyl group. Draw the skeletal formula for methylcyclohexane. 2 c) How many different isomers exist for methylcyclohexane (CyH34)? d)...
TU c) Start with the model of propene built in 3a), substituting different hydrogen atoms of propene with a methyl group to form isomers of butene, CaHg. How many different isomers exist for butene (C4Hg)? Prepare models and draw the Lewis structures for each of the isomers. d) Two of isomers of butene comprise a pair of stereoisomers. Draw the skeletal structures and include IUPAC names for the cis and trans isomers. Recall in the cis isomer both methyl groups...
3. Cyclic compounds The presence of the ring in all but very large ring cyclic molecules prevents full rotation of the ring atoms. For this reason, stereoisomerism may also occur in cyclic molecules. a) Prepare a model of cyclohexane, CH12. Draw the condensed formula b) Build a model of methylcyclohexane (C;H2a) by replacing one of the hydrogens of cyclohexane with a methyl group. Draw the skeletal formula for methylcyclohexane. c) How many different isomers exist for methylcyclohexane (C-Ha)? d) Start...
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4. Enantiomers.- THIS FOLLOWING EXERCISES ON PAGES 6 AND 7 ARE TO BE DONE AS A GROUP WITH THE LAB INSTRUCTOR!!!! a) Construct a model consisting of a tetrahedral carbon center with four different atoms attached - use white, green, orange and violet balls. Each color represents a different group or atom attached to the central carbon. Does this model have a plane of symmetry? Note 1: a plane of symmetry can be described as a cutting...
Week 10- Constitutional isomers Constitutional isomers have the same molecular formula, but their atoms are bonded in different orders. These may be further distinguished as chain isomers, which differ only in hydrocarbon chain structure, positional isomers, which differ in the location of a functional group, and functional group isomers which differ in the nature of their functional groups. Typically chain and position isomers show only modest differences in their physical and chemical properties, while functional group isomers differ greatly from...
Week 1l-seed somers.cf G Sotes of Teile Week 11-Stereoisomers.pdt X file:///C/Users/hp/Downloads/Week 11 Stereoisomers.pdf Automatic Zoom aj Prepare a mouer or cyclonexante, C6H12. Draw the condensed mommula. b) Build a model of methylcyclohexane (C7H14) by replacing one of the hydrogens of cyclohexane with a methyl group. Draw the skeletal formula for methylcyclohexane. 2 c) How many different isomers exist for methylcyclohexane (C7H14)? d) Start with the model of methylcyclohexane built in 4b), substitute different hydrogen atoms on the carbon atoms adjacent...
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PART 3: 2,3-BUTANEDIOL CH-CH(OH)-CH(OH)-CH, mirror images, not superimposable Build as many models of 2,3-butanediol as you can. First, attach two carbons with a single bond. To each carbon add one carbon, one hydrogen, and one oxygen. To complete the structure, Ti the remaining hydrogen atoms. Remember, a model is not different if it is completely superimposable on one already constructed! 13. How many stereochemically different models are possible for 2,3-butanediol? 14. What characteristic does one of these...
CHCH(OH)-CH(OH)-CH3 PART 3: 23-BUTANEDIOL Build as many models of 2.3-butanediol as you can. First, attach two carbons with a single bond To each carbon add one carbon, one hydrogen, and one oxygen. To complete the structure. fill in the remaining hydrogen atoms. Remember, a model is not different if it is completelv superimposable on one already constructed! 13. How many stereochemically different models are possible for 2.3-butanediol? 14. What characteristic does one of these models have that makes it different?...
EXPERIMENT W12: ORGANIC STRUCTURES AND MOLECULAR MODELS 7. Build models of all possible isomers of CHCl, and then draw and name the Lewis Structure for each Isomers that differ in their relative geometry (or orientation) across a rigid double bond are called geometrie isomers. Circle your geometric isomers. Label each molecule as polar or non-polar. Certain physical properties of molecules, such as boiling point, are dependent on the degree of polanty of a molecule. What hybrid orbital is used by...
4. Absolute Configuration and R/S Sequence Rules. In 3 you constructed models with two stereocenters that represented 4 stereoisomers. 2,3-Dibromobutanoic acid exemplifies such a compound, Make models for the isomers of this compound. a. Draw solid/dashed-wedge structures for the 4 possible stereoisomers and label the enantiomers and diastereomers. b. Specify the sequence priority for the substituents on carbon-2 and carbon-3. Label each structure with the proper R/S notation in the drawings above, for example (2R, 35). d. Draw Newman projections...