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page 3 of 5 Chem 231, Assignment 5 Part II - Reactions (16 marks] Draw the...
Part II - Reactions (16 marks] Draw the expected major product(s) for each of the following...
Part II - Reactions (16 marks] Draw the expected major product(s) for each of the following reactions. Question Answer 8. 1. NaH OH ? 2. OTs 9. NBS ? major product 10. Nal Br ? Acetone Br 11. 1. NaNH2 H3C-CECH ? 2. OTS 12. OH Br NaOH ? cyclic compound 13. OH HBT ? 14. ? OH cat. H2SO4 H20 Room temp. 15. Br MeOH
Thank you! Chem 202, Summer 2020 Homework Packet 5 part 2 (Subt and Elim Reactions) 5....
Thank you!
Chem 202, Summer 2020 Homework Packet 5 part 2 (Subt and Elim Reactions) 5. Alcohol Reactions Predict the product(s) OR starting material of the following reactions. Remember, Hydride shifts are possible if/when a more stable carbocation can exist (depending on reaction mechanism)! Put your answers in the indicated boxes (only organic molecules HCI a H20 H2SO4 (cat.) b. + H2O Δ MAJOR product Minor product H,904 (cat.) + H2O HBr d. + H20 OH A MAJOR product Minor...
Problem 10. Draw the structure of the major product formed in each of the following reactions....
Problem 10. Draw the structure of the major product formed in each of the following reactions. Consider the resulting stereochemistry of the products formed (6p) KBr ng MeOH NaF DMSO H2(g), Pd (cat.) c) Solvent OH 1) NaH (strong base) THF (solvent) d) 2) CI Nal e) CI Acetone
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions...
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
23. Select the product for the reaction shown: NaOH Ph H2O, THE 5°C ? OH OH...
23. Select the product for the reaction shown: NaOH Ph H2O, THE 5°C ? OH OH Ph Ph A. Ph B. C. Ph D. 3 27. Select the needed sequence of reactions to lead from the starting material to the desired product: OH OH A. PCC / Nah, MeOH / LDA, acetaldehyde / dil. HCI ? B. H2CrO4 / LDA, Mel / LDA, propanal i dil. HCI C. MCPBA / Nah, MeBr / Nah, propyl-1 / KOH D. NBS /...
Organic chem please help 3. Each of the following reactions gives a substitution product. Identify the...
Organic chem please help
3. Each of the following reactions gives a substitution product. Identify the major product in each case and indicate whether the reaction is likely to proceed via a bimolecular (SN2) or a unimolecular (SN1) mechanism. (8 pts) SO2CF3 Nal a) acetone CH3OH b) OMs 80% H2O CH3CH2OH c) Br NaCN DMF d)
Unit 3 Hinw '3 SNİSNDELE2 1. Give the major product(s) for the following reactions. Indicate the...
Unit 3 Hinw '3 SNİSNDELE2 1. Give the major product(s) for the following reactions. Indicate the mec reaction occurs, write "no reaction. s) in operation. If no KOC(CH) (CH COH b. H3C NaNH2 NHy Nal H3C H2CH-CH3 CH,COCH CH OH CH3 2. Give the mechanism of each of the following reactions. NaCN CH CH CHCN NaBr a. CH,CH,CH Br acetone HSCH,CH (CH) CSCH,CH3 HBr Cl + NaCI + CH OH NaOCH CH3OH Br CH OH CH3
2. Predict the major organic product(s) of the reactions below. Assume 1 equivalent of reagent unless...
2. Predict the major organic product(s) of the
reactions below. Assume 1 equivalent of reagent unless otherwise
stated, it's a solvent, or an oxidizing/reducing agent. Do consider
stereochemistry and regioselectivity.
2. Predict the major organic product(s) of the reactions below. Assume 1 equivalent of reagent unless otherwise stated, it's a solvent, or an oxidizing/reducing agent. Do consider stereochemistry and regioselectivity. (3 points each; 15 points total) A. Me 1. HNO3 2. O3 3. DMS 1. mCPBA, DCM (1 equiv) 2....
Complete the following reaction with the major product Reactions: complete the following reaction with the major...
Complete the following reaction with the major
product
Reactions: complete the following reaction with the major product HBr он 1- OH POCl3 pyridine 2- H2SO4 OH 3- Hl 4- H20 H3PO4 5- Cl2 H20 7- 1) BH2-THF 2) H202, KOH 8- 2) 9- 1) BH3-THF 10- DLL 10- Date: G# : 12, and 13- Br H20 но 2) NaH 14, and 15- ) NaOH i NaOH 2 dil H.0 3) PBr 3)HBr F6 FZ F8
4. Draw the organic product of these reactions. Note that in so some cases, a 2-step...
4. Draw the organic product of these reactions. Note that in so some cases, a 2-step process is written in this form. 1. reagents for 1st step REACTANT - PRODUCT 2. reagents for 2nd step OH + HB m i + HCI- + HCI + conc. H2SO4(aq) heat OH 1. NaOH 2. 1. mCPBA 2. H30+ 1. NaH CrO3, H2SO4(aq) OH acetone 5. State the major pathway by which these reactions wo product of that pathway. way by which these...
Part II - Reactions (16 marks] Draw the expected major product(s) for each of the following reactions. Question Answer 8. 1. NaH OH ? 2. OTs 9. NBS ? major product 10. Nal Br ? Acetone Br 11. 1. NaNH2 H3C-CECH ? 2. OTS 12. OH Br NaOH ? cyclic compound 13. OH HBT ? 14. ? OH cat. H2SO4 H20 Room temp. 15. Br MeOH
Thank you!
Chem 202, Summer 2020 Homework Packet 5 part 2 (Subt and Elim Reactions) 5. Alcohol Reactions Predict the product(s) OR starting material of the following reactions. Remember, Hydride shifts are possible if/when a more stable carbocation can exist (depending on reaction mechanism)! Put your answers in the indicated boxes (only organic molecules HCI a H20 H2SO4 (cat.) b. + H2O Δ MAJOR product Minor product H,904 (cat.) + H2O HBr d. + H20 OH A MAJOR product Minor...
Problem 10. Draw the structure of the major product formed in each of the following reactions. Consider the resulting stereochemistry of the products formed (6p) KBr ng MeOH NaF DMSO H2(g), Pd (cat.) c) Solvent OH 1) NaH (strong base) THF (solvent) d) 2) CI Nal e) CI Acetone
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
23. Select the product for the reaction shown: NaOH Ph H2O, THE 5°C ? OH OH Ph Ph A. Ph B. C. Ph D. 3 27. Select the needed sequence of reactions to lead from the starting material to the desired product: OH OH A. PCC / Nah, MeOH / LDA, acetaldehyde / dil. HCI ? B. H2CrO4 / LDA, Mel / LDA, propanal i dil. HCI C. MCPBA / Nah, MeBr / Nah, propyl-1 / KOH D. NBS /...
Organic chem please help
3. Each of the following reactions gives a substitution product. Identify the major product in each case and indicate whether the reaction is likely to proceed via a bimolecular (SN2) or a unimolecular (SN1) mechanism. (8 pts) SO2CF3 Nal a) acetone CH3OH b) OMs 80% H2O CH3CH2OH c) Br NaCN DMF d)
Unit 3 Hinw '3 SNİSNDELE2 1. Give the major product(s) for the following reactions. Indicate the mec reaction occurs, write "no reaction. s) in operation. If no KOC(CH) (CH COH b. H3C NaNH2 NHy Nal H3C H2CH-CH3 CH,COCH CH OH CH3 2. Give the mechanism of each of the following reactions. NaCN CH CH CHCN NaBr a. CH,CH,CH Br acetone HSCH,CH (CH) CSCH,CH3 HBr Cl + NaCI + CH OH NaOCH CH3OH Br CH OH CH3
2. Predict the major organic product(s) of the
reactions below. Assume 1 equivalent of reagent unless otherwise
stated, it's a solvent, or an oxidizing/reducing agent. Do consider
stereochemistry and regioselectivity.
2. Predict the major organic product(s) of the reactions below. Assume 1 equivalent of reagent unless otherwise stated, it's a solvent, or an oxidizing/reducing agent. Do consider stereochemistry and regioselectivity. (3 points each; 15 points total) A. Me 1. HNO3 2. O3 3. DMS 1. mCPBA, DCM (1 equiv) 2....
Complete the following reaction with the major
product
Reactions: complete the following reaction with the major product HBr он 1- OH POCl3 pyridine 2- H2SO4 OH 3- Hl 4- H20 H3PO4 5- Cl2 H20 7- 1) BH2-THF 2) H202, KOH 8- 2) 9- 1) BH3-THF 10- DLL 10- Date: G# : 12, and 13- Br H20 но 2) NaH 14, and 15- ) NaOH i NaOH 2 dil H.0 3) PBr 3)HBr F6 FZ F8
4. Draw the organic product of these reactions. Note that in so some cases, a 2-step process is written in this form. 1. reagents for 1st step REACTANT - PRODUCT 2. reagents for 2nd step OH + HB m i + HCI- + HCI + conc. H2SO4(aq) heat OH 1. NaOH 2. 1. mCPBA 2. H30+ 1. NaH CrO3, H2SO4(aq) OH acetone 5. State the major pathway by which these reactions wo product of that pathway. way by which these...
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