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Slide appropriate reactants into the boxes to conduct the following synthetic transformation. You don't need to...
Slide appropriate reactants into the boxes to conduct the following synthetic transformation. You don't need to...
Slide appropriate reactants into the boxes to conduct the following synthetic transformation. You don't need to necessarily fill all the boxes, but if you don't use them all, fill from the top down. Unused boxes can be left empty. BH3-THF; 2. NaOH, H2O2, H2o CH3CH2CH2U Hg2+, H2O, H+ KCN, HCN H20, H+ CH30H, H+ NaOH. H2O 1. (Sia)2BH; 2. NaOH, H2O2, H2O PhLi HOCH2CH20H, H+ Nothing Needed PCC PhMgBr CH3CH2NH2, H+ H2CrO4 KCN NaBH4, MeOH (CH3CH2CH2)2CuLi CH3CH2MgBr 1. LiAIH4 2....
Slide appropriate reactants into the boxes to conduct the following synthetic transformation. You don't ne Map...
Slide appropriate reactants into the boxes to conduct the following synthetic transformation. You don't ne Map to necessarily fill all the boxes, but if you don't use them all, fill from the top down. Unused boxes can be rent empty. Note: It is probably best to work these on paper, the same way you would on a test. Then once you've got your answer, look for the chemicals in the bins. When both a base and an electrophile both need...
Question 9 Which one of the following reaction steps work best to carry out the transformation...
Question 9 Which one of the following reaction steps work best to carry out the transformation shown below? ? ? H 1) BH3, THF PCC A) 2) H2O2, NaOH CH2Cl2 H20, H2SO4 (cat.) PCC B) CH2Cl2 1) BH3, THF HIO1 C) 2) HOh, NaOH D) OsO4 (CH3)3COOH, OH K2Cr207, H2SO4 H2O С в СА D
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary HBr Br2 CH2Cl2 HBr...
Provide the major product(s) for the following reactions: Show
Stereochemistry when necessary
HBr Br2 CH2Cl2 HBr Br2 ROOR H20 H2O СН,ОН H30* 1) BH3, THE 2) H2O2, NaOH, H2O 1) Hg(O2CCF3)2 CH3OH 2) NaBH4, NaOH 1) Hg(OAc)2, H20, THF 2) NaBH4, NaOH H2 Pd/C
Propose an efficient synthesis for the transformation below. Enter the appropriate number of letter from the...
Propose an efficient synthesis for the transformation below. Enter the appropriate number of letter from the reagent list handout Step 1 Step 2 Step 3 OH Alkyl Halides (X = CI, Br or 1) and Acyl chlorides: Assume Allig 15 present, if needed CIP CU CH3X X CI E A B EE Ketones. Aldehydes and Epoxides: Assume "then H20" is included if a protonation step is needed F A A K 0 MN Р Grignard, Wittig and Organocuprate Reagents: Assume...
NaBH4 CC Hg(OAC)2 H20, THE NaOH 1. Hg(O2CCF3)2, 'ProH 2. NaBH4, NaOH 1. BHz •THF 2....
NaBH4 CC Hg(OAC)2 H20, THE NaOH 1. Hg(O2CCF3)2, 'ProH 2. NaBH4, NaOH 1. BHz •THF 2. H2O2, HOⓇ R-OH + Nax — NaCN DMSO TSCI pyridine ОН MSCI pyridine NasMe DMSO cat. HA MeOH + g. Arrange in the Increasing acidity order HẠO ROH RC=CH HA NHA RH. cold KMnO4, HOor 1. Os04 2. NaHSO3 MICH3 1. mCPBA 2. H+, CH3OH, H2O 1. mCPBA 2. NaOCH3, H20 H2O / H+ Hg(OAC)2 H2O, THE NaBH4 NaOH 1. BH3 THF 2. HaO2...
25) What reagents can best be used to accomplish the following transformation? A) H+, H2O B)1....
25) What reagents can best be used to accomplish the following transformation? A) H+, H2O B)1. BH3-THF 2. Ho, H202 C)1. Hg(OAc)2, H2O/THF 2. NaBH4 D)1. Hg(O2CCF3)2 CH3OH 2. NaBH4 E) NaOH, H20
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions...
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
(30 pt) Draw the structures of the MAJOR products for the following reactions. Be sure to...
(30 pt) Draw the structures of the MAJOR products for the
following reactions. Be sure to clearly show the REGIO- and
STEREOCHEMISTRY of each product.
H2SO4 X - H2O BH3 H2O2 THF H20, OH Br2 CH2OH excess HBO d) CH3-C=C-CH3 1 eq Cl2 e) CH3 -C=C-CH3 CH2Cl2 Na CH3CO2H 9) CH.-C=C-H, under CH3COH f) CH3-CEC-CH3 liquid NH3 -78 °C H202 g) CH3CH2-CEC-H R2BH THE H2O, OH NaNH2 CH3CH2Br H2SO4 h) CH3CH2-CEC-H my Chcn=c20-n, Nanets, Cheka na H2O HgSO4 heat 1...
Q 2 - Fill in the boxes with the product(s) for the following reactions. Draw only...
Q 2 - Fill in the boxes with the product(s) for the following reactions. Draw only the predominate regioisomer and indicate the stereochemistry where appropriate. If a racemic mixture is formed, you may indicate this using a wavy line www or mark the chiral center with an asterisk (*), and write racemic in the box. You may also draw both enantiomers and write RACEMIC in the box. 1.BH3 2, H2O2, NaOH 1. Hg(OAc), H20 2. NaBH4 H3C CH3 1.BH 2....
Slide appropriate reactants into the boxes to conduct the following synthetic transformation. You don't need to necessarily fill all the boxes, but if you don't use them all, fill from the top down. Unused boxes can be left empty. BH3-THF; 2. NaOH, H2O2, H2o CH3CH2CH2U Hg2+, H2O, H+ KCN, HCN H20, H+ CH30H, H+ NaOH. H2O 1. (Sia)2BH; 2. NaOH, H2O2, H2O PhLi HOCH2CH20H, H+ Nothing Needed PCC PhMgBr CH3CH2NH2, H+ H2CrO4 KCN NaBH4, MeOH (CH3CH2CH2)2CuLi CH3CH2MgBr 1. LiAIH4 2....
Slide appropriate reactants into the boxes to conduct the following synthetic transformation. You don't ne Map to necessarily fill all the boxes, but if you don't use them all, fill from the top down. Unused boxes can be rent empty. Note: It is probably best to work these on paper, the same way you would on a test. Then once you've got your answer, look for the chemicals in the bins. When both a base and an electrophile both need...
Question 9 Which one of the following reaction steps work best to carry out the transformation shown below? ? ? H 1) BH3, THF PCC A) 2) H2O2, NaOH CH2Cl2 H20, H2SO4 (cat.) PCC B) CH2Cl2 1) BH3, THF HIO1 C) 2) HOh, NaOH D) OsO4 (CH3)3COOH, OH K2Cr207, H2SO4 H2O С в СА D
Provide the major product(s) for the following reactions: Show
Stereochemistry when necessary
HBr Br2 CH2Cl2 HBr Br2 ROOR H20 H2O СН,ОН H30* 1) BH3, THE 2) H2O2, NaOH, H2O 1) Hg(O2CCF3)2 CH3OH 2) NaBH4, NaOH 1) Hg(OAc)2, H20, THF 2) NaBH4, NaOH H2 Pd/C
Propose an efficient synthesis for the transformation below. Enter the appropriate number of letter from the reagent list handout Step 1 Step 2 Step 3 OH Alkyl Halides (X = CI, Br or 1) and Acyl chlorides: Assume Allig 15 present, if needed CIP CU CH3X X CI E A B EE Ketones. Aldehydes and Epoxides: Assume "then H20" is included if a protonation step is needed F A A K 0 MN Р Grignard, Wittig and Organocuprate Reagents: Assume...
NaBH4 CC Hg(OAC)2 H20, THE NaOH 1. Hg(O2CCF3)2, 'ProH 2. NaBH4, NaOH 1. BHz •THF 2. H2O2, HOⓇ R-OH + Nax — NaCN DMSO TSCI pyridine ОН MSCI pyridine NasMe DMSO cat. HA MeOH + g. Arrange in the Increasing acidity order HẠO ROH RC=CH HA NHA RH. cold KMnO4, HOor 1. Os04 2. NaHSO3 MICH3 1. mCPBA 2. H+, CH3OH, H2O 1. mCPBA 2. NaOCH3, H20 H2O / H+ Hg(OAC)2 H2O, THE NaBH4 NaOH 1. BH3 THF 2. HaO2...
25) What reagents can best be used to accomplish the following transformation? A) H+, H2O B)1. BH3-THF 2. Ho, H202 C)1. Hg(OAc)2, H2O/THF 2. NaBH4 D)1. Hg(O2CCF3)2 CH3OH 2. NaBH4 E) NaOH, H20
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
(30 pt) Draw the structures of the MAJOR products for the
following reactions. Be sure to clearly show the REGIO- and
STEREOCHEMISTRY of each product.
H2SO4 X - H2O BH3 H2O2 THF H20, OH Br2 CH2OH excess HBO d) CH3-C=C-CH3 1 eq Cl2 e) CH3 -C=C-CH3 CH2Cl2 Na CH3CO2H 9) CH.-C=C-H, under CH3COH f) CH3-CEC-CH3 liquid NH3 -78 °C H202 g) CH3CH2-CEC-H R2BH THE H2O, OH NaNH2 CH3CH2Br H2SO4 h) CH3CH2-CEC-H my Chcn=c20-n, Nanets, Cheka na H2O HgSO4 heat 1...
Q 2 - Fill in the boxes with the product(s) for the following reactions. Draw only the predominate regioisomer and indicate the stereochemistry where appropriate. If a racemic mixture is formed, you may indicate this using a wavy line www or mark the chiral center with an asterisk (*), and write racemic in the box. You may also draw both enantiomers and write RACEMIC in the box. 1.BH3 2, H2O2, NaOH 1. Hg(OAc), H20 2. NaBH4 H3C CH3 1.BH 2....
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